Catalysts, Volume 15, Issue 9
2025 September - 118 articles
Cover Story: Ammonia is emerging as a practical hydrogen carrier. However, turning it into high-purity H2 in an efficient way remains a challenge for both catalysts and reactors. This review analyzes the field from thermodynamics to industrial implementation. For a fair comparison, we evaluate catalyst performance using standardized metrics (WHSV, purified H2 productivity, and recovery factor), with Ru as a benchmark, and assess the lower-cost Ni, Co, and Fe systems. This analysis also examines the role of basic supports and alkali promoters, as well as key kinetic models. We then evaluate reactor concepts, from fixed beds to microreactors and H2-selective membrane reactors, capable of boosting yields at lower temperatures than other reactors. The present review approach can help guide the selection of catalyst and reactor design for ammonia-to-hydrogen systems. View this paper - Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
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