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Article

Fabrication and Characterization of Ti/TiC Composite Layers by an Electron-Beam Surface Modification

1
Academician Emil Djakov Institute of Electronics, Bulgarian Academy of Sciences, 72 Tzarigradsko Chausse Blvd, 1784 Sofia, Bulgaria
2
Department of Mathematics, Informatics and Natural Sciences, Technical University of Gabrovo, 4 Hadji Dimitar Street, 5300 Gabrovo, Bulgaria
3
Department of Material Science and Mechanics of Materials, Technical University of Gabrovo, 4 Hadji Dimitar Street, 5300 Gabrovo, Bulgaria
4
Department of Industrial Design and Textile Engineering, Technical University of Gabrovo, 4 Hadji Dimitar Street, 5300 Gabrovo, Bulgaria
*
Author to whom correspondence should be addressed.
Coatings 2023, 13(5), 951; https://doi.org/10.3390/coatings13050951
Submission received: 24 April 2023 / Revised: 15 May 2023 / Accepted: 17 May 2023 / Published: 19 May 2023

Abstract

In this study, the possibilities for modification and improvement of the surface structure and properties of titanium substrates by a formation of composite Ti/TiC layers are presented. The layers were fabricated by a two-step electron-beam surface modification technique. The first step consists of injection of C powder within the pure Ti substrates by electron-beam alloying technology. The second step is the refinement and homogenization of the microstructure by the electron-beam remelting procedure. During the remelting, the speed of the motion of the samples was varied, and two (most representative) velocities were chosen: 5 and 15 mm/s. Considering both speeds of the motion of the specimens, a composite structure in the form of fine TiC particles distributed within the base titanium matrix was formed. The remelting speed of 5 mm/s led to the formation of a much thicker composite layer, where the TiC particles were significantly more homogeneously distributed. The results obtained for the Vickers microhardness exhibit a significant increase in the value in the mentioned mechanical characteristic in comparison with the base Ti substrate. In the case of the lower speed of the motion of the specimen during the remelting procedure, the microhardness is 510 HV, or about 2.5 times higher than that of the titanium substrate. The application of a higher speed of the specimen motion leads to a decrease in the microhardness in comparison with the case of lower velocity. However, it is still much higher than that of the base Ti material. The mean microhardness of the sample obtained by the remelting speed of motion of 15 mm/s is 360 HV, or it is 1.8 times higher than that of the base material.
Keywords: electron-beam surface modification; titanium carbide; microstructure; microhardness; X-ray diffraction; scanning electron microscopy; energy-dispersive X-ray spectroscopy electron-beam surface modification; titanium carbide; microstructure; microhardness; X-ray diffraction; scanning electron microscopy; energy-dispersive X-ray spectroscopy

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MDPI and ACS Style

Valkov, S.; Nedeva, D.; Dunchev, V.; Padikova, F.; Ormanova, M.; Stoyanov, B.; Nedyalkov, N. Fabrication and Characterization of Ti/TiC Composite Layers by an Electron-Beam Surface Modification. Coatings 2023, 13, 951. https://doi.org/10.3390/coatings13050951

AMA Style

Valkov S, Nedeva D, Dunchev V, Padikova F, Ormanova M, Stoyanov B, Nedyalkov N. Fabrication and Characterization of Ti/TiC Composite Layers by an Electron-Beam Surface Modification. Coatings. 2023; 13(5):951. https://doi.org/10.3390/coatings13050951

Chicago/Turabian Style

Valkov, Stefan, Daniela Nedeva, Vladimir Dunchev, Fatme Padikova, Maria Ormanova, Borislav Stoyanov, and Nikolay Nedyalkov. 2023. "Fabrication and Characterization of Ti/TiC Composite Layers by an Electron-Beam Surface Modification" Coatings 13, no. 5: 951. https://doi.org/10.3390/coatings13050951

APA Style

Valkov, S., Nedeva, D., Dunchev, V., Padikova, F., Ormanova, M., Stoyanov, B., & Nedyalkov, N. (2023). Fabrication and Characterization of Ti/TiC Composite Layers by an Electron-Beam Surface Modification. Coatings, 13(5), 951. https://doi.org/10.3390/coatings13050951

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