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Materials, Volume 16, Issue 17 (September-1 2023) – 344 articles

Cover Story (view full-size image): Over 70,000 deaths occur worldwide each year due to infections with antibiotic-resistant strains of bacteria. Consequently, it is necessary to enhance the efficiency of quaternary wastewater treatment processes. Persulfate-assisted heterogeneous photocatalysis is a promising method for degrading organic pollutants, but it still requires further investigation. Here, we combined TiO2 and ZnO photocatalysts with peroxydisulfate (PDS) ions to enhance the photocatalytic activity and study the degradation of trimethoprim, a widely used antibiotic. In the case of ZnO, the positive effect of PDS successfully overcompensates for the unfavorable matrix effects due to highly efficient SO4•− generation. However, the interaction of organic and inorganic components with the surface of the photocatalyst and their competition for photogenerated charges must be considered. View this paper
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11 pages, 3382 KiB  
Article
The Effects of Compressive Residual Stress on Properties of Kyanite-Coated Zirconia Toughened Alumina Ceramics
by Hao-Long Wu, Haiyan Li, Dake Cao, Yan Qiu, Detian Wan and Yiwang Bao
Materials 2023, 16(17), 6071; https://doi.org/10.3390/ma16176071 - 4 Sep 2023
Viewed by 861
Abstract
In this study, the prestressed coating reinforcement method was employed to create kyanite-coated zirconia toughened alumina (ZTA) prestressed ceramics. Due to the mismatch of the coefficient of thermal expansion (CTE) between the coating and substrate, compressive residual stress was introduced in the coating. [...] Read more.
In this study, the prestressed coating reinforcement method was employed to create kyanite-coated zirconia toughened alumina (ZTA) prestressed ceramics. Due to the mismatch of the coefficient of thermal expansion (CTE) between the coating and substrate, compressive residual stress was introduced in the coating. The effects of compressive residual stress on the mechanical properties of ZTA have been demonstrated. Results show that the flexural strength of the kyanite-coated ZTA ceramics improved by 40% at room temperature compared to ZTA ceramics. In addition, the temperature dependence of mechanical properties has also been discussed. And the results show that the reinforcement gradually diminished with increasing temperature and eventually disappeared at 1000 °C. The modulus of elasticity of the material also exhibits a decreasing trend. Furthermore, the introduction of the prestressing coating enhanced the thermal shock resistance, but the strengthening effect diminished as the temperature increased and completely disappeared at 800 °C. Full article
(This article belongs to the Section Advanced and Functional Ceramics and Glasses)
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21 pages, 3275 KiB  
Article
Effect of the Advanced Cranial and Craniofacial Implant Fabrication on Their Degradation Affinity
by Edyta Chmal-Fudali, Daria Basińska, Agnieszka Kucharska-Jastrząbek, Marcin H. Struszczyk, Małgorzata Muzalewska, Marek Wyleżoł, Marcin Wątrobiński, Jacek Andrzejewski, Nina Tarzyńska and Karolina Gzyra-Jagieła
Materials 2023, 16(17), 6070; https://doi.org/10.3390/ma16176070 - 4 Sep 2023
Cited by 4 | Viewed by 922
Abstract
Biodegradable craniofacial and cranial implants are a new aspect in terms of reducing potential complications, especially in the long term after surgery. They are also an important contribution in the field of surgical reconstructions for children, for whom it is important to restore [...] Read more.
Biodegradable craniofacial and cranial implants are a new aspect in terms of reducing potential complications, especially in the long term after surgery. They are also an important contribution in the field of surgical reconstructions for children, for whom it is important to restore natural bone in a relatively short time, due to the continuous growth of bones. The aim of this study was to verify the impact of the technology on biodegradability and to estimate the risk of inappropriate implant resorption time, which is an important aspect necessary to select prototypes of implants for in vivo testing. Prototypes of implants were made using two technologies: 3D printing using a PLDLA: poly(L-co-D,L lactide) (PLDLA) filament containing hydroxyapatite nanoparticles, and injection using PLDLA. After the radiation sterilization process, they were subjected to in vitro degradation under accelerated conditions. As part of this study, the in vitro degradation of newly developed biodegradable implant technologies was assessed in accordance with the guidelines of European standards. It was found that the implant manufacturing process had a significant impact on the degradation time under simulated conditions in various media. Implants made using the injection technique were characterized by lower susceptibility to degradation media compared to the 3D-printed implant under accelerated conditions. Full article
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18 pages, 8753 KiB  
Article
Alloying Effect on Transformation Strain and Martensitic Transformation Temperature of Ti-Based Alloys from Ab Initio Calculations
by Honglin Fang, Xingge Xu, Hualei Zhang, Qiaoyan Sun and Jun Sun
Materials 2023, 16(17), 6069; https://doi.org/10.3390/ma16176069 - 4 Sep 2023
Viewed by 1007
Abstract
The accurate prediction of alloying effects on the martensitic transition temperature (Ms) is still a big challenge. To investigate the composition-dependent lattice deformation strain and the Ms upon the β to α″ phase transition, we calculate the total [...] Read more.
The accurate prediction of alloying effects on the martensitic transition temperature (Ms) is still a big challenge. To investigate the composition-dependent lattice deformation strain and the Ms upon the β to α″ phase transition, we calculate the total energies and transformation strains for two selected Ti−Nb−Al and Ti−Nb−Ta ternaries employing a first-principles method. The adopted approach accurately estimates the alloying effect on lattice strain and the Ms by comparing it with the available measurements. The largest elongation and the largest compression due to the lattice strain occur along ±[011]β and ±[100]β, respectively. As compared to the overestimation of the Ms from existing empirical relationships, an improved Ms estimation can be realized using our proposed empirical relation by associating the measured Ms with the energy difference between the β and α″ phases. There is a satisfactory agreement between the predicted and measured Ms, implying that the proposed empirical relation could accurately describe the coupling alloying effect on Ms. Both Al and Ta strongly decrease the Ms, which is in line with the available observations. A correlation between the Ms and elastic modulus, C44, is found, implying that elastic moduli may be regarded as a prefactor of composition-dependent Ms. This work sheds deep light on precisely and directly predicting the Ms of Ti-containing alloys from the first-principles method. Full article
(This article belongs to the Special Issue Metallic Materials: Microstructure, Phase Equilibria and Thermodynamics)
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11 pages, 4490 KiB  
Article
Effects of Thermal-Strain-Induced Atomic Intermixing on the Interfacial and Photoluminescence Properties of InGaAs/AlGaAs Multiple Quantum Wells
by Zhi Yang, Shuai Zhang, Shufang Ma, Yu Shi, Qingming Liu, Xiaodong Hao, Lin Shang, Bin Han, Bocang Qiu and Bingshe Xu
Materials 2023, 16(17), 6068; https://doi.org/10.3390/ma16176068 - 4 Sep 2023
Cited by 1 | Viewed by 1262
Abstract
Quantum-well intermixing (QWI) technology is commonly considered as an effective methodology to tune the post-growth bandgap energy of semiconductor composites for electronic applications in diode lasers and photonic integrated devices. However, the specific influencing mechanism of the interfacial strain introduced by the dielectric-layer-modulated [...] Read more.
Quantum-well intermixing (QWI) technology is commonly considered as an effective methodology to tune the post-growth bandgap energy of semiconductor composites for electronic applications in diode lasers and photonic integrated devices. However, the specific influencing mechanism of the interfacial strain introduced by the dielectric-layer-modulated multiple quantum well (MQW) structures on the photoluminescence (PL) property and interfacial quality still remains unclear. Therefore, in the present study, different thicknesses of SiO2-layer samples were coated and then annealed under high temperature to introduce interfacial strain and enhance atomic interdiffusion at the barrier–well interfaces. Based on the optical and microstructural experimental test results, it was found that the SiO2 capping thickness played a positive role in driving the blueshift of the PL peak, leading to a widely tunable PL emission for post-growth MQWs. After annealing, the blueshift in the InGaAs/AlGaAs MQW structures was found to increase with increased thickness of the SiO2 layer, and the largest blueshift of 30 eV was obtained in the sample covered with a 600 nm thick SiO2 layer that was annealed at 850 °C for 180 s. Additionally, significant well-width fluctuations were observed at the MQW interface after intermixing, due to the interfacial strain introduced by the thermal mismatch between SiO2 and GaAs, which enhanced the inhomogeneous diffusion rate of interfacial atoms. Thus, it can be demonstrated that the introduction of appropriate interfacial strain in the QWI process is of great significance for the regulation of MQW band structure as well as the control of interfacial quality. Full article
(This article belongs to the Topic Electronic and Optical Properties of Nanostructures)
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16 pages, 6519 KiB  
Article
Effects of Recycled Polymer on Melt Viscosity and Crystallization Temperature of Polyester Elastomer Blends
by Ji-Eun Lee, Jin-Woo Lee, Jae-Wang Ko, Kyung-Il Jo, Hyun-Ju Park and Ildoo Chung
Materials 2023, 16(17), 6067; https://doi.org/10.3390/ma16176067 - 4 Sep 2023
Viewed by 1692
Abstract
As the world is paying attention to the seriousness of environmental pollution, the need for a resource circulation economy is emerging due to the development of eco-friendly industrial groups. In particular, the recycling of thermoplastic elastomers without cross-link has been highlighted in the [...] Read more.
As the world is paying attention to the seriousness of environmental pollution, the need for a resource circulation economy is emerging due to the development of eco-friendly industrial groups. In particular, the recycling of thermoplastic elastomers without cross-link has been highlighted in the plastics field, which has rapidly developed the industry. Growing interests have been directed towards the advancement of thermoplastic polyether–ester elastomer (TPEE) as a material suitable for the circular economy owing to its remarkable recyclability, both in terms of mechanical and chemical processes. Due to its excellent processability, simple mechanical recycling is easy, which is a driving force towards achieving price competitiveness in the process. In molding TPEE resin, it is essential to check the thermal properties of the resin itself because the thermal properties, including the melting and crystallization temperatures of the resin, depend on the design of the polymer. In this study, the thermal and mechanical performances of TPEE blends were evaluated by manufacturing compounds by changing the amount of recycled resin and additives. When the recycled resin was added, the melt flow index (MFI) changed rapidly as the temperature of the melt flow index measurement increased. Rapid changes in MFI make the fiber spinning process uncontrollable and must be controlled by optimizing the addition of compatibilizers. Based on the thermal property results, compatibilizers such as Lotader and Elvaloy series exhibited minimal change in glass transition temperature, even with greater amounts added. This makes them well-suited as compatibilizers for fiber spinning. Full article
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16 pages, 657 KiB  
Article
Effect of Coffee and Polishing Systems on the Color Change of a Conventional Resin Composite Repaired by Universal Resin Composites: An In Vitro Study
by Gözde Aksoy Vaizoğlu, Nuran Ulusoy and Laden Güleç Alagöz
Materials 2023, 16(17), 6066; https://doi.org/10.3390/ma16176066 - 4 Sep 2023
Cited by 4 | Viewed by 1378
Abstract
The purpose of this study was to evaluate the color stability of repaired aesthetic restorative resin matrix materials after immersion in coffee and the effect of polishing systems after staining. One hundred and eighty cylindrical discs (8 mm × 2 mm) were prepared [...] Read more.
The purpose of this study was to evaluate the color stability of repaired aesthetic restorative resin matrix materials after immersion in coffee and the effect of polishing systems after staining. One hundred and eighty cylindrical discs (8 mm × 2 mm) were prepared using a conventional nano-fill resin composite (Clearfil Majesty Esthetic A2 shade) with round cavities (3 × 1 mm). Cavities were repaired by three resin composite materials: Clearfil Majesty Esthetic A2 shade, one-shaded nano-fill resin composite (Omnichroma) and group-shaded nano-hybrid resin composite (Optishade, medium shade). Each group was polished with three polishing systems (n = 20); aluminum oxide (Soflex Spiral Wheels, 3M ESPE), silicon carbide (Occlubrush, Kerr, CA, USA) and diamond particulate (Twist Dia Spiral Wheels, Kuraray, Okayama, Japan). Color change (ΔE00) measurements were performed with a spectrophotometer at the baseline. Half of the polished samples were either kept in distilled water or immersed in coffee for 15 days, and color measurements were repeated before and after polishing. Statistical analysis was performed using the Kruskal–Wallis test. Repaired samples showed different color correspondence values in all groups. All three restorative materials showed significant color changes (ΔE00) after immersion in coffee (p ≤ 0.05). Repolishing of stained samples showed color improvement values in all groups. The content of the polishing system played an important role in removing the stains. Full article
(This article belongs to the Special Issue Multiphase Systems with Polymeric Matrices: Polymer Blends and Composites II)
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22 pages, 5224 KiB  
Article
Residual Properties of Geopolymer Concrete for Post-Fire Evaluation of Structures
by Balamurali Kanagaraj, Nammalvar Anand, Diana Andrushia and Venkatesh Kodur
Materials 2023, 16(17), 6065; https://doi.org/10.3390/ma16176065 - 4 Sep 2023
Cited by 2 | Viewed by 1049
Abstract
The research focuses on effectively utilizing industrial by-products, namely fly ash (FA) and ground granulated blast furnace slag (GGBS), to develop sustainable construction materials that can help reduce carbon emissions in the construction industry. Geopolymer mix design using these by-products is identified as [...] Read more.
The research focuses on effectively utilizing industrial by-products, namely fly ash (FA) and ground granulated blast furnace slag (GGBS), to develop sustainable construction materials that can help reduce carbon emissions in the construction industry. Geopolymer mix design using these by-products is identified as a potential solution. The study investigates the impact of different water to binder ratios (W/B) ranging from 0.4 to 0.6 on the residual properties, including compressive strength (CS), of geopolymer concrete (GPC), in accordance with Indian Standard for Alkali activated concrete. Lower W/B ratios were found to result in a more compact and less porous microstructure in the GPC. Additionally, the research explores the post-fire performance of GPC with varying grades (M10, M20, M30, & M40) and different W/B ratios, following the ISO 834 standard fire curve. It was observed that concrete samples exposed to elevated temperatures displayed a more porous microstructure. The mass loss of GPC with 0.4 W/B was found to be 2.3–5.9% and for 0.6 W/B ratio, the loss was found to be 3–6.5%, after exposing to 30-, 60-, 90-, and 120-min of heating. In the case of strength loss, for 0.4 W/B ratio, the loss was 36.81–77.09%, and for 0.6 W/B ratio the loss was 38.3–100%, after exposing to 30-, 60-, 90-, and 120-min of heating. Overall, the findings suggest that optimizing the W/B ratio in geopolymer concrete can enhance its compressive strength, as well as residual properties, and contribute to its suitability as a sustainable construction material. However, the response to elevated temperatures should also be considered to ensure its performance in fire scenarios. Full article
(This article belongs to the Special Issue Microstructural, Mechanical, and Durability Characteristics of Cementitious Materials)
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13 pages, 3090 KiB  
Article
Effect of Cs+ Doping on the Carrier Dynamics of MAPbI3 Perovskite
by Menghan Duan, Yunpeng Wang, Pingli Zhang and Luchao Du
Materials 2023, 16(17), 6064; https://doi.org/10.3390/ma16176064 - 4 Sep 2023
Viewed by 1555
Abstract
Organic inorganic perovskite materials have received increasing attention in the optoelectronic field because of their unique properties. The ultrafast dynamics of photogenerated carriers determine photoelectric conversion efficiency, thus, it is feasible to influence the dynamics behavior of photogenerated carriers by regulating A-site cations. [...] Read more.
Organic inorganic perovskite materials have received increasing attention in the optoelectronic field because of their unique properties. The ultrafast dynamics of photogenerated carriers determine photoelectric conversion efficiency, thus, it is feasible to influence the dynamics behavior of photogenerated carriers by regulating A-site cations. This paper mainly used transient absorption spectra (TAS) technology to study the photogenerated carriers relaxation processes of organic–inorganic perovskite CsxMA1−xPbI3 materials at different x values. Three sets of time constants were obtained by global fitting at different values of x. The experimental results showed that the crystal structure of perovskite could be affected by adjusting the Cs+ doping amount, thereby regulating the carrier dynamics. The appropriate amount of A-cation doping not only maintained the organic–inorganic perovskite crystal phase, but also prolonged the photogenerated carrier’s lifetime. The 10% Cs+ doping CsxMA1−xPbI3 perovskite has potential for solar cell applications. We hope that our research can provide dynamics support for the development of organic–inorganic perovskite in solar cells. Full article
(This article belongs to the Topic Optical and Optoelectronic Properties of Materials and Their Applications)
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34 pages, 8772 KiB  
Review
The Role of Lithium-Ion Batteries in the Growing Trend of Electric Vehicles
by Alessandro M. Ralls, Kaitlin Leong, Jennifer Clayton, Phillip Fuelling, Cody Mercer, Vincent Navarro and Pradeep L. Menezes
Materials 2023, 16(17), 6063; https://doi.org/10.3390/ma16176063 - 4 Sep 2023
Cited by 15 | Viewed by 3712
Abstract
Within the automotive field, there has been an increasing amount of global attention toward the usability of combustion-independent electric vehicles (EVs). Once considered an overly ambitious and costly venture, the popularity and practicality of EVs have been gradually increasing due to the usage [...] Read more.
Within the automotive field, there has been an increasing amount of global attention toward the usability of combustion-independent electric vehicles (EVs). Once considered an overly ambitious and costly venture, the popularity and practicality of EVs have been gradually increasing due to the usage of Li-ion batteries (LIBs). Although the topic of LIBs has been extensively covered, there has not yet been a review that covers the current advancements of LIBs from economic, industrial, and technical perspectives. Specific overviews on aspects such as international policy changes, the implementation of cloud-based systems with deep learning capabilities, and advanced EV-based LIB electrode materials are discussed. Recommendations to address the current challenges in the EV-based LIB market are discussed. Furthermore, suggestions for short-term, medium-term, and long-term goals that the LIB-EV industry should follow are provided to ensure its success in the near future. Based on this literature review, it can be suggested that EV-based LIBs will continue to be a hot topic in the years to come and that there is still a large amount of room for their overall advancement. Full article
(This article belongs to the Special Issue Advanced Lithium-Based Battery Materials for Electric Vehicles)
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11 pages, 8091 KiB  
Article
Process Optimization, Morphology, Structure, and Adhesive Strength of Electrodeposited Ni–Fe–Graphene Composite Coating on the 7075 Aluminum Alloy
by Na Li, Lan Zhang, Huizhong Ma, Qiao Li and Xingke Sun
Materials 2023, 16(17), 6062; https://doi.org/10.3390/ma16176062 - 4 Sep 2023
Cited by 1 | Viewed by 1050
Abstract
The process parameters of electrodeposited Ni–Fe–graphene composite coating on the 7075 aluminum alloy were optimized by the orthogonal experiment. The optimized process parameters were determined as follows: graphene concentration of 1 g L−1, current density of 9 A dm−2, [...] Read more.
The process parameters of electrodeposited Ni–Fe–graphene composite coating on the 7075 aluminum alloy were optimized by the orthogonal experiment. The optimized process parameters were determined as follows: graphene concentration of 1 g L−1, current density of 9 A dm−2, agitation speed of 250 r min−1, and temperature of 60 °C, on the basis of hardness and friction coefficient. The Ni–Fe–graphene composite coating shows an increment of 393.0% in hardness and a decrement of 55.9% in friction coefficient in comparison with 7075 aluminum alloy substrate. The Ni–Fe–graphene composite coating binds tightly to 7075 aluminum alloy with adhesion strength of higher than 6.895 MPa. These make contributions to provide effective protection for aluminum alloys. Surface morphology and corrosion morphology, as well as morphology of the side bound to the substrate, were characterized. The scattered asperities on the surface were proven to be graphene nanoplatelets being wrapped by Ni–Fe, which comprehensively reveals the formation of asperities. Full article
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12 pages, 4692 KiB  
Article
Synthesis and Characterization of a Novel Two-Dimensional Copper p-Aminophenol Metal–Organic Framework and Investigation of Its Tribological Properties
by Lei Li, Zhijun Liu, Chuan Li, Xiaodong Wang and Mingling Li
Materials 2023, 16(17), 6061; https://doi.org/10.3390/ma16176061 - 4 Sep 2023
Viewed by 1124
Abstract
Here, a novel copper p-aminophenol metal–organic framework (Cu(PAP)2) is first reported. Powder X-ray diffraction (PXRD), infrared spectra (FTIR), Raman spectra, transmission electron microscopy (TEM) and X-ray photoemission spectroscopy (XPS), in combination with a structure simulation, indicated that Cu(PAP)2 is a [...] Read more.
Here, a novel copper p-aminophenol metal–organic framework (Cu(PAP)2) is first reported. Powder X-ray diffraction (PXRD), infrared spectra (FTIR), Raman spectra, transmission electron microscopy (TEM) and X-ray photoemission spectroscopy (XPS), in combination with a structure simulation, indicated that Cu(PAP)2 is a two-dimensional (2D) material with a staggered structure analogous to that of graphite. Based on its 2D graphite-like layer structure, Cu(PAP)2 was expected to exhibit preferable tribological behaviors as an additive in liquid lubricants, and the tribological properties of Cu(PAP)2 as a lubricating additive in hydrogenated polydecene (PAO6) or deionized water were investigated. Compared to PAO6 or deionized water, the results indicated that deionized water-based Cu(PAP)2 showed much better friction reduction and anti-wear behavior than PAO6-based Cu(PAP)2 did, which was due to Cu(PAP)2 penetrating the interface between friction pairs in deionized water, but not in PAO6, thus producing lower friction and wear resistance values. Full article
(This article belongs to the Topic Advances and Applications of 2D Materials, 2nd Volume)
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8 pages, 3167 KiB  
Communication
Efficient CsPbBr3 Quantum-Dot Light-Emitting Diodes Using Sputtered NiO Films as Hole Injection Layers
by Pao-Hsun Huang, Sih-An Chen, Li-Wei Chao, Jia-Xun Xie, Ching-Yu Liao, Zong-Liang Tseng and Sheng-Hui Chen
Materials 2023, 16(17), 6060; https://doi.org/10.3390/ma16176060 - 4 Sep 2023
Cited by 3 | Viewed by 1136
Abstract
Perovskite quantum dots (QDs) have showed excellent optoelectronic properties to extend the application range of novel solid-state lighting, such as perovskite QD based LEDs (QD-LEDs). However, the traditional device structure of perovskite QD-LEDs employed PEDOT:PSS as a hole inject layer (HIL), which impairs [...] Read more.
Perovskite quantum dots (QDs) have showed excellent optoelectronic properties to extend the application range of novel solid-state lighting, such as perovskite QD based LEDs (QD-LEDs). However, the traditional device structure of perovskite QD-LEDs employed PEDOT:PSS as a hole inject layer (HIL), which impairs stability due to acidic surface characteristics. This study proposes the sputtered NiO films as an HIL to replace acidic PEDOT:PSS. The NiO films with significantly different characteristics were prepared by controlling the sputtering parameters to investigate the devices’ performance of NiO-based CsPbBr3 QD-LEDs. The optimized device showed an excellent performance with maxima luminescence of 20,118 cd/m2 and an external quantum efficiency (EQE) up to 3.63%. Full article
(This article belongs to the Special Issue Nanomaterials and Quantum Dots: Advancements in Photocatalysis and Optoelectronics)
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16 pages, 4524 KiB  
Article
Life Cycle Assessment of Raw and Fe-Modified Biochars: Contributing to Circular Economy
by Carolina Gallego-Ramírez, Edwin Chica and Ainhoa Rubio-Clemente
Materials 2023, 16(17), 6059; https://doi.org/10.3390/ma16176059 - 4 Sep 2023
Cited by 5 | Viewed by 1604
Abstract
Biochar is a carbonaceous material, which can be decorated with metals, that has been garnering attention to be used in the treatment of water due to its contribution to waste management and circular economy. This study presents the life cycle assessment (LCA) regarding [...] Read more.
Biochar is a carbonaceous material, which can be decorated with metals, that has been garnering attention to be used in the treatment of water due to its contribution to waste management and circular economy. This study presents the life cycle assessment (LCA) regarding the generation of Pinus patula raw biochar and its modification with iron (Fe-modified biochar). SimaPro 9.3.0.3 software was used to simulate the environmental impacts of both carbonaceous materials. The potential environmental effects obtained from the production of Pinus patula raw biochar were mainly ascribed to the source of energy utilized during this process. The potential impacts demonstrated that the generation of gases and polycyclic aromatic hydrocarbons are the main concern. In the case of Fe-modified biochar, the potential environmental effects differed only in the stage of the biomass modification with the metal. These effects are associated with the extraction of Fe and the generation of wastewater. These findings provide an insight into the environmental effects linked to the production of raw and Fe-modified biochar. However, further LCA research should be performed concerning other materials and compounds than can be generated during the biomass thermochemical conversion. Full article
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20 pages, 7925 KiB  
Article
Gray Model Study of Strength and Pore Structure of Recycled Concrete Powder (RCP) Concrete Based on Low-Field NMR Technology
by Yongli Hou, Zhengxing Yu, Jianhua Zhang, Hongrui Yang and Weiqing Song
Materials 2023, 16(17), 6058; https://doi.org/10.3390/ma16176058 - 4 Sep 2023
Cited by 2 | Viewed by 1386
Abstract
In order to improve the resource utilization of recycled concrete powder (RCP), this study aimed to investigate the effect of RCP admixture, curing age, and alkali excitation on the strength of RCP concrete. In addition, the pore structure characteristics of RCP concrete were [...] Read more.
In order to improve the resource utilization of recycled concrete powder (RCP), this study aimed to investigate the effect of RCP admixture, curing age, and alkali excitation on the strength of RCP concrete. In addition, the pore structure characteristics of RCP concrete were analyzed in combination with low-field NMR. Furthermore, a gray predictive GM (1, 4) model was established to predict the mechanical properties of the concrete based on the pore structure parameters, especially the compressive and flexural tensile strengths. The results of the study indicate that the mechanical properties, namely compressive strength and flexural strength, of RCP concrete exhibit an initial increase followed by a subsequent decrease with increasing RCP content at 3 d, 7 d, and 28 d curing ages. In particular, the concrete exhibits the highest mechanical properties when the RCP content reaches 10%. As the curing age increases, the RCP gradually achieves full hydration, resulting in further refinement of the concrete pores and a denser structure, which subsequently improves the mechanical properties. In addition, the strength growth rate of alkali-excited recycled concrete (ARC) showed a continuous increase, indicating that alkali excitation increasingly improved the mechanical properties of the concrete. Furthermore, the study accurately predicted the mechanical properties of RCP concrete by using GM (1, 4) prediction models for its compressive strength and flexural tensile strength using pore characteristic parameters. Full article
(This article belongs to the Special Issue Advances in the Mechanical Properties of Cements, Mortars and Concretes)
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14 pages, 3648 KiB  
Article
Sorption Capacity of AlOOH/FeAl2 Composites towards As(V)
by Sergey O. Kazantsev, Konstantin V. Suliz, Nikolay G. Rodkevich and Aleksandr S. Lozhkomoev
Materials 2023, 16(17), 6057; https://doi.org/10.3390/ma16176057 - 4 Sep 2023
Cited by 1 | Viewed by 1223
Abstract
The treatment of wastewater from arsenic compounds is an important and urgent problem. Composite nanostructures consisting of boehmite and iron compounds have a high adsorption capacity towards As(V) specie. In this work, the adsorption properties of nanostructured composites prepared by the oxidation of [...] Read more.
The treatment of wastewater from arsenic compounds is an important and urgent problem. Composite nanostructures consisting of boehmite and iron compounds have a high adsorption capacity towards As(V) specie. In this work, the adsorption properties of nanostructured composites prepared by the oxidation of bimetallic Al/Fe nanoparticles with different iron contents were investigated. As a result of oxidation, boehmite AlOOH nanosheets are formed, with the resultant FeAl2 nanoparticles being distributed on the surface of boehmite nanosheets. The nanostructured composites prepared from Al/Fe nanoparticles containing 20 wt% Fe have been found to show the highest adsorption capacity towards As(V) specie, being 248 mg/g. The adsorption isotherms are most accurately described by the Freundlich model, with the arsenic adsorption process obeying pseudo second order kinetics. As a result of the study, the optimal ratio of Al and Fe in Al/Fe nanoparticles has been determined to obtain an AlOOH/FeAl2 composite adsorbent with a developed and accessible surface and a high sorption capacity towards As(V). This allows us to consider this material as a promising adsorbent for the removal of arsenic compounds from water. Full article
(This article belongs to the Special Issue Materials for Heavy Metals Removal from Waters)
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15 pages, 2309 KiB  
Article
Large Amplitude Vibration of FG-GPL Reinforced Conical Shell Panels on Elastic Foundation
by Jin-Rae Cho
Materials 2023, 16(17), 6056; https://doi.org/10.3390/ma16176056 - 3 Sep 2023
Cited by 5 | Viewed by 1115
Abstract
Functionally graded (FG) composite structures reinforced by graphene platelets (GPL) have been widely adopted as a state-of-the-art structural element due to their preeminent properties and functional designability. However, most studies are confined to beams, plates, and cylindrical panels, relying on the numerical differential [...] Read more.
Functionally graded (FG) composite structures reinforced by graphene platelets (GPL) have been widely adopted as a state-of-the-art structural element due to their preeminent properties and functional designability. However, most studies are confined to beams, plates, and cylindrical panels, relying on the numerical differential quadrature method (DQM) and the finite element numerical method. In this context, the current study intends to investigate the nonlinear free vibration of FG-GPL-reinforced composite (RC) conical panels resting on an elastic medium by developing a 2-D planar meshfree method-based nonlinear numerical method. The nonlinear free vibration problem is expressed by the first-order shell deformation theory and the von-Kármán nonlinearity. The complex conical neutral surface of the panel is transformed into a 2-D rectangular plane to avoid painstaking mathematical manipulation. The troublesome shear-membrane locking is suppressed by employing the MITC3+shell element, and the derived nonlinear modal equations are solved by introducing a three-step direct iterative scheme. The present method is compared with the DQM through the benchmark experiment, from which a good agreement between the two methods is observed. And, the nonlinear free vibration characteristics of FG-GPLRC conical panels on an elastic foundation are profoundly investigated, and it is found that those are significantly influenced by the foundation stiffness, the amount and dispersion pattern of GPLs, the panel geometry sizes, and the boundary condition. Full article
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12 pages, 6879 KiB  
Article
Effect of Surface Treatments with Low-Pressure Plasma on the Adhesion of Zirconia
by Pablo Sevilla, Mustafa Gseibat, Jesús Peláez, María J. Suárez and Carlos López-Suárez
Materials 2023, 16(17), 6055; https://doi.org/10.3390/ma16176055 - 3 Sep 2023
Cited by 3 | Viewed by 1309
Abstract
The purpose of this study was to investigate the effect of low-pressure plasma on the contact angle, shear bond strength (SBS), and the failure mode of zirconia ceramic. Zirconia specimens were divided into three groups according to the surface treatment methods as follows: [...] Read more.
The purpose of this study was to investigate the effect of low-pressure plasma on the contact angle, shear bond strength (SBS), and the failure mode of zirconia ceramic. Zirconia specimens were divided into three groups according to the surface treatment methods as follows: sandblasting with aluminum oxide (ZR-C), sandblasting with aluminum oxide and oxygen plasma (ZR-CP), and argon plasma (ZR-P). The contact angle, SBS, and surface characteristics were tested after thermocycling. Data analysis was made using the Kruskal–Wallis test and one-way analysis of variance. Plasma treatment significantly reduced the contact angle (p < 0.001) with the lowest value for the Zr-P group. An increase in oxygen and a decrease in carbon was observed on the zirconia surface in both plasma groups. For the SBS, there were significant differences among the groups (p < 0.018), the Zr-CP group showing the highest bond strength. Mixed failures were the most frequent. Plasma treatment was effective in increasing the wettability, increasing the oxygen/carbon ratio without changing zirconia surface morphology. The sandblasting plus plasma with oxygen group exhibited the highest bond strength. Full article
(This article belongs to the Special Issue Prospects for Dental Materials in Prosthodontics)
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21 pages, 14487 KiB  
Article
Eco-Friendly Coal Gangue and/or Metakaolin-Based Lightweight Geopolymer with the Addition of Waste Glass
by Celina Ziejewska, Agnieszka Bąk, Krzysztof Hodor and Marek Hebda
Materials 2023, 16(17), 6054; https://doi.org/10.3390/ma16176054 - 3 Sep 2023
Cited by 2 | Viewed by 1423
Abstract
Massive amounts of deposited coal gangue derived from the mining industry constitute a crucial problem that must be solved. On the other hand, common knowledge about the recycling of glass products and the reuse of waste glass is still insufficient, which in turn [...] Read more.
Massive amounts of deposited coal gangue derived from the mining industry constitute a crucial problem that must be solved. On the other hand, common knowledge about the recycling of glass products and the reuse of waste glass is still insufficient, which in turn causes economic and environmental problems. Therefore, this work investigated lightweight geopolymer foams manufactured based on coal gangue, metakaolin, and a mix of them to evaluate the influence of such waste on the geopolymer matrix. In addition, the effect of 20% (wt.) of waste glass on the foams was determined. Mineralogical and chemical composition, thermal behaviour, thermal conductivity, compressive strength, morphology, and density of foams were investigated. Furthermore, the structure of the geopolymers was examined in detail, including pore and structure thickness, homogeneity, degree of anisotropy, porosity with division for closed and open pores, as well as distribution of additives and pores using micro-computed tomography (microCT). The results show that the incorporation of waste glass increased compressive strength by approximately 54% and 9% in the case of coal-gangue-based and metakaolin-based samples, respectively. The porosity of samples ranged from 67.3% to 58.7%, in which closed pores constituted 0.3–1.8%. Samples had homogeneous distributions of pores and additions. Furthermore, the thermal conductivity ranged from 0.080 W/(m·K) to 0.117 W/(m·K), whereas the degree of anisotropy was 0.126–0.187, indicating that the structure of foams was approximate to isotropic. Full article
(This article belongs to the Special Issue Geopolymers in Construction Industry)
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15 pages, 4464 KiB  
Article
Analysis of Weld Lines in Micro-Injection Molding
by Sara Liparoti, Giorgia De Piano, Rita Salomone and Roberto Pantani
Materials 2023, 16(17), 6053; https://doi.org/10.3390/ma16176053 - 3 Sep 2023
Cited by 3 | Viewed by 1231
Abstract
Micro-injection molding (µIM) is a widespread process for the production of plastic parts with at least one dimension, or feature, in the microscale (conventionally below 500 µm). Despite injection molding being recognized as a robust process for obtaining parts with high geometry accuracy, [...] Read more.
Micro-injection molding (µIM) is a widespread process for the production of plastic parts with at least one dimension, or feature, in the microscale (conventionally below 500 µm). Despite injection molding being recognized as a robust process for obtaining parts with high geometry accuracy, one last occurrence remains a challenge in micro-injection molding, especially when junctions are present on the parts: the so-called weld lines. As weld lines are crucial in determining mechanical part performances, it is mandatory to clarify weld line position and characteristics, especially at the industrial scale during mold design, to limit failure causes. Many works deal with weld lines and their dependence on processing parameters for conventional injection molding, but only a few works focus on the weld line in µIM. This work examines the influence of mold temperature on the weld line position and strength by both experimental and simulation approaches in µIM. At mold temperatures below 100 °C, only short shots were obtained in the chosen cavity. At increased mold temperatures, weld lines show up to a 40% decrease in the whole length, and the overall tensile modulus doubles. This finding can be attributed to the reduction of the orientation at the weld line location favored by high mold temperatures. Moldflow simulations consistently reproduce the main features of the process, weld line position and length. The discrepancy between experimental and simulated results was attributed to the fact that crystallization in flow conditions was not accounted for in the model. Full article
(This article belongs to the Section Polymeric Materials)
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20 pages, 3940 KiB  
Article
Effect of Variable Synthesis Conditions on the Formation of Ye’elimite-Aluminate-Calcium (YAC) Cement and Its Hydration in the Presence of Portland Cement (OPC) and Several Accessory Additives
by Karol Durczak, Michał Pyzalski, Tomasz Brylewski and Agnieszka Sujak
Materials 2023, 16(17), 6052; https://doi.org/10.3390/ma16176052 - 3 Sep 2023
Cited by 5 | Viewed by 1142
Abstract
In the presented study, ye’elimite-aluminate-calcium (YAC) cement was synthesized. Complete synthesis of crystalline phases was achieved at a temperature of 1300 °C, which is 150 °C lower than the temperature standardly used in the processes of obtaining calcium aluminate cements (CAC). The greatest [...] Read more.
In the presented study, ye’elimite-aluminate-calcium (YAC) cement was synthesized. Complete synthesis of crystalline phases was achieved at a temperature of 1300 °C, which is 150 °C lower than the temperature standardly used in the processes of obtaining calcium aluminate cements (CAC). The greatest amount of ye’elimite phase (Klein complex), roughly 87% by mass, was acquired utilizing a sulphur ion transporter derived from artificial dihydrate gypsum obtained in the flue gas desulphurization process (variation I). In the case of anhydrite, the amount of synthesized crystalline ye’elimite in the clinker was 67% by weight (variant II). Depending on the synthesis conditions in the clinkers, the quantity of obtained calcium aluminates (C12A7, CA, and CA2) ranged from 20 to 40% by weight. Studies on the hydration process of YAC cement samples showed that the main products are hydrated calcium aluminates and dodecahydrate calcium alumino-sulphate. In sinters of YAC and OPC, no crystalline ettringite was observed. Hydration analysis of Chinese cement revealed the presence of crystalline ettringite and dodecahydrate calcium alumino-sulphate, as well as hydrated calcium silicates of the CSH type accompanied with pseudo-crystalline Al(OH)3. The obtained clinkers from variants I and II constitute a special binder, which, due to its phase composition after hydration, can be used in the construction of reactors for biogas production in eco-energy applications. Full article
(This article belongs to the Section Construction and Building Materials)
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25 pages, 5237 KiB  
Review
Cellular Automata Modeling as a Tool in Corrosion Management
by Juan C. Reinoso-Burrows, Norman Toro, Marcelo Cortés-Carmona, Fabiola Pineda, Mauro Henriquez and Felipe M. Galleguillos Madrid
Materials 2023, 16(17), 6051; https://doi.org/10.3390/ma16176051 - 3 Sep 2023
Cited by 2 | Viewed by 1807
Abstract
Cellular automata models have emerged as a valuable tool in corrosion management. This manuscript provides an overview of the application of cellular automata models in corrosion research, highlighting their benefits and contributions to understanding the complex nature of corrosion processes. Cellular automata models [...] Read more.
Cellular automata models have emerged as a valuable tool in corrosion management. This manuscript provides an overview of the application of cellular automata models in corrosion research, highlighting their benefits and contributions to understanding the complex nature of corrosion processes. Cellular automata models offer a computational approach to simulating corrosion behavior at the microscale, capturing the intricate interactions between electrochemical reactions, material properties, and environmental factors and generating a new vision of predictive maintenance. It reviews the key features of cellular automata, such as the grid-based representation of the material surface, the definition of state variables, and the rules governing cell-state transitions. The ability to model local interactions and emergent global behavior makes cellular automata particularly suitable for simulating corrosion processes. Finally, cellular automata models offer a powerful and versatile approach to studying corrosion processes, expanding models that can continue to enhance our understanding of corrosion and contribute to the development of effective corrosion prevention and control strategies. Full article
(This article belongs to the Topic Energy and Metals Recovery with Associated Corrosion Issues)
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25 pages, 8685 KiB  
Review
Predictive Modeling of Molecular Mechanisms in Hydrogen Production and Storage Materials
by Tanumoy Banerjee and Ganesh Balasubramanian
Materials 2023, 16(17), 6050; https://doi.org/10.3390/ma16176050 - 3 Sep 2023
Cited by 1 | Viewed by 1647
Abstract
Hydrogen has been widely considered to hold promise for solving challenges associated with the increasing demand for green energy. While many chemical and biochemical processes produce molecular hydrogen as byproducts, electrochemical approaches using water electrolysis are considered to be a predominant method for [...] Read more.
Hydrogen has been widely considered to hold promise for solving challenges associated with the increasing demand for green energy. While many chemical and biochemical processes produce molecular hydrogen as byproducts, electrochemical approaches using water electrolysis are considered to be a predominant method for clean and green hydrogen production. We discuss the current state-of-the-art in molecular hydrogen production and storage and, more significantly, the increasing role of computational modeling in predictively designing and deriving insights for enhancing hydrogen storage efficiency in current and future materials of interest. One of the key takeaways of this review lies in the continued development and implementation of large-scale atomistic simulations to enable the use of designer electrolyzer–electrocatalysts operating under targeted thermophysical conditions for increasing green hydrogen production and improving hydrogen storage in advanced materials, with limited tradeoffs for storage efficiency. Full article
(This article belongs to the Special Issue Advance Materials for Hydrogen Storage)
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18 pages, 6286 KiB  
Article
Preparation of High-Ductility Cement-Calcined Coal-Gangue-Powder-Composite-Based Rapid Repair Material
by Biaokun Ren, Lijuan Chai, Yuanzhen Liu and Yangkai Wang
Materials 2023, 16(17), 6049; https://doi.org/10.3390/ma16176049 - 3 Sep 2023
Cited by 6 | Viewed by 1073
Abstract
Coal gangue is a kind of solid waste. A high-ductility cement-calcined coal-gangue-powder-composite-based rapid repair material (HD-RRM) was prepared by partially replacing cement with calcined coal gangue powder (CCGP) for achieving high ductility and rapid hardening and conforming to the strength requirements of pavement [...] Read more.
Coal gangue is a kind of solid waste. A high-ductility cement-calcined coal-gangue-powder-composite-based rapid repair material (HD-RRM) was prepared by partially replacing cement with calcined coal gangue powder (CCGP) for achieving high ductility and rapid hardening and conforming to the strength requirements of pavement layers. First, the physical and chemical properties and the reactivity of the CCGP were investigated. Second, HD-RRM material was prepared, and its tensile performance characteristic parameters were investigated. Lastly, the hydration products and microstructure of HD-RRM were characterized through tests (e.g., non-evaporable water content, scanning electron microscopy (SEM), X-ray diffraction (XRD), and comprehensive thermogravimetric analysis and differential scanning calorimetry (TG-DSC)). As indicated by the experimental results, the CCGP with a particle size of 1250 mesh exhibited the maximum potential reactivity. The optimal mixing ratio for HD-RRM in the experiments comprised a water–cement ratio of 0.27, a sand–cement ratio of 0.3, a fiber volume fraction of 2%, a cement content of 70%, a CCGP content of 20%, a fly ash (FA) content of 10%, and a superplasticizer content of 0.1%. Using the abovementioned mix design, the prepared HD-RRM was endowed with a 6 h ultimate elongation of 2.75%, an ultimate tensile strength of 7.58 MPa, a compressive strength of 45.4 MPa, and an average crack width of 125.53 μm, which meets the requirements of repair materials and provides a design method for CCGP resource utilization and asphalt concrete road and bridge deck repair. Full article
(This article belongs to the Section Construction and Building Materials)
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13 pages, 799 KiB  
Article
Numerical Simulation of PFRC Fracture Subjected to High Temperature by Means of a Trilinear Softening Diagram
by Fernando Suárez, Alejandro Enfedaque, Marcos G. Alberti and Jaime C. Gálvez
Materials 2023, 16(17), 6048; https://doi.org/10.3390/ma16176048 - 3 Sep 2023
Viewed by 936
Abstract
Fibre-reinforced concrete (FRC) has been used for decades in certain applications in the construction industry, such as tunnel linings and precast elements, but has experienced important progress in recent times, boosted by the inclusion of guidelines for its use in some national and [...] Read more.
Fibre-reinforced concrete (FRC) has been used for decades in certain applications in the construction industry, such as tunnel linings and precast elements, but has experienced important progress in recent times, boosted by the inclusion of guidelines for its use in some national and international standards. Traditional steel fibres have been studied in depth and their performance is well-known, although in recent years new materials have been proposed as possible alternatives. Polyolefin macro-fibres, for instance, have been proven to enhance the mechanical properties of concrete and the parameters that define their behaviour (fibre length, fibre proportion or casting method, for instance) have been identified. These fibres overcome certain traditional problems related to steel fibres, such as corrosion or their interaction with magnetic fields, which can limit the use of steel in some applications. The behaviour of polyolefin fibre-reinforced concrete (PFRC) has been numerically reproduced with success through an embedded cohesive crack formulation that uses a trilinear softening diagram to describe the fracture behaviour of the material. Furthermore, concrete behaves well under high temperatures or fire events, especially when it is compared with other construction materials, but the behaviour of PFRC must be analysed if the use of these fibres is to be extended. To this end, the degradation of PFRC fracture properties has been recently experimentally analysed under a temperature range between 20 °C and 200 °C. As temperature increases, polyolefin fibres modify their mechanical properties and their shape, which reduce their performance as reinforcements of concrete. In this work, those experimental results, which include results of low (3 kg/m3) and high (10 kg/m3) proportion PFRC specimens, are used as reference to study the fracture behaviour of PFRC exposed to high temperatures from a numerical point of view. The experimental load-deflection diagrams are reproduced by modifying the trilinear diagram used in the cohesive model, which helps to understand how the trilinear diagram parameters are affected by high temperature exposure. Finally, some expressions are proposed to adapt the initial trilinear diagram (obtained with specimens not exposed to high temperature) in order to numerically reproduce the fracture behaviour of PFRC affected by high temperature exposure. Full article
(This article belongs to the Section Materials Simulation and Design)
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13 pages, 4945 KiB  
Article
Investigation of the Pozzolanic Activity Improvement of Yellow Phosphorus Slag with Thermal Activation
by Xinyue Liu, Xiaoming Liu, Zengqi Zhang, Chao Wei, Qingsen Zeng, Yantian Li and Shanliang Ma
Materials 2023, 16(17), 6047; https://doi.org/10.3390/ma16176047 - 3 Sep 2023
Cited by 2 | Viewed by 1100
Abstract
Yellow phosphorus slag (YPS) is a byproduct from the production of yellow phosphorus. It has potential pozzolanic activity and can be used as a supplementary cementitious material. However, the early strength of cement mortar decreases significantly with increasing YPS dosage, which restricts the [...] Read more.
Yellow phosphorus slag (YPS) is a byproduct from the production of yellow phosphorus. It has potential pozzolanic activity and can be used as a supplementary cementitious material. However, the early strength of cement mortar decreases significantly with increasing YPS dosage, which restricts the utilization of YPS in cement and concrete. This study aimed to increase the pozzolanic activity of YPS ash by thermal activation. The strength method, alkali dissolution method and polymerization degree method were used to evaluate the effect of thermal activation at different temperatures on the pozzolanic activity of YPS ash. The results showed that YPS ash calcined at 800 °C helps to enhance the early strength because the fluorine in cuspidine (Ca4Si2O7F2) is insoluble, reducing the retarding effect on the mortar. The higher late strength of YPS ash calcined at 100 °C was due to the low polymerization degree of [SiO4]. The pozzolanic activity of YPS ash is positively correlated with the dissolution concentration of (Si + Al) and the compressive strength and negatively associated with the polymerization degree. This paper shows a possibility for the large-scale utilization of YPS. Full article
(This article belongs to the Special Issue Sustainable Materials for Engineering Applications)
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45 pages, 8163 KiB  
Review
Recent Advances and Outlook in 2D Nanomaterial-Based Flame-Retardant PLA Materials
by Lesego Tabea Temane, Jonathan Tersur Orasugh and Suprakas Sinha Ray
Materials 2023, 16(17), 6046; https://doi.org/10.3390/ma16176046 - 2 Sep 2023
Cited by 4 | Viewed by 2227
Abstract
Poly (lactic acid) or polylactide (PLA) has gained widespread use in many industries and has become a commodity polymer. Its potential as a perfect replacement for petrochemically made plastics has been constrained by its extreme flammability and propensity to flow in a fire. [...] Read more.
Poly (lactic acid) or polylactide (PLA) has gained widespread use in many industries and has become a commodity polymer. Its potential as a perfect replacement for petrochemically made plastics has been constrained by its extreme flammability and propensity to flow in a fire. Traditional flame-retardants (FRs), such as organo-halogen chemicals, can be added to PLA without significantly affecting the material’s mechanical properties. However, the restricted usage of these substances causes them to bioaccumulate and endanger plants and animals. Research on PLA flame-retardants has mostly concentrated on organic and inorganic substances for the past few years. Meanwhile, there has been a significant increase in renewed interest in creating environmentally acceptable flame-retardants for PLA to maintain the integrity of the polymer, which is the current trend. This article reviews recent advancements in novel FRs for PLA. The emphasis is on two-dimensional (2D) nanosystems and the composites made from them that have been used to develop PLA nanocomposite (NCP) systems that are flame retarding. The association between FR loadings and efficiency for different FR-PLA systems is also briefly discussed in the paper, as well as their influence on processing and other material attributes. It is unmistakably established from the literature that adding 2D nanoparticles to PLA matrix systems reduces their flammability by forming an intumescent char/carbonized surface layer. This creates a barrier effect that successfully blocks the filtration of volatiles and oxygen, heat and mass transfer, and the release of combustible gases produced during combustion. Full article
(This article belongs to the Special Issue Recent Advances in Composites of Polymers with Graphene and Carbon Nanotubes)
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23 pages, 5465 KiB  
Article
Organosilicon Self-Assembled Surface Nanolayers on Zinc—Formation and Their Influence on the Electrochemical and Corrosion Zinc Ongoing
by Maxim Petrunin, Liudmila Maksaeva and Tatyana Yurasova
Materials 2023, 16(17), 6045; https://doi.org/10.3390/ma16176045 - 2 Sep 2023
Cited by 1 | Viewed by 1110
Abstract
The adsorption of vinyltrimethoxysilane (VS) on the surface of sputtered (by thermal spraying in vacuum) zinc has been investigated. The adsorption isotherms of VC on zinc from an aqueous solution were obtain. In order to determine the adsorption characteristics of VS molecules and [...] Read more.
The adsorption of vinyltrimethoxysilane (VS) on the surface of sputtered (by thermal spraying in vacuum) zinc has been investigated. The adsorption isotherms of VC on zinc from an aqueous solution were obtain. In order to determine the adsorption characteristics of VS molecules and to calculate the heats of adsorption, the obtained adsorption isotherms were mathematically processed in terms of the well-known adsorption approaches (approximations, adsorption isotherms). It has been established that this organosilane was chemisorbed on the surface of freshly deposited zinc after 60 min. After the sample was immersed in the solution, a self-organized organosilicon layer was formed on the metal surface. The application of Fourier transform infrared spectroscopy, atomic-force microscopy, and scanning electron microscopy allowed to us study in detail the interactions between VS molecules and the metal surface and to determine the structural features of the formed surface films. The mechanism of formation of self-assembled surface layers on zinc has been proposed. Electrochemical and corrosion research methods have been used to investigate the anticorrosion characteristics of organosilicon films on zinc. High stability of surface organosilicone layers with respect to the corrosive components of electrolyte action was shown by an infrared spectroscopy study carried out after corrosion tests Full article
(This article belongs to the Special Issue Metallic and Ceramic Materials Integrity – Surface Engineering for Wear, Corrosion and Erosion Prevention)
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12 pages, 625 KiB  
Article
Distribution of Electron Density in Self-Assembled One-Dimensional Chains of Si Atoms
by Mieczysław Jałochowski and Tomasz Kwapiński
Materials 2023, 16(17), 6044; https://doi.org/10.3390/ma16176044 - 2 Sep 2023
Cited by 1 | Viewed by 1242
Abstract
Scanning tunneling microscopy measurements of height profiles, along the chains of Si atoms on the terrace edges of a perfectly ordered Si(553)-Au surface, reveal an STM bias-dependent mixed periodicity with periods of one, two and one and a half lattice constants. The simple [...] Read more.
Scanning tunneling microscopy measurements of height profiles, along the chains of Si atoms on the terrace edges of a perfectly ordered Si(553)-Au surface, reveal an STM bias-dependent mixed periodicity with periods of one, two and one and a half lattice constants. The simple linear chain model usually observed with STM cannot explain the unexpected fractional periodicity in the height profile. It was found that the edge Si chain stands for, in fact, a zigzag structure, which is composed of two neighboring rows of Si atoms and was detected in the STM experiments. Tight-binding calculations of the local density of states and charge occupancy along the chain explain the voltage-dependent modulations of the STM profiles and show that oscillation periods are determined mainly by the surface and STM tip Fermi energies. Full article
(This article belongs to the Special Issue Low-Dimensional Materials for Quantum Science and Technology)
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18 pages, 4697 KiB  
Article
Bioconsolidation of Damaged Construction Calcarenites and Evaluation of the Improvement in Their Petrophysical and Mechanical Properties
by Yolanda Spairani-Berrio, J. Antonio Huesca-Tortosa, Carlos Rodriguez-Navarro, María Teresa Gonzalez-Muñoz and Fadwa Jroundi
Materials 2023, 16(17), 6043; https://doi.org/10.3390/ma16176043 - 2 Sep 2023
Cited by 1 | Viewed by 1498
Abstract
Bioconsolidation treatment using bacterial carbonatogenesis has been proposed as an environmentally friendly strategy for the efficient preservation of damaged stones, particularly suitable for carbonate stones. The study presented here deals with the evaluation of the performance of this treatment, applied to damaged carbonate [...] Read more.
Bioconsolidation treatment using bacterial carbonatogenesis has been proposed as an environmentally friendly strategy for the efficient preservation of damaged stones, particularly suitable for carbonate stones. The study presented here deals with the evaluation of the performance of this treatment, applied to damaged carbonate stones in two historical buildings in Spain. The methodology applied in this research serves as a reference for future similar studies. Results showed significant improvement in the petrophysical and mechanical properties of the damaged stone following the treatment through the production of calcite and vaterite by the abundant carbonatogenic bacteria inhabiting the stone. These bacteria were able to effectively consolidate weathered areas if an adequate nutritional solution was employed, thereby augmenting the stone’s resistance, as evidenced by the Drilling Resistance Measurement System (DRMS). FESEM images showed calcified bacteria and calcified exopolymeric substances (EPS) consolidating stone minerals without blocking their pores. In addition to consolidation, this biotreatment improves the stone’s behavior against water absorption and increases the contact angle of water droplets without significant modifications in the pore size or diminishing vapor permeability. No color changes are observed. Overall, these results show that the application of the nutritional solution (M-3P) for in situ consolidation of different types of porous carbonate building stones is a highly effective conservation method, with no modification of the chemical composition of the treated materials. Full article
(This article belongs to the Special Issue Repair, Reinforcement, Conservation of Existing Building Stock: Materials, Methods and Assessment)
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12 pages, 4465 KiB  
Article
Synthesis and Characterization of Agarose Hydrogels for Release of Diclofenac Sodium
by Anna Jarosz, Oliwia Kapusta, Dorota Gugała-Fekner and Mariusz Barczak
Materials 2023, 16(17), 6042; https://doi.org/10.3390/ma16176042 - 2 Sep 2023
Cited by 2 | Viewed by 1242
Abstract
Hydrogels are attractive biomaterials for the controlled release of various pharmaceuticals, due to their ability to embed biologically active moieties in a 3D polymer network. Among them, agarose-based hydrogels are an interesting, but still not fully explored, group of potential platforms for controlled [...] Read more.
Hydrogels are attractive biomaterials for the controlled release of various pharmaceuticals, due to their ability to embed biologically active moieties in a 3D polymer network. Among them, agarose-based hydrogels are an interesting, but still not fully explored, group of potential platforms for controlled drug release. In this work, agarose hydrogels with various contents of citric acid were prepared, and their mechanical and physicochemical properties were investigated using various instrumental techniques, such as rheological measurements, attenuated total reflection–Fourier transform infrared spectroscopy (ATR-FTIR). Releasing tests for diclofenac sodium (DICL) were run in various environments; water, PBS, and 0.01 M NaOH; which remarkably affected the profile of the controlled release of this model drug. In addition to affecting the mechanical properties, the amount of citric acid incorporated within a hydrogel network during synthesis was also of great importance to the rate of DICL release. Therefore, due to their high biocompatibility, agarose hydrogels can be regarded as safe and potential platforms for controlled drug release in biomedical applications. Full article
(This article belongs to the Special Issue Synthesis and Characterization of Hydrogels)
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