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Materials, Volume 18, Issue 7

2025 April-1 - 298 articles

Cover Story: Clotrimazole (CLO) is a widely used antifungal drug, but its effectiveness is limited by poor skin penetration. Microneedle (MN) systems offer a promising strategy to enhance topical drug delivery. This study aimed to develop CLO-coated MN systems using LCD-based 3D printing. Printing parameters were comprehensively optimized to ensure high print quality and adequate mechanical strength. The systems were coated with either a suspension or an ethanol-based hydrogel, with the latter showing superior properties. In vitro drug release, antifungal activity, and acute toxicity were analyzed, all of which confirmed the biocompatibility and potential effectiveness of these systems. The findings provide valuable insights into precise 3D printing parameter settings and a suitable foundation for further research into MN systems as a drug delivery platform. View this paper
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Articles (298)

  • Article
  • Open Access
4 Citations
1,696 Views
26 Pages

7 April 2025

Concrete, known for its high strength, durability, and flexibility, is a core material in construction. However, defects such as voids and honeycombing often occur due to improper pouring or vibration, weakening the concrete’s strength and affe...

  • Article
  • Open Access
1 Citations
1,554 Views
32 Pages

Comparative Analysis of Energy Viability of Crop Residue from Different Corn Varieties

  • Raquel García-Mateos,
  • María Teresa Miranda,
  • José Ignacio Arranz,
  • Pilar Romero,
  • Francisco José Sepúlveda and
  • Santiago Cuellar-Borrego

7 April 2025

The valorization of agricultural residues assumes a pivotal position in the circular economy by transforming waste into a useful and environmentally friendly product, with the cultivation of corn, as one of the world’s predominant crops, being...

  • Article
  • Open Access
6 Citations
1,458 Views
16 Pages

7 April 2025

This study proposes a novel modelling approach that integrates mutual information (MI)-based parameter screening with random forest (RF) modelling to achieve an accurate quantitative prediction of surface hardness and impact energy in two martensitic...

  • Article
  • Open Access
1,168 Views
14 Pages

The Effect of Aging Time at 600 °C on Tensile Properties of the 0.3Nb FeCrAl Alloy

  • Liping Tang,
  • Hongying Sun,
  • Guijun Wu,
  • Zhangquan Lv and
  • Yi Xiong

7 April 2025

This study examines the impact of aging at 600 °C on the tensile properties of 0.3NbFeCrAl alloy at various temperatures, including room temperature (RT), 300 °C, 350 °C, and 400 °C, as well as the corresponding changes in microstruct...

  • Communication
  • Open Access
3 Citations
2,858 Views
9 Pages

7 April 2025

Textile fibers are an essential component of daily necessities and are often used as forensic evidence, making their characterization crucial in forensic science. Different types of textile fibers can be identified using their unique Raman spectral c...

  • Article
  • Open Access
5 Citations
1,273 Views
22 Pages

Diffusion Mechanism in Running-Water and CFD-DEM Numerical Simulation of Expandable Particulate Grouting Material

  • Zhipeng Zhang,
  • Chenyang Ma,
  • Chen Zhao,
  • Zhuo Zheng,
  • Wei Li,
  • Rentai Liu,
  • Xiuhao Li and
  • Hongyan Wang

7 April 2025

In order to study the diffusion and sealing mechanism of an innovative grouted material tentatively called “expandable particulate grout material”, the diffusion process was simulated by the numerical method of CFD-DEM coupling. A numeric...

  • Article
  • Open Access
2 Citations
3,030 Views
31 Pages

Study of the Relationship Between the Structures and Biological Activity of Herbicides Derived from Phenoxyacetic Acid

  • Grzegorz Świderski,
  • Natalia Kowalczyk,
  • Gabriela Tyniecka,
  • Monika Kalinowska,
  • Renata Łyszczek,
  • Aleksandra Bocian,
  • Ewa Ciszkowicz,
  • Leszek Siergiejczyk,
  • Małgorzata Pawłowska and
  • Jacek Czerwiński

7 April 2025

Chloroderivatives of phenoxyacetic acid are a group of compounds commonly used as plant protection products. Differences in the molecular structure of these compounds are related to varying substitution and the number of chlorine atoms in the aromati...

  • Article
  • Open Access
5 Citations
1,343 Views
17 Pages

7 April 2025

Fused Deposition Modeling (FDM) has emerged as one of the most widely adopted additive manufacturing (AM) technologies due to its broad material availability and low production costs, enabling the efficient production of complex geometries and custom...

  • Article
  • Open Access
1 Citations
2,401 Views
30 Pages

A Material Study of Persian-Period Silver Coins and Hacksilber from Samaria

  • Dana Ashkenazi,
  • Maayan Cohen,
  • Haim Gitler,
  • Mati Johananoff and
  • Oren Tal

7 April 2025

An assembly of fourth-century BCE Samarian silver coins and late-fifth-century BCE Samarian cut silver sheets, Sidonian and Philistian coins from a hacksilber hoard allegedly found in the region of Samaria belonging to the David and Jemima Jeselsohn...

  • Article
  • Open Access
1 Citations
1,268 Views
30 Pages

6 April 2025

Steel frame infilled with composite plate shear wall (SF-CPSW) is an effective structure for lateral-load resisting. In the structural design, the vertical loads are primarily carried by the boundary SF, while the horizontal loads are expected to be...

  • Article
  • Open Access
6 Citations
1,760 Views
27 Pages

6 April 2025

This study presents a Multi-layer Quasi-Zero-Stiffness (ML-QZS) vibration isolation platform for variable loads in large-amplitude and low-frequency dynamic environments. In one isolation mount of the proposed ML-QZS isolation platform, Multi-layer p...

  • Article
  • Open Access
5 Citations
1,505 Views
17 Pages

6 April 2025

This study investigates the correlation between the cross-linked network structure and the macroscopic mechanical properties of 3,3-bis(azidomethyl)oxetane-tetrahydrofuran copolymer (PBT)-based solid propellants through molecular dynamics (MD) simula...

  • Article
  • Open Access
1 Citations
1,108 Views
16 Pages

6 April 2025

Fibrous materials, prevalent in biological tissues and engineered composites, undergo remodeling in response to mechanical loads, leading to plastic changes in fiber orientation. A previously developed continuum model describes this remodeling proces...

  • Article
  • Open Access
7 Citations
1,569 Views
22 Pages

Forming Process Prediction Model and Application of Laser Cladding for Remanufactured Screw Pump Rotors

  • Haiying Zu,
  • Yongpeng Liu,
  • Sihui Chen,
  • Xiang Jin,
  • Weidong Ye,
  • Mingyuan Sun,
  • Zhongmin Xiao and
  • Liming Yao

5 April 2025

In order to achieve high-quality repair of complex curved parts, a remanufacturing process method utilizing laser cladding and reverse engineering technology is proposed to be implemented by robots. This study focuses on the oscillating helical surfa...

  • Article
  • Open Access
4 Citations
1,287 Views
14 Pages

5 April 2025

This article presents the influence of lubricant on selected tribological properties of the rolling–sliding association, i.e., the wheel–rail system. Three solid lubricants were tested: soybean grease, molybdenum disulfide and graphite gr...

  • Article
  • Open Access
4 Citations
1,651 Views
19 Pages

Substrate Bias-Driven Structural and Mechanical Evolution of AlCrN and AlCrSiN Coatings via Reactive Magnetron Sputtering

  • Du-Cheng Tsai,
  • Rong-Hsin Huang,
  • Zue-Chin Chang,
  • Erh-Chiang Chen,
  • Yen-Lin Huang and
  • Fuh-Sheng Shieu

5 April 2025

AlCrN and AlCrSiN coatings were deposited via reactive magnetron sputtering. This study investigates the effects of radio frequency (RF) substrate bias, ranging from 0 V to 200 V, on the chemical composition, microstructure, and mechanical properties...

  • Article
  • Open Access
5 Citations
3,934 Views
31 Pages

An Experimental Investigation into Trochoidal Milling for High-Quality GFRP Machining

  • Ondřej Bílek,
  • Martin Řezníček,
  • Andrzej Matras,
  • Tomáš Solařík and
  • Lubomír Macků

5 April 2025

This study investigates the effectiveness of trochoidal (adaptive) milling in machining Glass Fiber Reinforced Polymer (GFRP), emphasizing its potential advantages over conventional milling. Six coated solid carbide end mills, each with distinct geom...

  • Article
  • Open Access
1 Citations
1,598 Views
16 Pages

Impact of NaHCO3/Na2CO3 Buffer Reagent on Mitigating the Corrosion of C110 Steel in Water-Based Annulus Protection Fluid at Ultrahigh Temperature

  • Zhi Zhang,
  • Mifeng Zhao,
  • Yan Li,
  • Junfeng Xie,
  • Wenwen Song,
  • Juantao Zhang,
  • Mengkai Wang,
  • Jie Zhou,
  • Yuan Wang and
  • Danping Li
  • + 1 author

5 April 2025

The drilling of ultradeep oil wells brings many challenges to the downhole tubular materials, where corrosion induced by halide annulus protection fluid is one major problem. In this work, the Na2CO3/NaHCO3 buffer system is employed to mitigate the c...

  • Article
  • Open Access
3 Citations
2,660 Views
19 Pages

Interactions of Terahertz Photons with Phonons of Two-Dimensional van der Waals MoS2/WSe2/MoS2 Heterostructures and Thermal Responses

  • Jingwen Huang,
  • Ningsheng Xu,
  • Yumao Wu,
  • Xue Ran,
  • Yue Fang,
  • Hongjia Zhu,
  • Weiliang Wang,
  • Huanjun Chen and
  • Shaozhi Deng

4 April 2025

The interaction between terahertz (THz) photons and phonons of materials is crucial for the development of THz photonics. In this work, typical two-dimensional (2D) van der Waals (vdW) transition metal chalcogenide (TMD) layers and heterostructures a...

  • Article
  • Open Access
1,210 Views
13 Pages

Optimization of Hybrid Composite–Metal Joints: Single Pin

  • Ruopu Bian,
  • Bin Wang,
  • Hongying Yang,
  • Jiazhi Ren,
  • Lujun Cui and
  • Oluwamayokun B. Adetoro

4 April 2025

Deepening the understanding of composite and metal joint methodologies applied in the aerospace industry is crucial for minimizing operational expenditures. Current investigations are focusing on innovative joining techniques that incorporate additiv...

  • Article
  • Open Access
3 Citations
1,387 Views
16 Pages

4 April 2025

This study investigates the effects of molybdenum (Mo) and boron (B) on the microstructures and impact properties in the coarse grain heat-affected zone (CGHAZ) of a low-carbon V-Ti-N steel. The results demonstrate that, at a heat input of up to 75 k...

  • Article
  • Open Access
1,281 Views
17 Pages

4 April 2025

The corrosion thinning behavior and mechanism of low-alloy water wall tubes of an ultra-supercritical power plant was investigated via SEM, EPMA, XRD, TEM, and laboratory simulation experiments. Fireside corrosion was first initiated by chemical pote...

  • Article
  • Open Access
1 Citations
1,158 Views
13 Pages

4 April 2025

This study explores the rheological properties of polydimethylsiloxane (PDMS) composites with glass beads (GBs) to replicate the compression-stiffening behavior of biological tissues. The mechanical properties of soft tissues arise from interactions...

  • Article
  • Open Access
1,325 Views
20 Pages

4 April 2025

Biomineralization technology is a promising method for soil cementation, enhancing its mechanical properties. However, its application in mitigating slope surface erosion caused by rainfall has not been fully explored. This study experimentally exami...

  • Article
  • Open Access
1 Citations
2,249 Views
32 Pages

Preparation and Characterization of Char Carbon Obtained by Carbonization of Unused Cigarette Filter Rods: The Product Application Assessment

  • Bojan Janković,
  • Dejan Cvetinović,
  • Milena Milošević,
  • Filip Veljković,
  • Vladimir Rajić,
  • Marija Janković and
  • Vladimir Dodevski

4 April 2025

The development of carbonaceous materials such as biochar has triggered a hot spot in materials application. In this study, a new type of char carbon was developed from raw cigarette filter rods (CFRs) via a carbonization process under moderate condi...

  • Article
  • Open Access
1 Citations
2,024 Views
19 Pages

4 April 2025

The chemical composition and molecular structure of the pitch-like products obtained by liquid-phase reaction of bituminous coal with heavy hydrocarbon fractions of coal and petroleum origin as solvents at a moderate temperature were comprehensively...

  • Article
  • Open Access
2 Citations
1,281 Views
21 Pages

4 April 2025

The growing interest in renewable resource-based materials has driven efforts to develop elastomeric biocomposites using biomass, phyto-ash, and biochar as fillers. These bio-additives, derived from beech wood through various processing methods, were...

  • Article
  • Open Access
3 Citations
1,585 Views
16 Pages

Synthesis, Characterization, and Investigation of the Properties of a New Promising Poly(Azomethine) Organic Semiconductor Material

  • Jihane Ismaili,
  • Chouki Zerrouki,
  • Najla Fourati,
  • Stephanie Leroy-Lhez,
  • Daniel Montplaisir,
  • Nicolas Villandier and
  • Rachida Zerrouki

4 April 2025

A new poly(azomethine) with improved solubility was successfully prepared by the polycondensation of terephthalaldehyde and 2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropane (4-BDAF) under green chemistry conditions. This new polymer containing hex...

  • Article
  • Open Access
1 Citations
1,090 Views
15 Pages

4 April 2025

Corrosion protection in reinforced concrete structures exposed to aggressive environments remains a critical challenge in civil and architectural engineering. One promising approach involves the application of corrosion-inhibiting monolayers on the r...

  • Article
  • Open Access
1 Citations
1,135 Views
15 Pages

Dielectric Properties of Isotactic Polypropylene with Lignocellulose-Based Biomass Filler

  • Dragana D. Cerovic,
  • Ivan M. Petronijevic,
  • Filip S. Marinkovic,
  • Slavica B. Maletic and
  • Dusan M. Popovic

4 April 2025

The ecological aspect of substituting synthetic materials with natural materials is of great interest nowadays. This paper examines the percentage of lignocellulose-based fillers that can be added to a synthetic polymer matrix to ensure the resulting...

  • Article
  • Open Access
6 Citations
1,851 Views
12 Pages

Enhanced Toughness of High-Entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C Ceramics with SiC Whiskers by High-Pressure and High-Temperature Sintering

  • Hao Li,
  • Zhenxing Yang,
  • Min Lian,
  • Shuailing Ma,
  • Wei Li,
  • Xinmiao Wei,
  • Xingbin Zhao,
  • Yilong Pan,
  • Yunfeng She and
  • Tian Cui
  • + 2 authors

4 April 2025

High-entropy ceramics (HECs) have garnered considerable interest due to their exceptional mechanical properties and high-temperature stability. Nevertheless, their inherent brittleness significantly restricts industrial applications, posing a challen...

  • Article
  • Open Access
1 Citations
1,380 Views
22 Pages

3 April 2025

This study successfully achieved the in situ synthesis of carbon nanotubes (CNTs) on aluminum powder substrates through rotating chemical vapor deposition (R-CVD) using nickel-based catalysts with acetylene as the carbon source. Through systematic pa...

  • Article
  • Open Access
4 Citations
2,738 Views
19 Pages

A Study on the Corrosion Behavior of Fe/Ni-Based Structural Materials in Unpurified Molten Chloride Salt

  • Unho Lee,
  • Min Wook Kim,
  • Jisu Na,
  • Mingyu Lee,
  • Sung Joong Kim,
  • Dong-Joo Kim and
  • Young Soo Yoon

3 April 2025

The molten salt reactor is a fourth-generation nuclear power plant considered a long-term eco-friendly energy source with high efficiency and the potential for green hydrogen production. The selection of alloys for such reactors, which can operate fo...

  • Review
  • Open Access
4 Citations
3,543 Views
31 Pages

Evaluation of Patellar Groove Prostheses in Veterinary Medicine: Review of Technological Advances, Technical Aspects, and Quality Standards

  • Mateusz Pawlik,
  • Piotr Trębacz,
  • Anna Barteczko,
  • Aleksandra Kurkowska,
  • Agata Piątek,
  • Zbigniew Paszenda and
  • Marcin Basiaga

3 April 2025

This review explores the technological advancements in, engineering considerations regarding, and quality standards of veterinary patellar groove replacement implants. Veterinary-specific regulations for these implants are currently lacking. Therefor...

  • Article
  • Open Access
6 Citations
4,743 Views
18 Pages

3 April 2025

The construction industry is facing an increased demand to adopt sustainable green building materials to minimize the carbon footprint. Hemp concrete is a green building material not only because of its low embodied carbon but also because of its abi...

  • Communication
  • Open Access
994 Views
14 Pages

3 April 2025

The anisotropic strain development and releasing process in materials is largely related to their intrinsic mechanical properties and mesoscale grain interactions. Uniaxial compression can induce a large amount activation energy in a system, which bu...

  • Article
  • Open Access
2 Citations
1,399 Views
20 Pages

Ultra-Small Iron-Based Nanoparticles with Mild Photothermal-Enhanced Cascade Enzyme-Mimic Reactions for Tumor Therapy

  • Jing Yu,
  • Shuangshan Li,
  • Xun Zhu,
  • Hongyan Yu,
  • Hao Gao,
  • Jiarui Qi,
  • Yao Ying,
  • Liang Qiao,
  • Jingwu Zheng and
  • Shenglei Che
  • + 1 author

3 April 2025

Chemodynamic therapy (CDT), which utilizes the catalytic reactions of nanoparticles to inhibit tumor growth, is a promising approach in cancer therapy. However, its efficacy is limited by insufficient hydrogen peroxide (H2O2) concentration in tumor m...

  • Article
  • Open Access
1,186 Views
15 Pages

3 April 2025

The FeZn-MOFs@Al2O3 catalyst was synthesized under solvothermal conditions. Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analys...

  • Article
  • Open Access
7 Citations
2,166 Views
17 Pages

3 April 2025

Constructing van der Waals heterojunctions with excellent properties has attracted considerable attention in the field of photocatalytic water splitting. In this study, four patterns, coined A, B, C, and D of Janus Ga2SSe/Bi2O3 van der Waals (vdW) he...

  • Article
  • Open Access
1 Citations
1,510 Views
21 Pages

The Impact of Superplasticizer Chemical Structure on Reactive Powder Concrete Properties

  • Stefania Grzeszczyk,
  • Aneta Matuszek-Chmurowska,
  • Natalina Makieieva,
  • Teobald Kupka and
  • Adam Sudoł

3 April 2025

It is difficult to obtain efficient flowability of reactive powder concrete (RPC) mix due to a low water/binder ratio. The improvement of material flowability could be achieved by using the latest generation polycarboxylate superplasticizers (SPs), a...

  • Article
  • Open Access
2 Citations
1,164 Views
22 Pages

3 April 2025

The adhesion of deleterious bacteria on titanium substrates not only causes economic losses but also endangers human life and health. The study is expected to address the challenging issues of using ZnO as an antibacterial material, including low bac...

  • Article
  • Open Access
1 Citations
1,068 Views
15 Pages

The Effect of Hollow Polymer Microspheres on the Pore Structure and Frost Resistance of Cement Mortar

  • Lihui Li,
  • Jianrui Ji,
  • Lingfeng Yu,
  • Zhihui Luo,
  • Panpan Zhang and
  • Kaimin Niu

3 April 2025

This study elucidates the effects of total air content, pore size distribution, and bubble spacing coefficient on mortar frost resistance. It presents a systematic comparison between mortars obtained with different porous structures. Conventional por...

  • Article
  • Open Access
1,330 Views
19 Pages

Microstructure and Mechanical Properties of Nb35Zr26Ti19Hf15Mo5 Refractory High-Entropy Alloy Under Rolling and Heat Treatment

  • Hanjun Zhang,
  • Baohong Zhu,
  • Wei Jiang,
  • Haochen Qiu,
  • Shuaishuai Wu,
  • Xuehui Yan and
  • Shengli Guo

3 April 2025

Refractory high-entropy alloys (RHEAs) have drawn much attention in the field of materials science for their unique properties and wide compositional design space. The Nb35Zr26Ti19Hf15Mo5 alloy is important for exploring RHEAs’ potential in hig...

  • Article
  • Open Access
1,492 Views
11 Pages

3 April 2025

The tetragonal R1−xZrx(FeCo)11Ti alloys, where R is a rare earth and Ti a transition metal, are promising candidates for permanent magnets. Sm1−xZrx(Fe0.8Co0.2)12−yTiy (x = 0 and 0.25; y = 1 and 0.7) master alloys were prepared by a...

  • Article
  • Open Access
3 Citations
1,215 Views
16 Pages

3 April 2025

The existence of bubble defects in ultra-low expansion quartz glass will affect the optical properties and mechanical strength of the material. The present paper proposes a novel defect characterization method based on ultrasonic nondestructive testi...

  • Article
  • Open Access
2 Citations
1,610 Views
15 Pages

3 April 2025

The management of washing water from concrete plants is a growing environmental and industrial concern due to its high alkalinity and the presence of suspended solids, chemical admixtures, and dissolved salts. This study investigates the impact of co...

  • Article
  • Open Access
3 Citations
3,090 Views
21 Pages

3 April 2025

Polypropylene (PP), a widely used recyclable plastic in packaging and engineering applications, is prone to thermo-oxidative degradation during reprocessing and molding at high temperatures. Antioxidants (AOs) are essential for stabilizing PP in both...

  • Article
  • Open Access
1 Citations
1,517 Views
12 Pages

3 April 2025

This study explored the effects of T5 and T6 heat treatments on the microstructure and tensile properties of a laser powder bed fusion (LPBF)-fabricated Al–Mn–Mg–Sc–Zr alloy. The as-built condition exhibited a bi-modal grain structure of equiaxed and...

  • Article
  • Open Access
2 Citations
1,322 Views
23 Pages

3 April 2025

The fallen leaf has the potential to be energy-valorized in cities with sustainability goals. Thermochemical characterization of garden waste through pyrolysis and combustion kinetics will establish the reactivity of this lignocellulosic biomass as b...

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Materials - ISSN 1996-1944