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Next Generation High Temperature Dielectrics for Energy Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Porous Materials".

Deadline for manuscript submissions: closed (30 November 2019) | Viewed by 3436

Special Issue Editor


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Guest Editor
Univ Leeds, Sch Chem & Proc Engn, Leeds LS2 9JT, W Yorkshire, UK
Interests: structure-property relationships in dielectric and ferroelectric materials

Special Issue Information

Dear Colleagues,

Innovative strategies are required to design and manufacture next-generation dielectric ceramics for high-temperature and high-voltage capacitors. Power electronics, including conversion and conditioning in renewable energy generation, and control or sensing systems in the aerospace and electric vehicle sectors, provide a major stimulus for research into robust capacitor materials.

Stable and high values of relative permittivity to temperatures of 250–500 °C, well above the operating limits of traditional ferroelectric-based high volumetric efficiency (Class II) capacitors have been demonstrated in a number of relaxor ferroelectric ceramics. Fundamental studies are beginning to shed some light on the reasons for the near-flat relative permittivity response in these compositionally complex relaxors, all of which contain Bi.

From an energy storage perspective, there is a need to develop ceramic dielectrics with much higher energy densities.  The retention of high relative permittivity under high electric fields, allied to high electrical breakdown strengths in thick- and thin-film relaxor ceramics provides opportunities for maximising energy storage density.  Anti-ferroelectrics and relaxors with ‘pinched’ polarisation - electric field response are also promising candidates in this context. Increasing the electrical breakdown strength of thin and thick-film coatings through improved processing and microstructural control is yet another topical research area.

Barriers to industrial translation would be removed by demonstrating Bi- and Pb-free high-temperature dielectrics capable of stable operation from –55 °C to 250/300 °C.

In summary, the technological importance of discovering and developing new and improved ceramic dielectric materials provides the impetus for this Special Issue. It is my great pleasure to invite manuscript submissions: research articles, reviews, and short communications are all welcome.

Dr. Steven Milne
Guest Editor

Manuscript Submission Information

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Keywords

  • Dielectrics
  • Ferroelectrics and relaxors
  • Ceramic processing
  • Nanostructure
  • Microstructure
  • Coatings and interfaces
  • Electrical properties
  • High-temperature capacitors
  • Energy devices

Published Papers (1 paper)

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Research

13 pages, 3852 KiB  
Article
Ultrahigh Energy Storage Properties in (Sr0.7Bi0.2)TiO3-Bi(Mg0.5Zr0.5)O3 Lead-Free Ceramics and Potential for High-Temperature Capacitors
by Xi Kong, Letao Yang, Zhenxiang Cheng and Shujun Zhang
Materials 2020, 13(1), 180; https://doi.org/10.3390/ma13010180 - 1 Jan 2020
Cited by 39 | Viewed by 3129
Abstract
Due to the enhanced demand for numerous electrical energy storage applications, including applications at elevated temperatures, dielectric capacitors with optimized energy storage properties have attracted extensive attention. In this study, a series of lead-free strontium bismuth titanate based relaxor ferroelectric ceramics have been [...] Read more.
Due to the enhanced demand for numerous electrical energy storage applications, including applications at elevated temperatures, dielectric capacitors with optimized energy storage properties have attracted extensive attention. In this study, a series of lead-free strontium bismuth titanate based relaxor ferroelectric ceramics have been successfully synthesized by high temperature solid-state reaction. The ultrahigh recoverable energy storage density of 4.2 J/cm3 under 380 kV/cm, with the high efficiency of 88%, was obtained in the sample with x = 0.06. Of particular importance is that this ceramic composition exhibits excellent energy storage performance over a wide work temperature up to 150 °C, with strong fatigue endurance and fast discharge speed. All these merits demonstrate the studied ceramic system is a potential candidate for high-temperature capacitors as energy storage devices. Full article
(This article belongs to the Special Issue Next Generation High Temperature Dielectrics for Energy Applications)
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