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Materials, Volume 13, Issue 4

2020 February-2 - 213 articles

Cover Story: Poly(L-lactide-co-glycolide)-block-poly (ethylene oxide) copolymer modified by blending with grafted dextrin or maltodextrin demonstrate very useful feature of this material as a biodegradable polymeric matrix for controlled release system of herbicides. The modification PLAGA/PEG copolymer by blending with modified dextrin affects the improvement of the release profile of active agent via enhancement of susceptibility of polymeric carrier to enzymatic degradation. This type of degradation allowed for the leaching of tested herbicides into the soil within few months which is very required from agrochemical and environmental protection point of view, because active substances are released through the whole vegetation period of cultivated plants. View this paper.
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Articles (213)

  • Feature Paper
  • Article
  • Open Access
22 Citations
5,687 Views
19 Pages

A Modular Millifluidic Platform for the Synthesis of Iron Oxide Nanoparticles with Control over Dissolved Gas and Flow Configuration

  • Luca Panariello,
  • Gaowei Wu,
  • Maximilian O. Besenhard,
  • Katerina Loizou,
  • Liudmyla Storozhuk,
  • Nguyen Thi Kim Thanh and
  • Asterios Gavriilidis

25 February 2020

Gas–liquid reactions are poorly explored in the context of nanomaterials synthesis, despite evidence of significant effects of dissolved gas on nanoparticle properties. This applies to the aqueous synthesis of iron oxide nanoparticles, where ga...

  • Article
  • Open Access
4 Citations
3,187 Views
8 Pages

24 February 2020

In an abruptly changing velocity under directional solidification, microstructures and the growth orientation of Al-Al2Cu eutectic lamellar were characterized. The change in solidification rate led to an interfacial instability, which results in a bi...

  • Article
  • Open Access
6 Citations
3,437 Views
8 Pages

24 February 2020

The nanoscale plasticity phenomena in zirconia-toughened alumina (ZTA) ceramics with yttria-stabilized zirconia (YSZ) addition of 10% and 30% fabricated by additive manufacturing based on a stereolithography technique were explored in detail by nanoi...

  • Article
  • Open Access
49 Citations
6,552 Views
16 Pages

Three-Dimensional Evaluation of Maxillary Sinus Changes in Growing Subjects: A Retrospective Cross-Sectional Study

  • Cinzia Maspero,
  • Marco Farronato,
  • Francesca Bellincioni,
  • Alessandro Annibale,
  • Jacopo Machetti,
  • Andrea Abate and
  • Davide Cavagnetto

24 February 2020

This study aims to evaluate changes of maxillary sinuses in growing subjects. Cone Beam Computed Tomography (CBCT) scans of 146 patients were divided according to gender and age (6–8, 9–11, 12–14 years old). Left, right and total ma...

  • Article
  • Open Access
45 Citations
7,845 Views
13 Pages

24 February 2020

In order to enhance the mechanical property of auxetic lattice structures, a new enhanced auxetic lattice structure was designed by embedding narrow struts into a three-dimensional (3D) re-entrant lattice structure. A series of enhanced lattice struc...

  • Communication
  • Open Access
15 Citations
3,968 Views
10 Pages

The Preparation and Properties of a Shell Structure Ceramsite

  • Wukui Zheng,
  • Diyang He,
  • Hui Li,
  • Fei Wang,
  • Yuxuan Yang and
  • Jingjie Zhang

24 February 2020

In this paper, a shell structure ceramsite has been prepared and researched in order to attempt a new method of producing lightweight ceramsite. In the experiment, raw material was made into slurry and polypropylene balls were treated with the soak-a...

  • Article
  • Open Access
11 Citations
5,032 Views
22 Pages

24 February 2020

A general formulation is considered for the free vibration of curved laminated composite beams (CLCBs) with alterable curvatures and diverse boundary restraints. In accordance with higher-order shear deformation theory (HSDT), an improved variational...

  • Article
  • Open Access
39 Citations
9,027 Views
14 Pages

The Heat Conductivity Properties of Hemp–Lime Composite Material Used in Single-Family Buildings

  • Sławomir Pochwała,
  • Damian Makiola,
  • Stanisław Anweiler and
  • Michał Böhm

24 February 2020

The main goal of the paper is to calculate the heat conductivity for three experimental hemp–lime composites used for structural construction purposes with the use of the experimental stand inside two compartments. Due to current construction t...

  • Article
  • Open Access
11 Citations
3,706 Views
16 Pages

Topography of the Interfacial Shear Strength and the Mean Intrinsic Tensile Strength of Hemp Fibers as a Reinforcement of Polypropylene

  • David Hernández-Díaz,
  • Ricardo Villar-Ribera,
  • Fernando Julián,
  • Quim Tarrés,
  • Francesc X. Espinach and
  • Marc Delgado-Aguilar

24 February 2020

The strength of the interphase between the reinforcements and the matrix has a major role in the mechanical properties of natural fiber reinforced polyolefin composites. The creation of strong interphases is hindered by the hydrophobic and hydrophili...

  • Communication
  • Open Access
9 Citations
4,126 Views
10 Pages

24 February 2020

Both lamellar and non-lamellar configurations are naturally present in bio-membranes, and the synthetic lipid-based liquid crystalline nano-assemblies, mimicking these unique structures, (including liposomes, cubosomes and hexosomes) are applicable i...

  • Article
  • Open Access
8 Citations
4,111 Views
13 Pages

Effects of Helix Geometry on Magnetic Guiding of Helical Polymer Composites on a Gastric Cancer Model: A Feasibility Study

  • Yongju Kim,
  • Jeong Eun Park,
  • Jeong Jae Wie,
  • Su Geun Yang,
  • Don Haeng Lee and
  • Young-Joo Jin

24 February 2020

This study investigates the effects of soft-robot geometry on magnetic guiding to develop an efficient helical mediator on a three-dimensional (3D) gastric cancer model. Four different magnetically active helical soft robots are synthesized by the in...

  • Article
  • Open Access
58 Citations
5,596 Views
16 Pages

Strength Development and Elemental Distribution of Dolomite/Fly Ash Geopolymer Composite under Elevated Temperature

  • Emy Aizat Azimi,
  • Mohd Mustafa Al Bakri Abdullah,
  • Petrica Vizureanu,
  • Mohd Arif Anuar Mohd Salleh,
  • Andrei Victor Sandu,
  • Jitrin Chaiprapa,
  • Sorachon Yoriya,
  • Kamarudin Hussin and
  • Ikmal Hakem Aziz

24 February 2020

A geopolymer has been reckoned as a rising technology with huge potential for application across the globe. Dolomite refers to a material that can be used raw in producing geopolymers. Nevertheless, dolomite has slow strength development due to its l...

  • Article
  • Open Access
10 Citations
3,969 Views
9 Pages

Willow Bark for Sustainable Energy Storage Systems

  • Mathias Andreas Hobisch,
  • Josphat Phiri,
  • Jinze Dou,
  • Patrick Gane,
  • Tapani Vuorinen,
  • Wolfgang Bauer,
  • Christian Prehal,
  • Thaddeus Maloney and
  • Stefan Spirk

24 February 2020

Willow bark is a byproduct from forestry and is obtained at an industrial scale. We upcycled this byproduct in a two-step procedure into sustainable electrode materials for symmetrical supercapacitors using organic electrolytes. The procedure employe...

  • Correction
  • Open Access
2,229 Views
1 Page

Correction: G. Papari et al. Terahertz Spectroscopy of Amorphous WSe2 and MoSe2 Thin Films. Materials 2018, 11, 1613

  • Gian Paolo Papari,
  • Can Koral,
  • Toby Hallam,
  • Georg Stefan Duesberg and
  • Antonello Andreone

24 February 2020

The exponential factor in Equation (1) of the paper published in Materials [1] reports a misprint and the correct expression of the transmission function is (1) T ˜ ( ω ) = E ˜ f ( ω ) E ˜ s ( &ome...

  • Article
  • Open Access
8 Citations
3,147 Views
17 Pages

24 February 2020

This work determines the effect of the addition of various amounts of vanadium oxide on the work of a cell built from a hybrid VxOy-TiO2-rGO system in a lithium-ion cell. Moreover, a new method based on solvothermal chemistry is proposed for the crea...

  • Article
  • Open Access
9 Citations
3,613 Views
10 Pages

24 February 2020

Our goal is to fabricate flexible magnetic polymer composites as antenna substrates for very high frequency (VHF)/low ultra high frequency (UHF) antennas for unmanned aerial vehicles (UAVs) and medical devices. Magnetodielectric materials, which have...

  • Article
  • Open Access
14 Citations
4,189 Views
16 Pages

Fractal Characteristics of Chip Morphology and Tool Wear in High-Speed Turning of Iron-Based Super Alloy

  • Xu Zhang,
  • Guangming Zheng,
  • Xiang Cheng,
  • Rufeng Xu,
  • Guoyong Zhao and
  • Yebing Tian

24 February 2020

Considering that iron-based super alloy is a kind of difficult-to-cut material, it is easy to produce work hardening and serious tool wear during machining. Therefore, this work aims to explore the chip change characteristics and tool wear mechanism...

  • Article
  • Open Access
17 Citations
4,456 Views
10 Pages

24 February 2020

A series of polycarboxylate superplasticizer (PCE) polymers were synthesized from acrylic acid (AA) and isoprenyloxy polyethylene glycol ether (IPEG) at the mole ratios of 3.0, 4.2, 5.0 and 6.0. In this study, the molecular weight properties of PCE p...

  • Article
  • Open Access
7 Citations
4,721 Views
12 Pages

Processing and Mechanical Properties of Ti2AlC MAX Phase Reinforced AE44 Magnesium Composite

  • Xufeng Pi,
  • Wenbo Yu,
  • Chaosheng Ma,
  • Xiaojun Wang,
  • ShouMei Xiong and
  • Antoine Guitton

23 February 2020

AE44 alloys and nanolaminated Ti2AlC particle-reinforced AE44 magnesium composites were synthesized by stir casting techniques and textured by hot extrusion methods. It was found that lamellar Al11RE3 precipitates spheroidized with the introduction o...

  • Article
  • Open Access
6 Citations
3,872 Views
11 Pages

Separation and Recovery of Refined Si from Al–Si Melt by Modified Czochralski Method

  • Jingwei Li,
  • Juncheng Li,
  • Yinhe Lin,
  • Jian Shi,
  • Boyuan Ban,
  • Guicheng Liu,
  • Woochul Yang and
  • Jian Chen

23 February 2020

Separation of refined silicon from Al–Si melt is still a puzzle for the solvent refining process, resulting in considerable waste of acid and silicon powder. A novel modified Czochralski method within the Al–Si alloy is proposed. After th...

  • Article
  • Open Access
75 Citations
9,431 Views
20 Pages

23 February 2020

Due to the negative impact of construction processes on the environment and a decrease in investments, there is a need for concrete structures to operate longer while maintaining their high performance. Self-healing concrete has the ability to heal i...

  • Article
  • Open Access
46 Citations
5,769 Views
16 Pages

Chitosan-Functionalized Graphene Nanocomposite Films: Interfacial Interplay and Biological Activity

  • Natalia Wrońska,
  • Aicha Anouar,
  • Mounir El Achaby,
  • Katarzyna Zawadzka,
  • Marta Kędzierska,
  • Katarzyna Miłowska,
  • Nadia Katir,
  • Khalid Draoui,
  • Sylwia Różalska and
  • Katarzyna Lisowska
  • + 3 authors

23 February 2020

Graphene oxide (GO) has recently captured tremendous attention, but only few functionalized graphene derivatives were used as fillers, and insightful studies dealing with the thermal, mechanical, and biological effects of graphene surface functionali...

  • Feature Paper
  • Review
  • Open Access
45 Citations
7,223 Views
15 Pages

23 February 2020

Surface modification of poly(ether ether ketone) (PEEK) aimed at applying it as a bone implant material aroused the unflagging interest of the research community. In view of the development of implantology and the growing demand for new biomaterials,...

  • Article
  • Open Access
14 Citations
4,637 Views
14 Pages

Thermoplastic Starch (TPS) Films Added with Mucilage from Opuntia Ficus Indica: Mechanical, Microstructural and Thermal Characterization

  • Fabrizio Scognamiglio,
  • Daniele Mirabile Gattia,
  • Graziella Roselli,
  • Franca Persia,
  • Ugo De Angelis and
  • Carlo Santulli

23 February 2020

Opuntia cladodes are a typical vegetable waste, from which mucilage in gel form can be extracted. This work proposes blending it with a self-produced thermoplastic starch (TPS), originating from potato starch with a high content in glycerol (ca. 30%)...

  • Article
  • Open Access
8 Citations
4,064 Views
20 Pages

Low Cycle Fatigue Life Evaluation of Notched Specimens Considering Strain Gradient

  • Shenghuan Qin,
  • Zaiyin Xiong,
  • Yingsong Ma and
  • Keshi Zhang

23 February 2020

An improved model based on the Chaboche constitutive model is proposed for cyclic plastic behavior of metal and low cycle fatigue of notched specimens under cyclic loading, considering the effect of strain gradient on nonlinear kinematic hardening an...

  • Article
  • Open Access
40 Citations
5,405 Views
22 Pages

Towards the Use of Waste Pig Fat as a Novel Potential Bio-Based Rejuvenator for Recycled Asphalt Pavement

  • Nader Nciri,
  • Taesub Shin,
  • Namho Kim,
  • Arnaud Caron,
  • Hanen Ben Ismail and
  • Namjun Cho

23 February 2020

This article presents a novel potential bio-based rejuvenator derived from waste pig fat (WPF) for use in recycled asphalt applications. To achieve this purpose, the impact of different doses waste pig fat (e.g., 0, 3, 6, and 9 wt.% WPF) on the recla...

  • Article
  • Open Access
112 Citations
11,840 Views
15 Pages

Diamond Like Carbon Films Containing Si: Structure and Nonlinear Optical Properties

  • Šarūnas Meškinis,
  • Andrius Vasiliauskas,
  • Mindaugas Andrulevičius,
  • Domantas Peckus,
  • Sigitas Tamulevičius and
  • Karolis Viskontas

23 February 2020

In the present research diamond-like carbon (DLC) films containing 4–29 at.% of silicon were deposited by reactive magnetron sputtering of carbon target. Study by X-ray photoelectron spectroscopy revealed the presence of Si–C bonds in the...

  • Article
  • Open Access
14 Citations
4,038 Views
13 Pages

23 February 2020

The electroplated cubic boron nitride (CBN) wheel has perfect precision retention and high-temperature grinding performance, which is widely used in the field of grinding difficult-to-cut materials, such as nickel-based superalloy. However, the resea...

  • Article
  • Open Access
77 Citations
5,918 Views
16 Pages

22 February 2020

A composite phase change material (PCM) was prepared by incorporating paraffin (PA) with expanded graphite (EG) and nano-metal particles to improve the thermal conductivity and reduce the leakage performance of PA once it melts and, consequently, dev...

  • Article
  • Open Access
46 Citations
5,279 Views
15 Pages

Evaluation of the Surface Characteristics of Dental CAD/CAM Materials after Different Surface Treatments

  • Konstantinos Papadopoulos,
  • Kimon Pahinis,
  • Kyriaki Saltidou,
  • Dimitrios Dionysopoulos and
  • Effrosyni Tsitrou

22 February 2020

Computer-aided design/computer-aided manufacturing (CAD/CAM) technology was developed to ensure the sufficient strength of tooth restorations, to improve esthetic restorations with a natural appearance and to make the techniques easier, faster and mo...

  • Article
  • Open Access
4 Citations
2,328 Views
11 Pages

Friction and Wear Properties of Ni3Si Alloy with Ti Addition at High Temperatures

  • Changyin Wu,
  • Muye Niu,
  • Shuai Bao,
  • Yuhang Sun and
  • Xinghua Zhang

22 February 2020

The tribological properties of Ni3Si alloy were studied at high temperatures. The effect of the addition of Ti was also analyzed. The surface composition was analyzed by Raman spectroscopy. The results showed that the friction coefficient decreased w...

  • Article
  • Open Access
51 Citations
5,085 Views
14 Pages

The Effects of Nanoclay on the Mechanical Properties, Carvacrol Release and Degradation of a PLA/PBAT Blend

  • Roberto Scaffaro,
  • Andrea Maio,
  • Emmanuel Fortunato Gulino,
  • Marco Morreale and
  • Francesco Paolo La Mantia

22 February 2020

The formulation of polymeric films endowed with the abilities of controlled release of antimicrobials and biodegradability is the latest trend of food packaging. Biodegradable polymer (Bio-Flex®)-based nanocomposites containing carvacrol as an an...

  • Article
  • Open Access
16 Citations
3,183 Views
14 Pages

22 February 2020

The rapid solidification of melt spinning has been widely used in the fabrication of high-performance skutterudite thermoelectric materials. However, the microstructure formation mechanism of the spun ribbon and its effects on the mechanical properti...

  • Review
  • Open Access
92 Citations
11,072 Views
61 Pages

Mg-Alloys for Forging Applications—A Review

  • Nikolaus P. Papenberg,
  • Stefan Gneiger,
  • Irmgard Weißensteiner,
  • Peter J. Uggowitzer and
  • Stefan Pogatscher

22 February 2020

Interest in magnesium alloys and their applications has risen in recent years. This trend is mainly evident in casting applications, but wrought alloys are also increasingly coming into focus. Among the most common forming processes, forging is a pro...

  • Review
  • Open Access
37 Citations
8,154 Views
8 Pages

22 February 2020

The technique described as indirect bonding is an alternative to the conventional intraoral method of bracket placement. The appliance position is planned and fixed on a plaster model and then transferred into the oral cavity. Indirect bonding is a p...

  • Letter
  • Open Access
4 Citations
2,749 Views
6 Pages

N-Doped Animal Keratin Waste Porous Biochar derived from Trapa Natans Husks

  • Wenjun Yin,
  • Zhonghua Zhang,
  • Tongcai Liu,
  • Jiao Xu,
  • Shaoze Xiao and
  • Yao Xu

22 February 2020

Animal-keratin-wastes (AKWs), horns (HN), hair (HR), puffed waterfowl feathers (PF), hydrolyzed waterfowl feathers (HF), hydrolyzed fish meal (HM), crab meat (CM), feathers (FR), shrimp chaff (SC), fish scales (FS), and waste leather (WL) were used a...

  • Article
  • Open Access
53 Citations
5,983 Views
17 Pages

22 February 2020

In the present work the rheological, thermo-mechanical, microstructural, and wetting characteristics of cement mortars with recycled expanded polystyrene (EPS) were analyzed. The samples were prepared after partial/total replacement of the convention...

  • Article
  • Open Access
25 Citations
4,090 Views
13 Pages

Reuse of CD and DVD Wastes as Reinforcement in Gypsum Plaster Plates

  • Manuel Alejandro Pedreño-Rojas,
  • María Jesús Morales-Conde,
  • Filomena Pérez-Gálvez and
  • Paloma Rubio-de-Hita

22 February 2020

The continuous and rapid evolution in the field of computing, and in particular in the field of storage devices, has led to the obsolescence of optical discs in favour of mass storage devices. In that sense, a large number of CDs and DVDs become obso...

  • Article
  • Open Access
16 Citations
3,384 Views
15 Pages

22 February 2020

The injection of carbon dioxide (CO2) in low-permeable reservoirs can not only mitigate the greenhouse effect on the environment, but also enhance oil and gas recovery (EOR). For numerical simulation work of this process, relative permeability can he...

  • Feature Paper
  • Article
  • Open Access
17 Citations
4,000 Views
16 Pages

Enhanced Stability of Li-RHC Embedded in an Adaptive TPX™ Polymer Scaffold

  • Thi Thu Le,
  • Claudio Pistidda,
  • Clarissa Abetz,
  • Prokopios Georgopanos,
  • Sebastiano Garroni,
  • Giovanni Capurso,
  • Chiara Milanese,
  • Julián Puszkiel,
  • Martin Dornheim and
  • Thomas Klassen
  • + 1 author

22 February 2020

In this work, the possibility of creating a polymer-based adaptive scaffold for improving the hydrogen storage properties of the system 2LiH+MgB2+7.5(3TiCl3·AlCl3) was studied. Because of its chemical stability toward the hydrogen storage mate...

  • Article
  • Open Access
8 Citations
4,202 Views
16 Pages

A Structural Comparison of Ordered and Non-Ordered Ion Doped Silicate Bioactive Glasses

  • Seray Schmitz,
  • Ana M. Beltrán,
  • Mark Cresswell and
  • Aldo R. Boccaccini

22 February 2020

One of the key benefits of sol-gel-derived glasses is the presence of a mesoporous structure and the resulting increase in surface area. This enhancement in textural properties has a significant effect on the physicochemical properties of the materia...

  • Article
  • Open Access
10 Citations
4,273 Views
23 Pages

22 February 2020

In recent years, advanced materials have attracted considerable interest in the field of temperature detection and sensing. This study examined the thermochromic properties of inorganic manganese violet (MV) with increasing temperature. According to...

  • Article
  • Open Access
1 Citations
4,369 Views
19 Pages

22 February 2020

Examination of possible pathways of how oxygen atoms can be added to a yttrium oxyhydride system allowed us to predict new derivatives such as hydroxyhydrides possessing the composition M2H3O(OH) (M = Y, Sc, La, and Gd) in which three different anion...

  • Article
  • Open Access
21 Citations
3,907 Views
15 Pages

Dilatometric Study of Phase Transformations in 5 Mn Steel Subjected to Different Heat Treatments

  • Mateusz Morawiec,
  • Adam Grajcar,
  • Władysław Zalecki,
  • Carlos Garcia-Mateo and
  • Marek Opiela

21 February 2020

The work presents results of phase transformation kinetics of hot-rolled 5% Mn steel subjected to different heat treatments. Three different schedules were introduced: isothermal holding in a bainite region, coiling simulation and intercritical annea...

  • Article
  • Open Access
10 Citations
3,981 Views
24 Pages

21 February 2020

The effect of silicon on diffusion behavior of the carbide forming elements in Ni-Mo-Cr-Fe based corrosion-resistant alloy is studied by diffusion couple experiment. One group of diffusion couples are made of the alloy with a different silicon conten...

  • Article
  • Open Access
13 Citations
4,727 Views
12 Pages

Amino Anthraquinone: Synthesis, Characterization, and Its Application as an Active Material in Environmental Sensors

  • Salman Ali,
  • Muhammad Tahir,
  • Nasir Mehboob,
  • Fazal Wahab,
  • Steven J. Langford,
  • Suhana Mohd Said,
  • Mahidur R. Sarker,
  • Sabariah Julai and
  • Sawal Hamid Md Ali

21 February 2020

This work reports synthesis, thin film characterizations, and study of an organic semiconductor 2-aminoanthraquinone (AAq) for humidity and temperature sensing applications. The morphological and phase studies of AAq thin films are carried out by sca...

  • Article
  • Open Access
11 Citations
4,828 Views
20 Pages

The Influence of the Welding Process on the Ultrasonic Inspection of 9%Ni Steel Pipe Circumferential Welded Joints

  • João da Cruz Payão Filho,
  • Elisa Kimus Dias Passos,
  • Rodrigo Stohler Gonzaga,
  • Daniel Drumond Santos,
  • Vinicius Pereira Maia and
  • Diego Russo Juliano

21 February 2020

This work aims to compare the ultrasonic inspection of 9%Ni steel joints welded with the Gas Metal Arc Welding (GMAW) process and Shielded Metal Arc Welding (SMAW) process. These are the two most widely used processes used to weld pipes for CO2 injec...

  • Article
  • Open Access
15 Citations
2,922 Views
20 Pages

21 February 2020

The laser energy density (ED) is often utilized in many additive manufacturing (AM) processes studies to help researchers to further investigate the process-structure-property correlations of Ti6Al4V alloys. However, the reliability of the ED is stil...

  • Review
  • Open Access
45 Citations
4,642 Views
16 Pages

Developing Nanostructured Ti Alloys for Innovative Implantable Medical Devices

  • Ruslan Z. Valiev,
  • Egor A. Prokofiev,
  • Nikita A. Kazarinov,
  • Georgy I. Raab,
  • Timur B. Minasov and
  • Josef Stráský

21 February 2020

Recent years have witnessed much progress in medical device manufacturing and the needs of the medical industry urges modern nanomaterials science to develop novel approaches for improving the properties of existing biomaterials. One of the ways to e...

  • Article
  • Open Access
3 Citations
3,086 Views
11 Pages

21 February 2020

The effect of recrystallization of 99.3Sn–0.7Cu wt. % solder alloy on the allotropic transition of β to α-Sn (so-called tin pest phenomenon) was investigated. Bulk samples were prepared, and an InSb inoculator was mechanically applie...

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Materials - ISSN 1996-1944