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Search Results (1,275)

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26 pages, 4856 KiB  
Article
PREFACE: A Search for Long-Lived Particles at the Large Hadron Collider
by Burak Hacisahinoglu, Suat Ozkorucuklu, Maksym Ovchynnikov, Michael G. Albrow, Aldo Penzo and Orhan Aydilek
Physics 2025, 7(3), 33; https://doi.org/10.3390/physics7030033 (registering DOI) - 1 Aug 2025
Abstract
The Standard Model (SM) fails to explain many problems (neutrino masses, dark matter, and matter–antimatter asymmetry, among others) that may be resolved with new particles beyond the SM. No observation of such new particles may be explained either by their exceptionally high mass [...] Read more.
The Standard Model (SM) fails to explain many problems (neutrino masses, dark matter, and matter–antimatter asymmetry, among others) that may be resolved with new particles beyond the SM. No observation of such new particles may be explained either by their exceptionally high mass or by considerably small coupling to SM particles. The latter case implies relatively long lifetimes. Such long-lived particles (LLPs) then to have signatures different from those of SM particles. Searches in the “central region” are covered by the LHC general purpose experiments. The forward small angle region far from the interaction point (IP) is unexplored. Such particles are expected to have the energy as large as E = O(1 TeV) and Lorentz time dilation factor γ=E/m102103 (with m the particle mass) hence long enough decay distances. A new class of specialized LHC detectors dedicated to LLP searches has been proposed for the forward regions. Among these experiments, FASER is already operational, and FACET is under consideration at a location 100 m from the LHC IP5 (the CMS detector intersection). However, some features of FACET require a specially enlarged beam pipe, which cannot be implemented for LHC Run 4. In this study, we explore a simplified version of the proposed detector PREFACE compatible with the standard LHC beam pipe in the HL-LHC Run 4. Realistic Geant4 simulations are performed and the background is evaluated. An initial analysis of the physics potential with the PREFACE geometry indicates that several significant channels could be accessible with sensitivities comparable to FACET and other LLP searches. Full article
(This article belongs to the Section High Energy Physics)
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14 pages, 1014 KiB  
Article
Bioenergy Production from Solid Fuel Conversion of Cattle Manure and Resource Utilization of the Combustion Residues
by Eunsung Lee, Junsoo Ha and Seongwook Oa
Processes 2025, 13(8), 2417; https://doi.org/10.3390/pr13082417 - 30 Jul 2025
Viewed by 63
Abstract
Cattle manure accounts for approximately one-third of the total livestock manure produced in the Republic of Korea and is typically composted. To elucidate its feasibility as a renewable resource, this study evaluated the conversion of cattle manure into a solid biofuel and the [...] Read more.
Cattle manure accounts for approximately one-third of the total livestock manure produced in the Republic of Korea and is typically composted. To elucidate its feasibility as a renewable resource, this study evaluated the conversion of cattle manure into a solid biofuel and the nutrient recovery potential of its combustion residues. Solid fuel was prepared from cattle manure collected in Gyeongsangbuk-do, Korea, and its fuel characteristics and ash composition were analyzed after combustion. Combustion tests conducted using a dedicated solid fuel boiler showed that an average lower heating value of 13.27 MJ/kg was achieved, meeting legal standards. Under optimized combustion, CO and NOx emissions (129.9 and 41.5 ppm) were below regulatory limits (200 and 90 ppm); PM was also within the 25 mg/Sm3 standard. The bottom ash contained high concentrations of P2O5 and K, and its heavy metal content was below the regulatory threshold, suggesting its potential reuse as a fertilizer material. Although the Zn concentration in the fly ash exceeded the standard, its quantity was negligible. Therefore, the solid fuel conversion of cattle manure can become a viable and environmentally sustainable solution for both bioenergy production and nutrient recycling, contributing to improved waste management in livestock operations. Full article
(This article belongs to the Section Environmental and Green Processes)
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17 pages, 4077 KiB  
Article
The Impact of Sm Promoter on the Catalytic Performance of Ni/Al2O3-SiO2 in Methane Partial Oxidation for Enhanced H2 Production
by Salwa B. Alreshaidan, Rasha S. A. Alanazi, Omalsad H. Odhah, Ahmed A. Ibrahim, Fekri Abdulraqeb Ahmed Ali, Naif Alarifi, Khaled M. Banabdwin, Sivalingam Ramesh and Ahmed S. Al-Fatesh
Catalysts 2025, 15(8), 721; https://doi.org/10.3390/catal15080721 (registering DOI) - 29 Jul 2025
Viewed by 182
Abstract
This study investigates the effects of samarium (Sm) promotion on the catalytic activity of 5 weight percent Ni catalysts for partial oxidation of methane (POM)-based hydrogen production supported on a Si-Al mixed oxide (10SiO2+90Al2O3) system. Several 5% [...] Read more.
This study investigates the effects of samarium (Sm) promotion on the catalytic activity of 5 weight percent Ni catalysts for partial oxidation of methane (POM)-based hydrogen production supported on a Si-Al mixed oxide (10SiO2+90Al2O3) system. Several 5% Ni-based catalysts supported on silica–alumina was used to test the POM at 600 °C. Sm additions ranged from 0 to 2 wt.%. Impregnation was used to create these catalysts, which were then calcined at 500 °C and examined using BET, H2-TPR, XRD, FTIR, TEM, Raman spectroscopy, and TGA methods. Methane conversion (57.85%) and hydrogen yield (56.89%) were greatly increased with an ideal Sm loading of 1 wt.%, indicating increased catalytic activity and stability. According to catalytic tests, 1 wt.% Sm produced high CH4 conversion and H2 production, as well as enhanced stability and resistance to carbon deposition. Nitrogen physisorption demonstrated a progressive decrease in pore volume and surface area with the addition of Sm, while maintaining mesoporosity. At moderate Sm loadings, H2-TPR and XRD analyses showed changes in crystallinity and increased NiO reducibility. Sm incorporation into the support and its impact on the ordering of carbon species were indicated by FTIR and Raman spectra. The optimal conditions to maximize H2 yield were successfully identified through optimization of the best catalyst, and there was good agreement between the theoretical predictions (87.563%) and actual results (88.39%). This displays how successfully the optimization approach achieves the intended outcome. Overall, this study demonstrates that the performance and durability of Ni-based catalysts for generating syngas through POM are greatly enhanced by the addition of a moderate amount of Sm, particularly 1 wt.%. Full article
(This article belongs to the Section Industrial Catalysis)
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16 pages, 2131 KiB  
Article
A Comparative Study on ZrO2- and MgO-Based Sulfonic Acid Materials for the Reactive Adsorption of o-Xylene
by Hongmei Wang, Xiaoxu Zhang, Ziqi Shen and Zichuan Ma
Molecules 2025, 30(15), 3171; https://doi.org/10.3390/molecules30153171 - 29 Jul 2025
Viewed by 157
Abstract
The recovery and abatement of volatile organic compounds (VOCs) have received increasing attention due to their significant environmental and health impacts. Supported sulfonic acid materials have shown great potential in converting aromatic VOCs into their non-volatile derivatives through reactive adsorption. However, the anchoring [...] Read more.
The recovery and abatement of volatile organic compounds (VOCs) have received increasing attention due to their significant environmental and health impacts. Supported sulfonic acid materials have shown great potential in converting aromatic VOCs into their non-volatile derivatives through reactive adsorption. However, the anchoring state of sulfonic acid groups, which is closely related to the properties of the support, greatly affects their performance. In this study, two supported sulfonic acid materials, SZO and SMO, were prepared by treating ZrO2 and MgO with chlorosulfonic acid, respectively, to investigate the influence of the support properties on the anchoring state of sulfonic acid groups and their reactive adsorption performance for o-xylene. The supports, adsorbents, and adsorption products were extensively characterized, and the reactivity of SZO and SMO towards o-xylene was systematically compared. The results showed that sulfonic acid groups are anchored on the ZrO2 surface through covalent bonding, forming positively charged sulfonic acid sites ([O1.5Zr-O]δ−-SO3Hδ+) with a loading of 3.6 mmol/g. As a result, SZO exhibited excellent removal efficiency (≥91.3%) and high breakthrough adsorption capacity (ranging from 38.59 to 82.07 mg/g) for o-xylene in the temperature range of 130 –150 °C. In contrast, sulfonic acid groups are anchored on the MgO surface via ion-paired bonding, leading to the formation of negatively charged sulfonic acid sites ([O0.5Mg]+:OSO3H), which prevents their participation in the electrophilic sulfonation reaction with o-xylene molecules. This work provides new insights into tuning and enhancing the performance of supported sulfonic acid materials for the resource-oriented treatment of aromatic VOCs. Full article
(This article belongs to the Special Issue Applied Chemistry in Asia)
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18 pages, 3347 KiB  
Article
Assessment of Machine Learning-Driven Retrievals of Arctic Sea Ice Thickness from L-Band Radiometry Remote Sensing
by Ferran Hernández-Macià, Gemma Sanjuan Gomez, Carolina Gabarró and Maria José Escorihuela
Computers 2025, 14(8), 305; https://doi.org/10.3390/computers14080305 - 28 Jul 2025
Viewed by 160
Abstract
This study evaluates machine learning-based methods for retrieving thin Arctic sea ice thickness (SIT) from L-band radiometry, using data from the European Space Agency’s (ESA) Soil Moisture and Ocean Salinity (SMOS) satellite. In addition to the operational ESA product, three alternative approaches are [...] Read more.
This study evaluates machine learning-based methods for retrieving thin Arctic sea ice thickness (SIT) from L-band radiometry, using data from the European Space Agency’s (ESA) Soil Moisture and Ocean Salinity (SMOS) satellite. In addition to the operational ESA product, three alternative approaches are assessed: a Random Forest (RF) algorithm, a Convolutional Neural Network (CNN) that incorporates spatial coherence, and a Long Short-Term Memory (LSTM) neural network designed to capture temporal coherence. Validation against in situ data from the Beaufort Gyre Exploration Project (BGEP) moorings and the ESA SMOSice campaign demonstrates that the RF algorithm achieves robust performance comparable to the ESA product, despite its simplicity and lack of explicit spatial or temporal modeling. The CNN exhibits a tendency to overestimate SIT and shows higher dispersion, suggesting limited added value when spatial coherence is already present in the input data. The LSTM approach does not improve retrieval accuracy, likely due to the mismatch between satellite resolution and the temporal variability of sea ice conditions. These results highlight the importance of L-band sea ice emission modeling over increasing algorithm complexity and suggest that simpler, adaptable methods such as RF offer a promising foundation for future SIT retrieval efforts. The findings are relevant for refining current methods used with SMOS and for developing upcoming satellite missions, such as ESA’s Copernicus Imaging Microwave Radiometer (CIMR). Full article
(This article belongs to the Special Issue Machine Learning and Statistical Learning with Applications 2025)
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15 pages, 2504 KiB  
Article
The Effect of the Interaction of Intense Low-Energy Radiation with a Zinc-Oxide-Based Material
by Ihor Virt, Piotr Potera, Nazar Barchuk and Mykola Chekailo
Crystals 2025, 15(8), 685; https://doi.org/10.3390/cryst15080685 - 28 Jul 2025
Viewed by 125
Abstract
Laser annealing of oxide functional thin films makes them compatible with substrates of various types, especially flexible materials. The effects of optical annealing on Ni-doped ZnO thin films were the subject of investigation and analysis in this study. Using pulsed laser deposition, we [...] Read more.
Laser annealing of oxide functional thin films makes them compatible with substrates of various types, especially flexible materials. The effects of optical annealing on Ni-doped ZnO thin films were the subject of investigation and analysis in this study. Using pulsed laser deposition, we deposited polycrystalline ZnNiO films on sapphire and silicon substrates. The deposited film was annealed by laser heating. A continuous CO2 laser was used for this purpose. The uniformly distributed long-wavelength radiation of the CO2 laser can penetrate deeper from the surface of the thin film compared to short-wavelength lasers such as UV and IR lasers. After growth, optical post-annealing processes were applied to improve the conductive properties of the films. The crystallinity and surface morphology of the grown films and annealed films were analyzed using SEM, and their electrical parameters were evaluated using van der Pauw effect measurements. We used electrical conductivity measurements and investigated the photovoltaic properties of the ZnNiO film. After CO2 laser annealing, changes in both the crystalline structure and surface appearance of ZnO were evident. Subsequent to laser annealing, the crystallinity of ZnO showed both change and degradation. High-power CO2 laser annealing changed the structure to a mixed grain size. Surface nanostructuring occurred. This was confirmed by SEM morphological studies. After irradiation, the electrical conductivity of the films increased from 0.06 Sm/cm to 0.31 Sm/cm. The lifetime of non-equilibrium charge carriers decreased from 2.0·10−9 s to 1.2·10−9 s. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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13 pages, 2039 KiB  
Article
Establishment of Singleplex and Duplex TaqMan RT-qPCR Detection Systems for Strawberry Mottle Virus (SMoV) and Strawberry Vein Banding Virus (SVBV)
by Tengfei Xu, Dehang Gao, Mengmeng Wu, Hongqing Wang and Chengyong He
Plants 2025, 14(15), 2330; https://doi.org/10.3390/plants14152330 - 27 Jul 2025
Viewed by 247
Abstract
SMoV and SVBV are two major viruses that pose significant threats to the global strawberry industry. Both are latent viruses, making early detection difficult due to their uneven distribution and low concentration in host tissues. Traditional RT-PCR techniques are insufficient for precise and [...] Read more.
SMoV and SVBV are two major viruses that pose significant threats to the global strawberry industry. Both are latent viruses, making early detection difficult due to their uneven distribution and low concentration in host tissues. Traditional RT-PCR techniques are insufficient for precise and quantitative detection. In this study, TaqMan RT-qPCR detection systems for SMoV and SVBV were established for application in practical production settings, enabling accurate, rapid, and efficient detection of strawberry viruses. When viral accumulation in plants is low, the highly sensitive TaqMan RT-qPCR technique allows for accurate quantification, facilitating the early identification of infected plants and preventing large-scale outbreaks in cultivation areas. The development of a duplex TaqMan RT-qPCR assay enables simultaneous quantification of SMoV and SVBV in a single reaction, improving detection efficiency and providing technical support for risk assessment and effective control of strawberry viral diseases. Full article
(This article belongs to the Section Plant Molecular Biology)
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19 pages, 7965 KiB  
Article
The Influence of Light Rare-Earth Substitution on Electronic and Magnetic Properties of CoFe2O4 Nanoparticles
by Rareș Bortnic, Adam Szatmari, Tiberiu Dragoiu, Radu George Hategan, Roman Atanasov, Lucian Barbu-Tudoran, Coriolan Tiusan, Raluca Lucacel-Ciceo, Roxana Dudric and Romulus Tetean
Nanomaterials 2025, 15(15), 1152; https://doi.org/10.3390/nano15151152 - 25 Jul 2025
Viewed by 237
Abstract
Co0.95R0.05Fe2O4 nanoparticles with R = La, Pr, Nd, Sm, and Eu were synthesized via an environmentally friendly sol–gel method. The prepared samples were studied using X-ray diffraction measurements (XRD), transmission electron microscopy (TEM), X-ray photoelectron microscopy [...] Read more.
Co0.95R0.05Fe2O4 nanoparticles with R = La, Pr, Nd, Sm, and Eu were synthesized via an environmentally friendly sol–gel method. The prepared samples were studied using X-ray diffraction measurements (XRD), transmission electron microscopy (TEM), X-ray photoelectron microscopy (XPS), and magnetic measurements. All compounds were found to be single phases adopting a cubic Fd-3m structure. EDS analysis confirmed the presence of Co, Fe, R, and oxygen in all cases. The XPS measurements reveal that the Co 2p core-level spectra are characteristic for Co3+ ions, as indicated by the 2p3/2 and 2p1/2 binding energies and spin–orbit splitting values. The analysis of the Fe 2p core-level spectra reveals the presence of both Fe3+ and Fe2+ ions in the investigated samples. The doped samples exhibit lower saturation magnetizations than the pristine sample. Very good agreement with the saturation magnetization values was obtained if we assumed that the light rare-earth ions occupy octahedral sites and their magnetic moments align parallel to those of the 3d transition metal ions. The ZFC-FC curves indicate that some nanoparticles remain superparamagnetic, while others exhibit ferrimagnetic ordering at room temperature, suggesting the presence of interparticle interactions. The Mr/Ms ratio at room temperature reflects the dominance of magnetostatic interactions. Full article
(This article belongs to the Section Nanophotonics Materials and Devices)
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17 pages, 3361 KiB  
Technical Note
Noise Mitigation of the SMOS L1C Multi-Angle Brightness Temperature Based on the Lookup Table
by Ke Chen, Ruile Wang, Qian Yang, Jiaming Chen and Jun Gong
Remote Sens. 2025, 17(15), 2585; https://doi.org/10.3390/rs17152585 - 24 Jul 2025
Viewed by 142
Abstract
Owing to the inherently lower sensitivity of microwave aperture synthesis radiometers (ASRs), Soil Moisture and Ocean Salinity (SMOS) satellite brightness temperature (TB) measurements exhibit significantly greater system noise than real-aperture microwave radiometers do. This paper introduces a novel noise mitigation method for the [...] Read more.
Owing to the inherently lower sensitivity of microwave aperture synthesis radiometers (ASRs), Soil Moisture and Ocean Salinity (SMOS) satellite brightness temperature (TB) measurements exhibit significantly greater system noise than real-aperture microwave radiometers do. This paper introduces a novel noise mitigation method for the SMOS L1C multi-angle TB product. The proposed method develops a multi-angle sea surface TB relationship lookup table, enabling the mapping of SMOS L1C multi-angle TB data to any single-angle TB, thereby averaging to the measurements to reduce noise. Validation experiments demonstrate that the processed SMOS TB data achieve noise levels comparable to those of the Soil Moisture Active Passive (SMAP) satellite. Additionally, the salinity retrieval experiments indicate that the noise mitigation technique has a clear positive effect on SMOS salinity retrieval. Full article
(This article belongs to the Special Issue Recent Advances in Microwave and Millimeter-Wave Imaging Sensing)
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18 pages, 2163 KiB  
Article
Transmission Opportunity and Throughput Prediction for WLAN Access Points via Multi-Dimensional Feature Modeling
by Wei Li, Xin Huang, Danju Lv, Yueyun Yu, Yan Zhang, Zhicheng Zhu and Ting Zhou
Electronics 2025, 14(15), 2941; https://doi.org/10.3390/electronics14152941 - 23 Jul 2025
Viewed by 223
Abstract
With the rapid development of wireless communication, Wireless Local Area Networks (WLANs) are widely deployed in high-density environments. Ensuring fast handovers and optimal AP selection during device roaming is critical for maintaining network throughput and user experience. However, frequent mobility, high access density, [...] Read more.
With the rapid development of wireless communication, Wireless Local Area Networks (WLANs) are widely deployed in high-density environments. Ensuring fast handovers and optimal AP selection during device roaming is critical for maintaining network throughput and user experience. However, frequent mobility, high access density, and dynamic channel fluctuations complicate throughput prediction. To address this, we propose a method combining the Snow-Melting Optimizer (SMO) with decision tree regression models to optimize feature selection and model transmission opportunities (TXOP) and AP throughput. Experimental results show that the Extreme Gradient Boosting (XGBoost) model performs best, achieving high prediction accuracy for TXOP (MSE = 1.3746, R2 = 0.9842) and AP throughput (MAE = 2.5071, R2 = 0.9896). This approach effectively captures the nonlinear relationships between throughput and network factors in dense WLAN scenarios, demonstrating its potential for real-world applications. Full article
(This article belongs to the Special Issue AI in Network Security: New Opportunities and Threats)
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25 pages, 2029 KiB  
Article
Germination Enhances Phytochemical Profiles of Perilla Seeds and Promotes Hair Growth via 5α-Reductase Inhibition and Growth Factor Pathways
by Anurak Muangsanguan, Warintorn Ruksiriwanich, Pichchapa Linsaenkart, Pipat Tangjaidee, Korawan Sringarm, Chaiwat Arjin, Pornchai Rachtanapun, Sarana Rose Sommano, Korawit Chaisu, Apinya Satsook and Juan Manuel Castagnini
Biology 2025, 14(7), 889; https://doi.org/10.3390/biology14070889 - 20 Jul 2025
Viewed by 420
Abstract
Seed germination is recognized for enhancing the accumulation of bioactive compounds. Perilla frutescens (L.) Britt., commonly known as perilla seed, is rich in fatty acids that may be beneficial for anti-hair loss. This study investigated the hair regeneration potential of perilla seed extracts—non-germinated [...] Read more.
Seed germination is recognized for enhancing the accumulation of bioactive compounds. Perilla frutescens (L.) Britt., commonly known as perilla seed, is rich in fatty acids that may be beneficial for anti-hair loss. This study investigated the hair regeneration potential of perilla seed extracts—non-germinated (NG-PS) and germinated in distilled water (0 ppm selenium; G0-PS), and germinated with 80 ppm selenium (G80-PS)—obtained from supercritical fluid extraction (SFE) and screw compression (SC). SFE extracts exhibited significantly higher levels of polyphenols, tocopherols, and fatty acids compared to SC extracts. Among the germinated groups, G0-PS showed the highest bioactive compound content and antioxidant capacity. Remarkably, treatment with SFE-G0-PS led to a significant increase in the proliferation and migration of hair follicle cells, reaching 147.21 ± 2.11% (p < 0.05), and resulted in complete wound closure. In addition, its antioxidant and anti-inflammatory properties were reflected by a marked scavenging effect on TBARS (59.62 ± 0.66% of control) and suppressed nitrite amounts (0.44 ± 0.01 µM). Moreover, SFE-G0-PS markedly suppressed SRD5A1-3 gene expression—key regulators in androgenetic alopecia—in both DU-145 and HFDPCs, with approximately 2-fold and 1.5-fold greater inhibition compared to finasteride and minoxidil, respectively. Simultaneously, it upregulated the expression of hair growth-related genes, including CTNNB1, SHH, SMO, GLI1, and VEGF, by approximately 1.5-fold, demonstrating stronger activation than minoxidil. These findings suggest the potential of SFE-G0-PS as a natural therapeutic agent for promoting hair growth and preventing hair loss. Full article
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13 pages, 1527 KiB  
Article
Ethnic-Specific and UV-Independent Mutational Signatures of Basal Cell Carcinoma in Koreans
by Ye-Ah Kim, Seokho Myung, Yueun Choi, Junghyun Kim, Yoonsung Lee, Kiwon Lee, Bark-Lynn Lew, Man S. Kim and Soon-Hyo Kwon
Int. J. Mol. Sci. 2025, 26(14), 6941; https://doi.org/10.3390/ijms26146941 - 19 Jul 2025
Viewed by 282
Abstract
Basal cell carcinoma (BCC), the most common skin cancer, is primarily driven by Hedgehog (Hh) and TP53 pathway alterations. Although additional pathways were implicated, the mutational landscape in Asian populations, particularly Koreans, remains underexplored. We performed whole-exome sequencing of BCC tumor tissues from [...] Read more.
Basal cell carcinoma (BCC), the most common skin cancer, is primarily driven by Hedgehog (Hh) and TP53 pathway alterations. Although additional pathways were implicated, the mutational landscape in Asian populations, particularly Koreans, remains underexplored. We performed whole-exome sequencing of BCC tumor tissues from Korean patients and analyzed mutations in 11 established BCC driver genes (PTCH1, SMO, GLI1, TP53, CSMD1/2, NOTCH1/2, ITIH2, DPP10, and STEAP4). Mutational profiles were compared with Caucasian cohort profiles to identify ethnicity-specific variants. Ultraviolet (UV)-exposed and non-UV-exposed tumor sites were compared; genes unique to non-UV-exposed tumors were further analyzed with protein–protein interaction analysis. BCCs in Koreans exhibited distinct features, including fewer truncating and more intronic variants compared to Caucasians. Korean-specific mutations in SMO, PTCH1, TP53, and NOTCH2 overlapped with oncogenic gain-of-function/loss-of-function (GOF/LOF) variants annotated in OncoKB, with some occurring at hotspot sites. BCCs in non-exposed areas showed recurrent mutations in CSMD1, PTCH1, and NOTCH1, suggesting a UV-independent mechanism. Novel mutations in TAS1R2 and ADCY10 were exclusive to non-exposed BCCs, with protein–protein interaction analysis linking them to TP53 and NOTCH2. We found unique ethnic-specific and UV-independent mutational profiles of BCCs in Koreans. TAS1R2 and ADCY10 may contribute to tumorigenesis of BCC in non-exposed areas, supporting the need for population-specific precision oncology. Full article
(This article belongs to the Special Issue Skin Cancer: From Molecular Pathophysiology to Novel Treatment)
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19 pages, 2954 KiB  
Article
Maximum Power Extraction of Photovoltaic Systems Using Dynamic Sliding Mode Control and Sliding Observer
by Ali Karami-Mollaee and Oscar Barambones
Mathematics 2025, 13(14), 2305; https://doi.org/10.3390/math13142305 - 18 Jul 2025
Viewed by 183
Abstract
In this paper, a robust optimized controller is implemented in the photovoltaic generator system (PVGS). The PVGS is composed of individual photovoltaic (PV) cells, which convert solar energy to electrical energy. To optimize the efficiency of the PVGS under variable solar irradiance and [...] Read more.
In this paper, a robust optimized controller is implemented in the photovoltaic generator system (PVGS). The PVGS is composed of individual photovoltaic (PV) cells, which convert solar energy to electrical energy. To optimize the efficiency of the PVGS under variable solar irradiance and temperatures, a maximum power point tracking (MPPT) controller is necessary. Additionally, the PVGS output voltage is typically low for many applications. To achieve the MPPT and to gain the output voltage, an increasing boost converter (IBC) is employed. Then, two issues should be considered in MPPT. At first, a smooth control signal for adjusting the duty cycle of the IBC is important. Another critical issue is the PVGS and IBC unknown sections, i.e., the total system uncertainty. Therefore, to address the system uncertainties and to regulate the smooth duty cycle of the converter, a robust dynamic sliding mode control (DSMC) is proposed. In DSMC, a low-pass integrator is placed before the system to suppress chattering and to produce a smooth actuator signal. However, this integrator increases the system states, and hence, a sliding mode observer (SMO) is proposed to estimate this additional state. The stability of the proposed control scheme is demonstrated using the Lyapunov theory. Finally, to demonstrate the effectiveness of the proposed method and provide a reliable comparison, conventional sliding mode control (CSMC) with the same proposed SMO is also implemented. Full article
(This article belongs to the Special Issue Applied Mathematics and Intelligent Control in Electrical Engineering)
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19 pages, 6796 KiB  
Article
Performance Assessment of Advanced Daily Surface Soil Moisture Products in China for Sustainable Land and Water Management
by Dai Chen, Zhounan Dong and Jingnan Chen
Sustainability 2025, 17(14), 6482; https://doi.org/10.3390/su17146482 - 15 Jul 2025
Viewed by 225
Abstract
This study evaluates the performance of nine satellite and model-based daily surface soil moisture products, encompassing sixteen algorithm versions across mainland China to support sustainable land and water management. The assessment utilizes 2018 in situ measurements from over 2400 stations in China’s Automatic [...] Read more.
This study evaluates the performance of nine satellite and model-based daily surface soil moisture products, encompassing sixteen algorithm versions across mainland China to support sustainable land and water management. The assessment utilizes 2018 in situ measurements from over 2400 stations in China’s Automatic Soil Moisture Monitoring Network. All products were standardized to a 0.25° × 0.25° grid in the WGS-84 coordinate system through reprojection and resampling for consistent comparison. Daily averaged station observations were matched to product pixels using a 10 km radius buffer, with the mean station value as the reference for each time series after rigorous quality control. Results reveal distinct performance rankings, with SMAP-based products, particularly the SMAP_IB descending orbit variant, achieving the lowest unbiased root mean square deviation (ubRMSD) and highest correlation with in situ data. Blended products like ESA CCI and NOAA SMOPS, alongside reanalysis datasets such as ERA5 and MERRA2, outperformed SMOS and China’s FY3 products. The SoMo.ml product showed the broadest spatial coverage and strong temporal consistency, while FY3-based products showed limitations in spatial reliability and seasonal dynamics capture. These findings provide critical insights for selecting appropriate soil moisture datasets to enhance sustainable agricultural practices, optimize water resource allocation, monitor ecosystem resilience, and support climate adaptation strategies, therefore advancing sustainable development across diverse geographical regions in China. Full article
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20 pages, 4894 KiB  
Article
Ag-Cu Synergism-Driven Oxygen Structure Modulation Promotes Low-Temperature NOx and CO Abatement
by Ruoxin Li, Jiuhong Wei, Bin Jia, Jun Liu, Xiaoqing Liu, Ying Wang, Yuqiong Zhao, Guoqiang Li and Guojie Zhang
Catalysts 2025, 15(7), 674; https://doi.org/10.3390/catal15070674 - 11 Jul 2025
Viewed by 352
Abstract
The efficient simultaneous removal of NOx and CO from sintering flue gas under low-temperature conditions (110–180 °C) in iron and steel enterprises remains a significant challenge in the field of environmental catalysis. In this study, we present an innovative strategy to enhance [...] Read more.
The efficient simultaneous removal of NOx and CO from sintering flue gas under low-temperature conditions (110–180 °C) in iron and steel enterprises remains a significant challenge in the field of environmental catalysis. In this study, we present an innovative strategy to enhance the performance of CuSmTi catalysts through silver modification, yielding a bifunctional system capable of oxygen structure regulation and demonstrating superior activity for the combined NH3-SCR and CO oxidation reactions under low-temperature, oxygen-rich conditions. The modified AgCuSmTi catalyst achieves complete NO conversion at 150 °C, representing a 50 °C reduction compared to the unmodified CuSmTi catalyst (T100% = 200 °C). Moreover, the catalyst exhibits over 90% N2 selectivity across a broad temperature range of 150–300 °C, while achieving full CO oxidation at 175 °C. A series of characterization techniques, including XRD, Raman spectroscopy, N2 adsorption, XPS, and O2-TPD, were employed to elucidate the Ag-Cu interaction. These modifications effectively optimize the surface physical structure, modulate the distribution of acid sites, increase the proportion of Lewis acid sites, and enhance the activity of lattice oxygen species. As a result, they effectively promote the adsorption and activation of reactants, as well as electron transfer between active species, thereby significantly enhancing the low-temperature performance of the catalyst. Furthermore, in situ DRIFTS investigations reveal the reaction mechanisms involved in NH3-SCR and CO oxidation over the Ag-modified CuSmTi catalyst. The NH3-SCR process predominantly follows the L-H mechanism, with partial contribution from the E-R mechanism, whereas CO oxidation proceeds via the MvK mechanism. This work demonstrates that Ag modification is an effective approach for enhancing the low-temperature performance of CuSmTi-based catalysts, offering a promising technical solution for the simultaneous control of NOx and CO emissions in industrial flue gases. Full article
(This article belongs to the Special Issue Environmentally Friendly Catalysis for Green Future)
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