Search Results (218)

FeAl intermetallic compounds exhibit high application potential in high-voltage transmission lines to withstand external forces such as powerlines’ own gravity and wind force. The ordered crystal structure in FeAl intermetallic compounds endows materials with high strength, but the remarkable brittleness at room temperature restricts engineering applications. This contradiction is essentially closely related to the deformation mechanism at the nanoscale. Here, we performed molecular dynamics simulations to reveal anomalous grain size effects and deformation mechanisms in nanocrystalline FeAl intermetallic material. Models with grain sizes ranging from 6.2 to 17.4 nm were systematically investigated under uniaxial tensile stress. The study uncovers a distinctive inverse Hall-Petch relationship governing flow stress within the nanoscale regime. This behavior stems from high-density grain boundaries promoting dislocation annihilation over pile-up. Crucially, the material exhibits anomalous ductility at ultra-high strain rates due to stress-induced phase transformation dominating the plastic deformation. The nascent FCC phase accommodates strain through enhanced slip systems and inherent low stacking fault energy with the increasing phase fraction paralleling the stress plateau. Nanoconfinement suppresses the propagation of macroscopic defects while simultaneously suppressing room-temperature brittle fracture and inhibiting the rapid phase transformation pathways at extreme strain rates. These findings provide new theoretical foundations for designing high-strength and high-toughness intermetallic nanocompounds. Full article

Noncoplanar spin textures give rise not only to unusual magnetic structures but also to emergent electromagnetic responses stemming from scalar spin chirality, such as the topological Hall effect. In this study, we theoretically investigate nonreciprocal transport phenomena induced by noncoplanar magnetic orderings through microscopic model analyses. By focusing on meron–antimeron spin textures that exhibit local scalar spin chirality while maintaining vanishing global chirality, we demonstrate that the electronic band structure becomes asymmetrically modulated, which leads to the emergence of nonreciprocal transport. The present mechanism arises purely from the noncoplanar magnetic texture itself and requires neither net magnetization nor relativistic spin–orbit coupling. We further discuss the potential relevance of our findings to the compound Gd₂PdSi₃, which has been suggested to host a meron–antimeron crystal phase at low temperatures. Full article

This study investigates how lighting conditions influence emotional and neural responses in a standardized, simulated museum environment. A multimodal evaluation framework combining subjective and objective measures was used. Thirty-two international students assessed their viewing experiences using 14 semantic differential descriptors, while real-time EEG signals were recorded via the EMOTIV EPOC X device. Spectral energy analyses of the α, β, and θ frequency bands were conducted, and a θα energy ratio combined with γ coefficients was used to model attention and comfort levels. The results indicated that high illuminance (300 lx) and high correlated color temperature (4000 K) significantly enhanced both attention and comfort. Art majors showed higher attention levels than engineering majors during short-term viewing. Among four regression models, the backpropagation (BP) neural network achieved the highest predictive accuracy (R² = 88.65%). These findings provide empirical support for designing culturally inclusive museum lighting and offer neuroscience-informed strategies for promoting the global dissemination of traditional Chinese culture, further supported by retrospective interview insights. Full article

This study examines the microstructural evolution, mechanical properties, and wear behavior of medium-carbon dual-phase steel (AISI 1040) processed via Multi-Axis Compression (MAC). The DP steel was produced through inter-critical annealing at 745 °C, followed by MAC at 500 °C, resulting in a refined grain microstructure. Optical micrographs confirmed the presence of ferrite and martensite phases after annealing, with significant grain refinement observed following MAC. The average grain size decreased from 66 ± 4 μm to 18 ± 1 μm after nine MAC passes. Mechanical testing revealed substantial improvements in hardness (from 145 ± 9 HV to 298 ± 18 HV) and ultimate tensile strength (from 557 ± 33 MPa to 738 ± 44 MPa), attributed to strain hardening and the Hall–Petch effect. Fractographic analysis revealed a ductile failure mode in the annealed sample, while DP0 and DP9 exhibited a mixed fracture mode. Both DP0 and DP9 samples demonstrated superior wear resistance compared to the annealed sample. However, the DP9 sample exhibited slightly lower wear resistance than DP0, likely due to the fragmentation of martensite induced by high accumulated strain, which could act as crack initiation sites during sliding wear. Furthermore, wear resistance was significantly enhanced due to the combined effects of the DP structure and Severe Plastic Deformation (SPD). These findings highlight the potential of MAC processing for developing high-performance steels suitable for lightweight automotive applications. Full article

Tantalum oxide is a wide bandgap material commonly used as an insulating dielectric layer for devices. In this work, hexagonal Ta₂O₅ (δ-Ta₂O₅) films doped with tungsten (W) were deposited on α-Al₂O₃ (0001) by metal–organic chemical vapor deposition (MOCVD). The effects of W doping on the structural, morphology, and photoelectrical properties of the obtained films were studied. The results showed that all W-doped films were n-type semiconductors. The XRD measurement result exhibited that the increase in the W doping concentration leads to the changes in the preferred growth crystal plane of the films from δ-Ta₂O₅ ($10\overline{1}1$) to (0001). The 1.5% W-doped film possessed the best crystal quality and conductivity. The Hall measurement showed that the minimum resistivity of the film was 2.68 × 10⁴ Ω∙cm, and the maximum carrier concentration was 7.39 × 10¹⁴ cm³. With the increase in the W concentration, the surface roughness of the film increases, while the optical bandgap decreases. The optical band gap of the 1.5% W-doped film was 3.92 eV. The W doping mechanisms were discussed. Full article

In this study, lanthanum (La), a rare earth element, was added at concentrations of 0.25 wt.%, 0.5 wt.%, and 0.75 wt.% to an Al–10%Si–2%Cu-based alloy prepared by die casting. The effects of solution and aging heat treatment conditions on the mechanical properties and corrosion resistance were investigated. Microstructural changes, hardness, and corrosion behavior were analyzed as functions of La content and heat treatment parameters. The optimal hardness was achieved at a solution treatment temperature of 500 °C or higher and an aging time of 2 h. In particular, the addition of 0.5 wt.% La led to significant refinement of the α-Al grains, enhancing hardness through the Hall–Petch strengthening mechanism. Furthermore, the combined effects of aging treatment and La addition promoted the formation of a fine, uniform microstructure and stable dispersion of precipitates, resulting in improved mechanical performance. Electrochemical polarization tests revealed that the alloy containing 0.5 wt.% La exhibited the best corrosion resistance. This enhancement was attributed to the formation of the LaCu₂Al₄Si intermetallic compound, which has a lower electrochemical potential than the Al₂Cu phase, thereby reducing corrosion susceptibility within the microstructure. Full article

The tin dioxide (SnO₂) thin films in this work were prepared by using plasma-enhanced atomic layer deposition (PEALD), and a systematic analysis was conducted to evaluate the influence of post-deposition annealing at various temperatures in a nitrogen–hydrogen mixed atmosphere on their surface morphology, optical behavior, and electrical performance. The SnO₂ films were characterized by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Hall effect measurements. With increasing annealing temperatures, the SnO₂ films exhibited enhanced crystallinity, a higher oxygen vacancy (O_V) peak area ratio, and improved mobility and carrier concentration. These enhancements make the annealed SnO₂ films highly suitable as electron transport layers (ETLs) in perovskite solar cells (PSCs), providing practical guidance for the design of high-performance PSCs. Full article

One-dimensional TiO₂ nanotube arrays (TNAs) were vertically aligned and obtained via the electrochemical anodization method. In this study, Bi₂S₃-TiO₂-SiO₂/TNA heterojunction photocatalysts were successfully prepared with different amounts of Bismuth(III) sulfide (Bi₂S₃) loading on the TNAs by the successive ionic layer adsorption and reaction (SILAR) method and characterized by X-ray diffraction (XRD) patterns, field-emission scanning electron microscope–energy-dispersive spectroscopy (FESEM-EDS), Fourier transform infrared (FTIR) spectra, ultraviolet-visible diffuse reflectance spectra (UV–Vis/DRS), and electrochemical impedance spectroscopy (EIS) techniques. The photocatalytic performances of the samples were investigated by degrading Basic Yellow 28 (BY 28) under visible-light irradiation. Optimization of the condition using the response surface methodology (RSM) and central composite rotatable design (CCRD) technique resulted in the degradation of BY 28 dye, showing that the catalyst with 9.6 mg/cm² (designated as Bi₂S_3(9.6)-TiO₂-SiO₂/TNA) showed the maximum yield in the degradation process. The crystallite size of about 17.03 nm was estimated using the Williamson–Hall method. The band gap energies of TiO₂-SiO₂/TNA and Bi₂S_3(9.6)-TiO₂-SiO₂/TNA were determined at 3.27 and 1.87 eV for the direct electronic transitions, respectively. The EIS of the ternary system exhibited the smallest arc diameter, indicating an accelerated charge transfer rate that favors photocatalytic activity. Full article

Vernacular architecture is a complex and living heritage type, and the study of the evolution laws of its spatial form is of great value to the conservation of architectural heritage diversity. Taking vernacular architecture in the Yunnan–Tibet area as the research object, based on the theory of spatial syntax, 30 building samples were subjected to global and local calculations of MD, I_RRA, and NACH values, while the common characteristics among the samples were obtained by using Kendall’s W test, and the individual characteristics among the samples were obtained by using differentiation analysis. The results show that: (a) vernacular architecture in the Yunnan–Tibet area exhibits characteristics of multi-cluster branched centrality and spatial hierarchical layout; (b) these architectures possess four categories of inheritance factors: the privacy of granary spaces, the centrality of corridor spaces, the passability of breeding areas, and the independence of scripture hall spaces; (c) these architectures possess three categories of differentiation factors: the functional evolution of traditional spaces, the spatial reconstruction of breeding areas, and the “Toilet Revolution” driven by multiple forces. This study elucidates the regulatory role of cultural continuity in shaping the spatial forms of vernacular architecture, providing new evidence for analyzing the formation mechanisms of vernacular architecture in the Yunnan–Tibet area. Full article

Topological photonic crystals have garnered significant attention due to their fascinating topological edge states. These states are robust against sharp bends and defects and exhibit the novel property of unidirectional transmission. In this study, we analyze the topological edge states of gyromagnetic topological photonic crystals in analogy with the quantum Hall effect. Through expanding and shrinking six dielectric cylinders, the optical quantum spin Hall effect is achieved. And helical edge states with pseudo-spin are demonstrated. Owing to the novel topological properties of these edge states, robust waveguides are proposed. Furthermore, integrating these two distinct types of topological states, a novel circulator with topological characteristics is designed. These topologically protected photonic devices will be beneficial for developing integrated circuits. Full article

This study aims to examine the impact of ESG management activities (independent variable) on organizational trust and organizational commitment (mediating variables), as well as organizational performance (dependent variable), among members of large manufacturing enterprises. Additionally, it investigates the moderating effect of job position on the relationship between ESG management activities and organizational performance. For the empirical analysis of this study, data were collected from 561 employees of three large manufacturing companies—Company L, Company H, and another Company H—all of which have implemented and are practicing ESG management. The data were analyzed using SPSS 29.0 and structural equation modeling (SEM: AMOS 29.0). The key findings from the empirical analysis are as follows: First of all, all three ESG factors—environmental (E), social (S), and governance (G)—had a positive effect on organizational trust. The environmental and governance factors had a positive effect on organizational commitment. However, the social factor exhibited a negative effect on organizational commitment. The environmental factor showed a negative effect on organizational performance. By contrast, the social and governance factors had a positive effect on organizational performance. Organizational trust was found to enhance organizational commitment significantly, confirming that employees who trust their organization are more likely to be committed to it. Fifth, a strong sense of trust in the organization was shown to contribute positively to organizational performance and competitiveness. Organizational commitment positively impacted organizational performance, reinforcing the idea that highly committed employees contribute to better outcomes. Finally, this study confirmed that job position moderated the relationship between ESG management activities and organizational performance, indicating that employees at different hierarchical levels perceive ESG management’s impact differently. This study expands the research scope of ESG management beyond marketing, HR, and service industries to focus on employees in large manufacturing enterprises. This provides new insights into how ESG initiatives influence internal organizational dynamics. This study is meaningful in that it provides a foundation for expanding future research into the field of finance or other areas of the manufacturing industry. From a practical standpoint, the findings highlight the necessity of strategic initiatives to ensure that employees fully understand and engage with ESG-related policies. To successfully implement ESG management, organizations must develop effective communication and integration strategies that foster employees’ recognition of ESG initiatives. Full article

The Al-Sb co-doped SnO₂ composite thin films were prepared by the sol–gel spin-coating method. The structure, morphology, optical and electrical properties of the samples were investigated using XRD, XPS, SEM, UV-Vis spectroscopy, and Hall effect tester, respectively. It was found that when the aluminum doping amount was 15 at%, the resistivity of the sample was the lowest, and the overall optoelectronic performance was the best. Moreover, the Al-SnO₂ composite thin film transformed from an n-type semiconductor to a p-type semiconductor. When Al and Sb were co-doped, the carrier concentration increased significantly from 4.234 × 10¹⁹ to 6.455 × 10²⁰. Finally, the conduction type of the Al-Sb-SnO₂ composite thin film changed from p-type to n-type. In terms of optical performance, the transmittance of the Al-Sb co-doped SnO₂ composite thin films in the visible light region was significantly improved, reaching up to 80% on average, which is favorable for applications in transparent optoelectronic devices. Additionally, the absorption edge of the thin films exhibited a blue-shift after co-doping, indicating an increase in the bandgap energy, which can be exploited to tune the light-absorption properties of the thin films for specific photonic applications. Full article

Art exhibition spaces increasingly emphasize visitor experience, yet the relationships among spatial structure, visitor behavior, and emotional response remain unclear. Traditional space syntax analyses typically focus on physical spatial structures, insufficiently capturing visitors’ emotional and cognitive experiences. To address these gaps, this study presents an integrative evaluation framework that combines space syntax theory with multimodal physiological measurements to systematically assess spatial design performance in art exhibition environments. Eye-tracking and heart rate variability (HRV) experiments were conducted to investigate how spatial configuration affects visual attention and emotional responses. Visibility graph analysis, spatial integration metrics, and regression modeling were applied using the third-floor temporary exhibition hall of the Pudong Art Museum in Shanghai as a case study. The results revealed that HRV levels (β = −7.92) were significantly predicted via spatial integration, and the relationship between spatial integration and the number of fixations was partially mediated by HRV (indirect effect: β = −0.36; direct effect: β = 8.23). Additionally, zones with higher occlusivity were associated with more complex scanpaths (mean complexity: 0.14), whereas highly integrated regions triggered more fixations (mean = 10.54) and longer total fixation durations (mean = 2946.98 ms). Therefore, spatial syntax, when coupled with physiological indicators, provides a robust and actionable method for evaluating and optimizing exhibition space design. Full article

In aerospace applications, titanium matrix composites (TMCs) must balance high strength, thermal stability, and vibration resistance. This study investigates the microstructural evolution and multi-property correlations in single-phase ZrC-reinforced (TMC1) and dual-phase ZrC-NbC-co-reinforced (TMC2) TMCs via SEM/TEM, XRD, tensile testing, and ANSYS simulations. The in situ reaction (Ti + ZrC/NbC → TiC + Zr/Nb) and NbC-induced grain boundary pinning drive microstructural optimization in TMC2, achieving 30% higher reinforcement homogeneity and 5 μm grain refinement from 15 μm to 10 μm. TMC2’s tensile strength reaches 1210 MPa, a 15% increase over TMC1, with an elongation at a break of 4.74%, 2.2 times that of TMC1. This performance stems from synergistic Hall–Petch strengthening and nano-TiC dispersion strengthening. Modal simulations show TMC2 exhibits a first-mode natural frequency of 98.5 kHz, 1.1% higher than TMC1’s 97.4 kHz, with maximum displacement reduced by 2.3%. These improvements correlate with TMC2’s elevated elastic modulus (125 GPa vs. 110 GPa) and uniform mass/stiffness distribution. The ZrC-NbC synergy establishes a microstructural framework for the concurrent enhancement of static and dynamic properties, offering critical insights for a high-performance TMC design in extreme environments. Full article

The low-symmetry Weyl semimetallic Td-phase WTe₂ exhibits both a distinct out-of-plane damping torque (${\tau }_{\mathrm{DL}}$) and exceptional charge–spin interconversion efficiency enabled by strong spin-orbit coupling, positioning it as a prime candidate for spin–orbit torque (SOT) applications in two-dimensional transition metal dichalcogenides. Herein, we report on thickness-dependent unconventional out-of-plane ${\tau }_{\mathrm{DL}}$ in chemically vapor-deposited (CVD) polycrystalline Td-WTe₂ (t)/Ni₈₀Fe₂₀/MgO/Ti (Td-WTN-t) heterostructures. Angle-resolved spin-torque ferromagnetic resonance measurements on the Td-WTN-12 structure showed significant spin Hall conductivities of σ_SH,y = 4.93 × 10³ (ℏ/2e) Ω⁻¹m⁻¹ and σ_SH,z = 0.81 × 10³ (ℏ/2e) Ω⁻¹m⁻¹, highlighting its potential for wafer-scale spin–orbit torque device applications. Additionally, a detailed examination of magnetotransport properties in polycrystalline few-layer Td-WTe₂ films as a function of thickness revealed a marked amplification of the out-of-plane magnetoresistance, which can be ascribed to the anisotropic nature of charge carrier scattering mechanisms within the material. Spin pumping measurements in Td-WTN-t heterostructures further revealed thickness-dependent spin transport properties of Td-WTe₂, with damping analysis yielding an out-of-plane spin diffusion length of λ_SD ≈ 14 nm. Full article