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Catalysts, Volume 7, Issue 9

September 2017 - 37 articles

Cover Story: Non-edible lignocellulosic biomass can be converted into drop-in biofuels via various routes among which much attention has been recently paid to a combination of biological and chemical transformations. The promising example is that fermentation-derived acetone and alcohols can be catalytically transformed into long-chain hydrocarbons of fuel range. In the chemical transformation are involved two reaction steps such as alcohol dehydrogenation into aldehyde over metallic sites and aldol condensation between acetone of enol/enolate type and in-situ formed aldehyde over basic sites. This desired conversion is achieved by Cu catalysts supported on the ceria-zirconia of ceria rich. View Paper here
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Articles (37)

  • Feature Paper
  • Article
  • Open Access
18 Citations
6,950 Views
14 Pages

Expanding the Scope of Cu(I) Catalyzed “Click Chemistry” with Abnormal NHCs: Three-Fold Click to Tris-Triazoles

  • Nga Kim T. Ho,
  • Sven O. Reichmann,
  • Dennis Rottschäfer,
  • Regine Herbst-Irmer and
  • Rajendra S. Ghadwal

1 September 2017

Cationic copper(I) complexes [Cu(aIPrPh)(IPr)]I (3) and [Cu(aIPrPh)2]I (4) featuring an abnormal N-heterocyclic carbene (aNHC) (aIPrPh = 1,3-bis(2,6-diisopropylphenyl)-2-phenyl- imidazol-4-ylidene) and/or an NHC (IPr = 1,3-Bis(2,6-diisopropylphenyl)i...

  • Feature Paper
  • Review
  • Open Access
24 Citations
9,130 Views
57 Pages

The Beneficial Sinergy of MW Irradiation and Ionic Liquids in Catalysis of Organic Reactions

  • Barbara Floris,
  • Federica Sabuzi,
  • Pierluca Galloni and
  • Valeria Conte

1 September 2017

The quest for sustainable processes is becoming more and more important, with catalysis playing a major role in improving atom economy and reducing waste. Organic syntheses with less need of protecting/de-protecting steps are highly desirable. The co...

  • Article
  • Open Access
8 Citations
4,461 Views
10 Pages

31 August 2017

A novel nicotine hydroxylase was isolated from Pseudomonas sp. ZZ-5 (HSPHZZ). The sequence encoding the enzyme was 1206 nucleotides long, and encoded a protein of 401 amino acids. Recombinant HSPHZZ was functionally overexpressed in Escherichia coli...

  • Article
  • Open Access
13 Citations
6,194 Views
17 Pages

31 August 2017

The effect of active solutions suitable for the in situ activation of selective catalytic reduction (SCR) catalysts was experimentally investigated using a designed in situ activation modeling device. To gain further insight, scanning electron micros...

  • Article
  • Open Access
49 Citations
7,276 Views
13 Pages

Nature and Location of Carbonaceous Species in a Composite HZSM-5 Zeolite Catalyst during the Conversion of Dimethyl Ether into Light Olefins

  • María Ibáñez,
  • Paula Pérez-Uriarte,
  • Miguel Sánchez-Contador,
  • Tomás Cordero-Lanzac,
  • Andrés T. Aguayo,
  • Javier Bilbao and
  • Pedro Castaño

30 August 2017

The deactivation of a composite catalyst based on HZSM-5 zeolite (agglomerated in a matrix using boehmite as a binder) has been studied during the transformation of dimethyl ether into light olefins. The location of the trapped/retained species (on t...

  • Article
  • Open Access
18 Citations
5,580 Views
10 Pages

Continuous-Flow Monolithic Silica Microreactors with Arenesulphonic Acid Groups: Structure–Catalytic Activity Relationships

  • Agnieszka Ciemięga,
  • Katarzyna Maresz,
  • Janusz J. Malinowski and
  • Julita Mrowiec-Białoń

30 August 2017

The performance of monolithic silica microreactors activated with sulphonic acid groups and a packed bed reactor with Amberlyst 15 resin were compared in the esterification of acetic acid with n-butanol. The monolithic microreactors were made of sing...

  • Review
  • Open Access
64 Citations
9,412 Views
21 Pages

Controllable and Large-Scale Synthesis of Carbon Nanostructures: A Review on Bamboo-Like Nanotubes

  • Zirui Jia,
  • Kaichang Kou,
  • Ming Qin,
  • Hongjing Wu,
  • Fabrizio Puleo and
  • Leonarda Francesca Liotta

30 August 2017

Bamboo-like carbon nanotubes are members of the carbon nanotubes (CNTs) family, whose structure is made up of separated hollow compartments and bamboo knots. Due to the peculiar structure of the CNTs species, the growth mechanism and related features...

  • Feature Paper
  • Review
  • Open Access
24 Citations
7,641 Views
24 Pages

28 August 2017

The monolithic catalyst, namely the structured catalyst, is one of the important categories of catalysts used in various fields, especially in catalytic exhaust after-treatment. Despite its successful application in conventional wash-coated catalysts...

  • Article
  • Open Access
21 Citations
7,431 Views
13 Pages

The Kinetic Resolution of Racemic Amines Using a Whole-Cell Biocatalyst Co-Expressing Amine Dehydrogenase and NADH Oxidase

  • Hyunwoo Jeon,
  • Sanghan Yoon,
  • Md Murshidul Ahsan,
  • Sihyong Sung,
  • Geon-Hee Kim,
  • Uthayasuriya Sundaramoorthy,
  • Seung-Keun Rhee and
  • Hyungdon Yun

25 August 2017

Amine dehydrogenase (AmDH) possesses tremendous potential for the synthesis of chiral amines because AmDH catalyzes the asymmetric reductive amination of ketone with high enatioselectivity. Although a reductive application of AmDH is favored in pract...

  • Feature Paper
  • Article
  • Open Access
59 Citations
6,065 Views
14 Pages

Exploiting the Versatility of Aminated Supports Activated with Glutaraldehyde to Immobilize β-galactosidase from Aspergillus oryzae

  • Hadjer Zaak,
  • Sara Peirce,
  • Tiago L. De Albuquerque,
  • Mohamed Sassi and
  • Roberto Fernandez-Lafuente

25 August 2017

The enzyme β-galactosidase from Aspergillus oryzae has been immobilized in aminated (MANAE)-agarose beads via glutaraldehyde chemistry using different strategies. The immobilization on MANAE-supports was first assayed at different pH values (this gav...

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Catalysts - ISSN 2073-4344