Nanomaterials, Volume 12, Issue 7
2022 April-1 - 206 articles
Cover Story: We report the synthesis of a hybrid nanocatalyst obtained through the immobilization of a bioinspired [{Mn(bpy)(H2O)}(µ-2-MeC6H4COO)2(µ-O){Mn(bpy)(NO3)}]NO3 compound into functionalized, monodispersed, and mesoporous silica nanoparticles. The in situ dual-functionalization sol–gel strategy adopted here leads to the synthesis of raspberry-shaped silica nanoparticles of ca. 72 nm with a large open porosity, with the preferential localization of 1,4-pyridine within the pores, and with sulfobetaine zwitterion on the nanoparticles’ peripheries. These nano-objects exhibit improved catalase-mimicking activity in water thanks to the encapsulation/immobilization of the catalytic active complex and high colloidal stability in water, as demonstrated through the dismutation reaction of hydrogen peroxide. View this paper - Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
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