Preparation, Separation, Characterization and Application of Carbon Nanotubes

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "2D and Carbon Nanomaterials".

Deadline for manuscript submissions: 20 October 2024 | Viewed by 707

Special Issue Editor


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Guest Editor
Security and Disruptive Technologies Research Centre, National Research Council of Canada, 1200 Montreal Road, M-12, Ottawa, ON K1A 0R6, Canada
Interests: carbon nanotubes; conjugated polymers; transistors; sensors

Special Issue Information

Dear Colleagues,

Since the seminal discovery of carbon nanotubes by Sumio Iijima more than 30 years ago, research interest in this field has grown dramatically due to their unique optical and electronic properties. Synthesized raw tube material usually contains both semiconducting and metallic tubes with a wide diameter and chirality distribution, besides some other impurities, which means that it is usually not good enough for practical usage. Synthetic techniques have been improved substantially by finetuning the catalyst and preparation conditions used. Post-synthesis separation has also been sought out. The purity requirement is heavily dependent on the application. For example, for thin film transistors with channel lengths over 10 um, 99.9% semiconducting purity could be enough, but 99.9999% is desired for high-performance short-channel field-effect transistors. For optical applications, high-purity single-chirality samples are needed. Currently, high semiconducting purity and some single-chirality carbon nanotubes could be easily obtained from solution processes.

The present Special Issue of Nanomaterials is aimed at presenting the current state-of-the-art research related to carbon nanotubes, covering not only the preparation and enrichment process to address purity and chiral selectivity issues but also device applications, such as thin film transistors, photodetectors, single photo emission and sensors. For this Special Issue, we welcome contributions from leading groups in the field and hope to give a balanced view of the current state of the art in this discipline.

Dr. Zhao Li
Guest Editor

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Keywords

  • carbon nanotubes
  • purification
  • enrichment
  • transistors
  • sensors

Published Papers (2 papers)

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Research

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12 pages, 6429 KiB  
Article
Improving the Adhesion of Multi-Walled Carbon Nanotubes to Titanium by Irradiating the Interface with He+ Ions: Atomic Force Microscopy and X-ray Photoelectron Spectroscopy Study
by Petr M. Korusenko, Egor V. Knyazev, Olga V. Petrova, Denis V. Sokolov, Sergey N. Povoroznyuk, Konstantin E. Ivlev, Ksenia A. Bakina, Vyacheslav A. Gaas and Alexander S. Vinogradov
Nanomaterials 2024, 14(8), 699; https://doi.org/10.3390/nano14080699 - 17 Apr 2024
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Abstract
A complex study of the adhesion of multi-walled carbon nanotubes to a titanium surface, depending on the modes of irradiation with He+ ions of the “MWCNT/Ti” system, was conducted using atomic force microscopy and X-ray photoelectron spectroscopy. A quantitative assessment of the [...] Read more.
A complex study of the adhesion of multi-walled carbon nanotubes to a titanium surface, depending on the modes of irradiation with He+ ions of the “MWCNT/Ti” system, was conducted using atomic force microscopy and X-ray photoelectron spectroscopy. A quantitative assessment of the adhesion force at the interface, performed using atomic force microscopy, demonstrated its significant increase as a result of treatment of the “MWCNT/Ti” system with a beam of helium ions. The nature of the chemical bonding between multi-walled carbon nanotubes and the surface of the titanium substrate, which causes this increase in the adhesion of nanotubes to titanium as a result of ion irradiation, was investigated by X-ray photoelectron spectroscopy. It was established that this bonding is the result of the formation of chemical C–O–Ti bonds between titanium and carbon atoms with the participation of oxygen atoms of oxygen-containing functional groups, which are localized on defects in the nanotube walls formed during ion irradiation. It is significant that there are no signs of direct bonding between titanium and carbon atoms. Full article
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Review

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21 pages, 3745 KiB  
Review
The Effectiveness Mechanisms of Carbon Nanotubes (CNTs) as Reinforcements for Magnesium-Based Composites for Biomedical Applications: A Review
by Abbas Saberi, Madalina Simona Baltatu and Petrica Vizureanu
Nanomaterials 2024, 14(9), 756; https://doi.org/10.3390/nano14090756 (registering DOI) - 25 Apr 2024
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Abstract
As a smart implant, magnesium (Mg) is highly biocompatible and non-toxic. In addition, the elastic modulus of Mg relative to other biodegradable metals (iron and zinc) is close to the elastic modulus of natural bone, making Mg an attractive alternative to hard tissues. [...] Read more.
As a smart implant, magnesium (Mg) is highly biocompatible and non-toxic. In addition, the elastic modulus of Mg relative to other biodegradable metals (iron and zinc) is close to the elastic modulus of natural bone, making Mg an attractive alternative to hard tissues. However, high corrosion rates and low strength under load relative to bone are some challenges for the widespread use of Mg in orthopedics. Composite fabrication has proven to be an excellent way to improve the mechanical performance and corrosion control of Mg. As a result, their composites emerge as an innovative biodegradable material. Carbon nanotubes (CNTs) have superb properties like low density, high tensile strength, high strength-to-volume ratio, high thermal conductivity, and relatively good antibacterial properties. Therefore, using CNTs as reinforcements for the Mg matrix has been proposed as an essential option. However, the lack of understanding of the mechanisms of effectiveness in mechanical, corrosion, antibacterial, and cellular fields through the presence of CNTs as Mg matrix reinforcements is a challenge for their application. This review focuses on recent findings on Mg/CNT composites fabricated for biological applications. The literature mentions effective mechanisms for mechanical, corrosion, antimicrobial, and cellular domains with the presence of CNTs as reinforcements for Mg-based nanobiocomposites. Full article
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