Progress in Advanced High-Entropy Alloy Design and Applications: Microstructures, Mechanical, Electrochemical and Tribological Properties

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Entropic Alloys and Meta-Metals".

Deadline for manuscript submissions: 30 June 2026 | Viewed by 3452

Editors


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Guest Editor
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, AB T6G 2R3, Canada
Interests: microstructural characterization (TEM, XPS, SIMS, ESEM); metal and alloys; zinc-air batteries; thin films and coating; electro/electroless deposition

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Guest Editor
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, AB T6G 2R3, Canada
Interests: materials design; tribo-materials; wear; corrosion; surfaces and interfaces; computational materials science
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Special Issue Information

Dear Colleagues,

About twenty years ago, a non-conventional multicomponent alloy system was proposed, known as the high-entropy alloy (HEA). It has since attracted intensive interest from the materials science and engineering community. An HEA contains five or more principal elements, rather than those with one or two principal elements with other minor elements. HEAs have been extensively studied and have been demonstrated to possess many superior properties over conventional alloys. Although the HEA was initially considered to be in a state of single-phase solid solution, most HEAs actually have multi-phase microstructures, which are rather complicated. However, this also provide more opportunities for HEAs to be readily tailored for desired properties. HEAs have been found to be very promising for a wide range of applications. Significant efforts have been made to extend HEAs to various technological and industrial fields, e.g., nuclear energy, aerospace, manufacturing, mining, etc. Thus, it is important to evaluate the performance of HEAs under various operation conditions and understand the responses of HEAs to different external actions or processes. For instance, the following are representative cases that HEAs may encounter: mechanical– electrochemical attacks, wear–corrosion, fretting-hot corrosion, stress- irradiation–high-temperature synergistic attacks, erosion in aggressive environments, etc. The performance of HEAs during these processes is certainly related to their phase constituents and microstructures.

This Special Issue aims to collect research progress in these areas and provide a platform for researchers to report and share their findings, especially regarding the microstructure, mechanical and tribological properties, and performance of HEAs in different environments. Understanding the synergistic effects of different external factors would help design optimal HEAs for maximized benefits. We invite scientists and engineers to present their articles that reveal microstructural features of high- and medium-entropy alloys at various scales (such as at macro, micron, and atomic levels) and that correlate these features with the performance of the multicomponent alloys during the above-mentioned processes. All experimental and theoretical/ computational studies are welcome.

The reported studies include, but are not limited to, the following topics:

  • Phase identification, crystal structures, and chemical compositions.
  • Phase transformations, microstructural evolution, and control.
  • Lattice defects in HEAs/MEAs (medium-entropy alloys) and their influences on the properties of the alloys.
  • The design of advanced HEAs/MEAS and composites.
  • Mechanical properties at different temperatures.
  • Wear, corrosion, and wear–corrosion synergy at different temperatures.
  • Exploring HEAs/MEAs for applications in nuclear energy, aerospace, manufacturing, mining, and others.

Dr. Anqiang He
Prof. Dr. Dongyang Li
Guest Editors

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Keywords

  • phase identification, crystal structures, and chemical compositions
  • phase transformations, microstructural evolution, and control
  • lattice defects in HEAs/MEAs (medium-entropy alloys) and their influences on the properties of the alloys
  • the design of advanced HEAs/MEAS and composites
  • mechanical properties at different temperatures
  • wear, corrosion, and wear–corrosion synergy at different temperatures
  • exploring HEAs/MEAs for applications in nuclear energy, aerospace, manufacturing, mining, and others

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Published Papers (3 papers)

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Research

9 pages, 5559 KB  
Article
Effect of Carbon Addition on Mechanical and Corrosion Properties of CoCrFeNiMn High-Entropy Alloy
by Huiling Zhou, Hongqun Liu, Ji Li, Chengtao Li, Haokun Yang and Yanxin Qiao
Metals 2026, 16(1), 50; https://doi.org/10.3390/met16010050 - 30 Dec 2025
Cited by 4 | Viewed by 547
Abstract
The CoCrFeNiMn High-Entropy Alloy (HEA) with 0, 0.5 and 1.0 at.% Carbon (C) addition has been evaluated by mechanical and corrosion testing, including tensile, wear and corrosion resistance testings. The result shows that the medium of 0.5 at.% C addition into HEA brings [...] Read more.
The CoCrFeNiMn High-Entropy Alloy (HEA) with 0, 0.5 and 1.0 at.% Carbon (C) addition has been evaluated by mechanical and corrosion testing, including tensile, wear and corrosion resistance testings. The result shows that the medium of 0.5 at.% C addition into HEA brings higher tensile toughness with 27,213.6 MPa%, less wear damage (0.37 mm3) and superior thermodynamic stability (0.73 VSCE), compared with that of the other two compositions. The tensile fracture observation points out that the high C addition embrittles the HEA with poorer toughness and wear resistance with content increasing to 1.0 at.%. The HEA material with 0.5 at.% C addition has high corrosion potential and the lowest corrosion current density, indicating that the appropriate C-alloying plays a significant role in determining the corrosion properties of HEA. The current study shall provide meaningful instruction for high-performance C-alloyed HEA development. Full article
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18 pages, 6524 KB  
Article
The Influence of Mo and Y on the Microstructure and Properties of TiZrHfNb Series Refractory High-Entropy Alloys
by Haifei Zhang, Longzhen Lai, Cong Zhang and Haixia Tian
Metals 2025, 15(12), 1336; https://doi.org/10.3390/met15121336 - 4 Dec 2025
Cited by 1 | Viewed by 779
Abstract
TiZrHfNbMo refractory high-entropy alloy has poor plasticity and a relatively high density at room temperature, which limits its wide industrial application. To develop RHEAs featuring a simple structure, low density, and excellent overall performance. In this study, three refractory high-entropy alloys of Ti [...] Read more.
TiZrHfNbMo refractory high-entropy alloy has poor plasticity and a relatively high density at room temperature, which limits its wide industrial application. To develop RHEAs featuring a simple structure, low density, and excellent overall performance. In this study, three refractory high-entropy alloys of Ti22Zr25Hf(35−x)Nb18Mox (x = 10, 15, 20) were preliminarily designed, and the effects of different Mo contents on their microstructure and properties were investigated. All three components are of a single-phase BCC structure. Room-temperature and high-temperature compression and friction wear tests show that, with the increase in Mo, the solid solution strengthening effect is enhanced. The room temperature yield strength increases by 35.1%, the high-temperature yield strength increases by 227.5%, and the wear rate decreases by 60.5%. However, the room temperature fracture strain of Mo20 is reduced to 24%. Therefore, Y was introduced into the Mo20 refractory high-entropy alloy at mass fractions of 0.1% and 0.2% to further enhance its plasticity. The experimental results show that the addition of Y, through grain refinement and solid solution strengthening, simultaneously enhances room-temperature plasticity (from 24% to 32%) and wear resistance. The findings furnish a theoretical framework for rational element selection in RHEAs design. Full article
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14 pages, 3146 KB  
Article
Research on Performance Prediction Method of Refractory High-Entropy Alloy Based on Ensemble Learning
by Guangxiang Tian, Pingluo Zhao, Yangwei Wang, Hongmei Zhang, Liying Xing and Xingwang Cheng
Metals 2025, 15(4), 371; https://doi.org/10.3390/met15040371 - 27 Mar 2025
Cited by 5 | Viewed by 1566
Abstract
Due to the huge component space of refractory high-entropy alloy, the traditional, experimental “trial and error method” can not meet the design requirements. In order to improve the “trial and error method”, guidance is provided for the prediction and design of refractory high-entropy [...] Read more.
Due to the huge component space of refractory high-entropy alloy, the traditional, experimental “trial and error method” can not meet the design requirements. In order to improve the “trial and error method”, guidance is provided for the prediction and design of refractory high-entropy alloys. Based on the literature data, a comprehensive dataset was constructed, including the composition, phase composition, and strength data of various high-entropy alloys. On this basis, nine regression models were established for strength prediction. By comparison, the XGBoost (XGB) model achieves better prediction performance in the test set; the root mean square error (RMSE) is 195.53 MPa, and the coefficient of determination (R2) is 0.87. By using Shapley additive interpretation (SHAP) to analyze the explainability of the model, it was found that the key characteristics affecting the mechanical properties of the high-entropy alloy were mixed entropy and electronegativity. In order to further evaluate the precision of the model, through the vacuum arc melting preparation, Ti27.5Zr26.5Nb25.5Ta8.5Al12 high-entropy alloys were experimentally verified. The alloy experiments’ yield strength was 1356 MPa, predicting strength was 1304.71 MPa, external validation error was 3.81%, and the average accuracy of the model was 87.38%. Full article
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