Grinding and Concentration Technology of Critical Metals

A special issue of Metals (ISSN 2075-4701).

Deadline for manuscript submissions: closed (30 November 2021) | Viewed by 26413

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Guest Editor
Escuela Politécnica de Mieres, Universidad de Oviedo, 33600 Mieres, Spain
Interests: comminution; energy efficiency; mineral processing; mineral waste streams; critical raw material production; process technoeconomic analysis; sustainability; circular economy of minerals
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Special Issue Information

Dear Colleagues,

The global raw materials sector is expected to experience a noticeable shift towards new production methods in the coming decades. Climate change, cleaner production ways, and circular economy requirements must be conjugated to make new production routes greener, cleaner, and more efficient. This is going to be especially crucial in the case of the sources of critical metals. In the particular case of grinding operations, which is estimated to be up to 4% of global energy consumption—with very low efficiency—a really big challenge is faced. According to the US Department of Energy estimations (https://www.energy.gov/sites/prod/files/2013/11/f4/mining_bandwidth.pdf), a reduction of about 20% of grinding energy consumption could be reached just by applying the best available techniques (state-of-the-art equipment), and this reduction could reach up to 50% with the results of research and innovation efforts.

The purpose of this Special Issue is to provide papers featuring the latest developments in the field of grinding technology applied to the production of critical metals from primary and secondary resources. This Special Issue welcomes work conducted in the following research areas: modeling and simulation in critical metals comminution, improvements in energy efficiency in conventional comminution, and new strategies to reduce grindability in critical metals ores (physical or chemical: grinding aids, microwave pretreatments, electrofragmentation, etc).

Dr. Juan M Menéndez-Aguado
Guest Editor

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Keywords

  • Grindability
  • Comminution
  • Modeling and simulation
  • Milling
  • Critical metals
  • Energy efficiency
  • Crushing
  • Grinding
  • Size classification
  • Ore sorting
  • Gravity separation
  • Magnetic separation
  • High tension separation
  • Froth flotation

Published Papers (11 papers)

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Editorial

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3 pages, 182 KiB  
Editorial
Grinding and Concentration Technology of Critical Metals
by Juan M. Menéndez Aguado
Metals 2022, 12(4), 585; https://doi.org/10.3390/met12040585 - 30 Mar 2022
Viewed by 1126
Abstract
The production and supply of raw materials in a global market are not without risks, and both the recent COVID-19 pandemic and the current one (Russia–Ukrania conflict) raised public awareness about the importance of multiple value chains [...] Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)

Research

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13 pages, 3365 KiB  
Article
Study of Comminution Kinetics in an Electrofragmentation Lab-Scale Device
by Angel R. Llera, Ana Díaz, Francisco J. Pedrayes, Juan M. Menéndez-Aguado and Manuel G. Melero
Metals 2022, 12(3), 494; https://doi.org/10.3390/met12030494 - 14 Mar 2022
Cited by 3 | Viewed by 1576
Abstract
A significant challenge in mineral raw materials comminution is the improvement of process energy efficiency. Conventional comminution techniques, although globally used, are far from being considered power-efficient. The use of high-voltage electric pulses in comminution is a concept that is worthy of study; [...] Read more.
A significant challenge in mineral raw materials comminution is the improvement of process energy efficiency. Conventional comminution techniques, although globally used, are far from being considered power-efficient. The use of high-voltage electric pulses in comminution is a concept that is worthy of study; despite its lack of industrial-scale validation after several decades of lab-scale research, it seems promising as a pretreatment leading to energy savings. In this article, the Cumulative Kinetic Model methodology is adapted to model the comminution effect in an electrofragmentation device, and study a dunite rock ore. The results show that product particle size distribution (PSD) can be predicted with reasonable accuracy using the proposed model. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
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7 pages, 258 KiB  
Article
Variability of the Ball Mill Bond’s Standard Test in a Ta Ore Due to the Lack of Standardization
by Gloria González García, Alfredo L. Coello-Velázquez, Begoña Fernández Pérez and Juan M. Menéndez-Aguado
Metals 2021, 11(10), 1606; https://doi.org/10.3390/met11101606 - 9 Oct 2021
Cited by 5 | Viewed by 1310
Abstract
There is no doubt about the practical interest of Fred Bond’s methodology in the field of comminution, not only in tumbling mills design and operation but also in mineral raw materials grindability characterization. Increasing energy efficiency in comminution operations globally is considered a [...] Read more.
There is no doubt about the practical interest of Fred Bond’s methodology in the field of comminution, not only in tumbling mills design and operation but also in mineral raw materials grindability characterization. Increasing energy efficiency in comminution operations globally is considered a significant challenge involving several Sustainable Development Goals (SDGs). In particular, the Bond work index (wi) is considered a critical parameter at an industrial scale, provided that power consumption in comminution operations accounts for up to 40% of operational costs. Despite this, the variability of wi when performing the ball mill Bond’s standard test is not always understood enough. This study shows the results of a variability analysis (a 33 factorial design) performed to elucidate the influence on wi of several parameters obtained from the particle size distribution (PSD) in feed and product. Results showed a clear variability in the work and grindability indexes with some of the variables considered. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
12 pages, 1686 KiB  
Article
Particle Size Distribution Models for Metallurgical Coke Grinding Products
by Laura Colorado-Arango, Juan M. Menéndez-Aguado and Adriana Osorio-Correa
Metals 2021, 11(8), 1288; https://doi.org/10.3390/met11081288 - 16 Aug 2021
Cited by 12 | Viewed by 2635
Abstract
Six different particle size distribution (Gates–Gaudin–Schuhmann (GGS), Rosin–Rammler (RR), Lognormal, Normal, Gamma, and Swebrec) models were compared under different metallurgical coke grinding conditions (ball size and grinding time). Adjusted R2, Akaike information criterion (AIC), and the root mean of square error [...] Read more.
Six different particle size distribution (Gates–Gaudin–Schuhmann (GGS), Rosin–Rammler (RR), Lognormal, Normal, Gamma, and Swebrec) models were compared under different metallurgical coke grinding conditions (ball size and grinding time). Adjusted R2, Akaike information criterion (AIC), and the root mean of square error (RMSE) were employed as comparison criteria. Swebrec and RR presented superior comparison criteria with the higher goodness-of-fit and the lower AIC and RMSE, containing the minimum variance values among data. The worst model fitting was GGS, with the poorest comparison criteria and a wider results variation. The undulation Swebrec parameter was ball size and grinding time-dependent, considering greater b values (b > 3) at longer grinding times. The RR α parameter does not exhibit a defined tendency related to grinding conditions, while the k parameter presents smaller values at longer grinding times. Both models depend on metallurgical coke grinding conditions and are hence an indication of the grinding behaviour. Finally, oversize and ultrafine particles are found with ball sizes of 4.0 cm according to grinding time. The ball size of 2.54 cm shows slight changes in particle median diameter over time, while 3.0 cm ball size requires more grinding time to reduce metallurgical coke particles. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
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11 pages, 1236 KiB  
Article
Unveiling the Link between the Third Law of Comminution and the Grinding Kinetics Behaviour of Several Ores
by Victor Ciribeni, Juan M. Menéndez-Aguado, Regina Bertero, Andrea Tello, Enzo Avellá, Matías Paez and Alfredo L. Coello-Velázquez
Metals 2021, 11(7), 1079; https://doi.org/10.3390/met11071079 - 5 Jul 2021
Cited by 4 | Viewed by 1542
Abstract
As a continuation of a previous research work carried out to estimate the Bond work index (wi) by using a simulator based on the cumulative kinetic model (CKM), a deeper analysis was carried out to determine the link between the [...] Read more.
As a continuation of a previous research work carried out to estimate the Bond work index (wi) by using a simulator based on the cumulative kinetic model (CKM), a deeper analysis was carried out to determine the link between the kinetic and energy parameters in the case of metalliferous and non-metallic ore samples. The results evidenced a relationship between the CKM kinetic parameter k and the grindability index gbp; and also with the wi, obtained following the standard procedure. An excellent correlation was obtained in both cases, posing the definition of alternative work index estimation tests with the advantages of more straightforward and quicker laboratory procedures. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
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11 pages, 2697 KiB  
Article
Variability Study of Bond Work Index and Grindability Index on Various Critical Metal Ores
by Gloria G. García, Josep Oliva, Eduard Guasch, Hernán Anticoi, Alfredo L. Coello-Velázquez and Juan M. Menéndez-Aguado
Metals 2021, 11(6), 970; https://doi.org/10.3390/met11060970 - 17 Jun 2021
Cited by 11 | Viewed by 3351
Abstract
It is a well-known fact that the value of the Bond work index (wi) for a given ore varies along with the grinding size. In this study, a variability bysis is carried out with the Bond standard grindability tests on [...] Read more.
It is a well-known fact that the value of the Bond work index (wi) for a given ore varies along with the grinding size. In this study, a variability bysis is carried out with the Bond standard grindability tests on different critical metal ores (W, Ta), ranging from coarse grinding (rod mills) to fine grinding (ball mills). The relationship between wi and grinding size did not show a clear correlation, while the grindability index (gpr) and the grinding size showed a robust correlation, fitting in all cases to a quadratic curve with a very high regression coefficient. This result suggests that, when performing correlation studies among ore grindability and rock mechanics parameters, it is advised to use the grindability index instead of the Bond work index. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
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11 pages, 1809 KiB  
Article
A Comparative Study of Energy Efficiency in Tumbling Mills with the Use of Relo Grinding Media
by Nikolay Kolev, Petar Bodurov, Vassil Genchev, Ben Simpson, Manuel G. Melero and Juan M. Menéndez-Aguado
Metals 2021, 11(5), 735; https://doi.org/10.3390/met11050735 - 29 Apr 2021
Cited by 6 | Viewed by 3323
Abstract
An evaluation of Relo grinding media (RGM, Reuleaux tetrahedron-shaped bodies) performance versus standard grinding media (balls) was made through a series of grinding tests, including a slight modification of the standard Bond test procedure. Standard Bond tests showed a reduction in the Bond [...] Read more.
An evaluation of Relo grinding media (RGM, Reuleaux tetrahedron-shaped bodies) performance versus standard grinding media (balls) was made through a series of grinding tests, including a slight modification of the standard Bond test procedure. Standard Bond tests showed a reduction in the Bond ball mill work index (wi) of the mineral sample used in this study when using Relo grinding media. The modified Bond test procedure is based on using the standard Bond ball work index test but changing the circulating loads (350%, 250%, 150%, 100%). The comparative tests with RGM were carried out at the same number of revolutions as the grinding tests with balls at respective circulating load. The RGM charge yielded a 14% higher net undersize product than balls, which hints at improving energy efficiency and the potential for significant mining industry benefits. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
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13 pages, 6813 KiB  
Article
Grinding Kinetics Study of Tungsten Ore
by Jennire V. Nava, Alfredo L. Coello-Velázquez and Juan M. Menéndez-Aguado
Metals 2021, 11(1), 71; https://doi.org/10.3390/met11010071 - 31 Dec 2020
Cited by 10 | Viewed by 1866
Abstract
The European Commission (EC) maintains the consideration of tungsten as a critical raw material for the European industry, being the comminution stage of tungsten-bearing minerals an essential step in the tungsten concentration process. Comminution operations involve approximately 3–4% of worldwide energy consumption; therefore, [...] Read more.
The European Commission (EC) maintains the consideration of tungsten as a critical raw material for the European industry, being the comminution stage of tungsten-bearing minerals an essential step in the tungsten concentration process. Comminution operations involve approximately 3–4% of worldwide energy consumption; therefore, grinding optimization should be a priority. In this study, the grinding behavior of tungsten ore from Barruecopardo Mine (Salamanca, Spain) is analyzed. A protocol based on Austin’s methodology and PBM is developed in order to study the influence of operational and geometallurgical variables on grinding kinetics. In addition to the kinetic parameters, the breakage probability (Si) and breakage function (Bij) is determined. The selection function was formulated for the Barruecopardo Mine with respect to the mill speed. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
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19 pages, 3723 KiB  
Article
Kinetics of Dry-Batch Grinding in a Laboratory-Scale Ball Mill of Sn–Ta–Nb Minerals from the Penouta Mine (Spain)
by Jenniree V. Nava, Teresa Llorens and Juan María Menéndez-Aguado
Metals 2020, 10(12), 1687; https://doi.org/10.3390/met10121687 - 17 Dec 2020
Cited by 9 | Viewed by 2627
Abstract
The optimization of processing plants is one of the main concerns in the mining industry, since the comminution stage, a fundamental operation, accounts for up to 70% of total energy consumption. The aim of this study was to determine the effects that ball [...] Read more.
The optimization of processing plants is one of the main concerns in the mining industry, since the comminution stage, a fundamental operation, accounts for up to 70% of total energy consumption. The aim of this study was to determine the effects that ball size and mill speed exert on the milling kinetics over a wide range of particle sizes. This was done through dry milling and batch grinding tests performed on two samples from the Penouta Sn–Ta–Nb mine (Galicia, Spain), and following Austin methodology. In addition, the relationships amongst Sn, Ta and Nb content, as metals of interest, the specific rate of breakage Si, the kinetic parameters, and the operational conditions were studied through X-Ray fluorescence (XRF) techniques. The results show that, overall, the specific rate of breakage Si decreases with decreasing feed particle size and increasing ball size for most of the tested conditions. A selection function, αT, was formulated on the basis of the ball size for both Penouta mine samples. Finally, it was found that there does exist a direct relationship amongst Sn, Ta and Nb content, as metals of interest, in the milling product, the specific rate of breakage Si and the operational–mineralogical variables of ball size, mill speed and feed particle size. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
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11 pages, 1023 KiB  
Article
Application of the Cumulative Kinetic Model in the Comminution of Critical Metal Ores
by Victor Ciribeni, Regina Bertero, Andrea Tello, Matías Puerta, Enzo Avellá, Matías Paez and Juan María Menéndez Aguado
Metals 2020, 10(7), 925; https://doi.org/10.3390/met10070925 - 9 Jul 2020
Cited by 10 | Viewed by 2360
Abstract
Over the last decades, several reliable mathematical models have been developed for simulating ore comminution processes and determining the Work Index. Since Fred Chester Bond developed the Work Index standard procedure in 1961, numerous attempts have been made to find simpler, faster, and [...] Read more.
Over the last decades, several reliable mathematical models have been developed for simulating ore comminution processes and determining the Work Index. Since Fred Chester Bond developed the Work Index standard procedure in 1961, numerous attempts have been made to find simpler, faster, and economically more advantageous alternative tests. In this paper, a Bond test simulation based on the cumulative kinetic model (CKM) has been checked on a spreadsheet. The research has been accomplished by conventionally determining the kinetic parameters for some Ag and Au ores and for three pure minerals and one rock that are common constituents of the gangue rock. Analysis of the results obtained allowed to develop a simplified procedure for calculating the kinetic parameters and their application to Work Index determination through simulation. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
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Review

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16 pages, 3837 KiB  
Review
A Review of Alternative Procedures to the Bond Ball Mill Standard Grindability Test
by Vladimir Nikolić, Gloria G. García, Alfredo L. Coello-Velázquez, Juan M. Menéndez-Aguado, Milan Trumić and Maja S. Trumić
Metals 2021, 11(7), 1114; https://doi.org/10.3390/met11071114 - 12 Jul 2021
Cited by 7 | Viewed by 2656
Abstract
Over the years, alternative procedures to the Bond grindability test have been proposed aiming to avoid the need for the standard mill or to reduce and simplify the grinding procedure. Some of them use the standard mill, while others are based on a [...] Read more.
Over the years, alternative procedures to the Bond grindability test have been proposed aiming to avoid the need for the standard mill or to reduce and simplify the grinding procedure. Some of them use the standard mill, while others are based on a non-standard mill or computation techniques. Therefore, papers targeting to propose a better alternative claim to improve validity, to reduce test duration, or to propose simpler and faster alternative methods for determining the Bond work index (wi). In this review paper, a compilation and critical analysis of selected proposals is performed, concluding that some of the short procedures could be useful for control purposes, while the simulation-based procedures could be interesting within a process digitalisation strategy. Full article
(This article belongs to the Special Issue Grinding and Concentration Technology of Critical Metals)
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