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Halide Perovskite Crystal Materials and Optoelectronic Devices

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Optical and Photonic Materials".

Deadline for manuscript submissions: 20 July 2025 | Viewed by 820

Special Issue Editor


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Guest Editor
State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, No. 27 Shanda South Road, Jinan 250100, China
Interests: perovskite single crystals; halide perovskite crystals

Special Issue Information

Dear Colleagues,

Halide perovskite single crystals are an emerging material for a diverse range of optoelectronic devices due to their low trap density, superior properties, and low-cost growth. Since 2009, halide perovskite materials have attracted great attention in the optoelectronic field due to their superior properties, including their tunable bandgap, long carrier diffusion length, and high carrier mobility. However, perovskite optoelectronic devices usually suffer from severe stability issues, which correlate intimately with trap-mediated ion migration. Perovskite single crystals, without grain boundaries, exhibit ultra-low trap density and offer a chance for addressing ion migration and stability issues. The intrinsic optoelectronic properties of halide perovskite single crystals were first investigated in 2015 based on bulk single crystals. After that, perovskite single crystals with different morphologies have been prepared, including single-crystal films, nanowires, and nanocrystals, that satisfy the requirement of a diverse range of optoelectronic applications. For example, the efficiency of single-crystal perovskite solar cells has rocketed from 6.5% to 24.3% after only several years of development. The sensitivity and detection limit of single-crystal perovskite are much better than its commercial counterparts.

This Special Issue aims to collect recent investigations of halide perovskite single-crystal growth and device application and promote the future development of this emerging research field. This Special Issue will focus on the growth and optimization of halide perovskite single crystals as well as their optoelectronic applications, including X-ray detectors, light-emitting diodes, field-effect transistors, etc.

We encourage researchers to submit their latest original research articles, perspectives, or reviews on themes that include, but are not limited to, the following:

  • Novel growth strategies to modulate the defects, quality, and carrier transport properties of halide perovskite single crystals;
  • Explorations of novel properties and applications of halide perovskite crystals;
  • Designs of halide perovskite single crystals with new compositions, in particular, with lead-free materials;
  • Advanced device structures and performance based on perovskite single crystals;
  • Degradation mechanisms of halide perovskite single-crystal materials and devices.

Prof. Dr. Zhaolai Chen
Guest Editor

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Keywords

  • perovskite crystals
  • growth strategy
  • halide perovskite crystals
  • perovskite crystals devices
  • halide perovskite materials

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Published Papers (1 paper)

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Research

15 pages, 4184 KiB  
Article
Photocatalysis of Methyl Orange (MO), Orange G (OG), Rhodamine B (RhB), Violet and Methylene Blue (MB) Under Natural Sunlight by Ba-Doped BiFeO3 Thin Films
by Abderrahmane Boughelout, Abdelmadjid Khiat and Roberto Macaluso
Materials 2025, 18(4), 887; https://doi.org/10.3390/ma18040887 - 18 Feb 2025
Viewed by 501
Abstract
We present structural, morphological, optical and photocatalytic properties of multiferroic Bi0.98Ba0.02FeO3 (BBFO2) perovskite thin films prepared by a combined sol–gel and spin-coating method. X-ray diffraction (XRD) analysis revealed that all the perovskite films consisted of the stable polycrystalline [...] Read more.
We present structural, morphological, optical and photocatalytic properties of multiferroic Bi0.98Ba0.02FeO3 (BBFO2) perovskite thin films prepared by a combined sol–gel and spin-coating method. X-ray diffraction (XRD) analysis revealed that all the perovskite films consisted of the stable polycrystalline rhombohedral phase structure (space group R3c) with a tolerance factor of 0.892. By using Rietveld refinement of diffractogram XRD data, crystallographic parameters, such as bond angle, bond length, atom position, unit cell parameters, and electron density measurements were computed. Scanning electron microscopy (SEM) allowed us to assess the homogeneous and smooth surface morphology of the films with a small degree of porosity, while chemical surface composition characterization by X-ray photoelectron spectroscopy (XPS) showed the presence of Bi, Fe, O and the doping element Ba. Absorption measurements allowed us to determine the energy band gap of the films, while photoluminescence measurements have shown the presence of oxygen vacancies, which are responsible for the enhanced photocatalytic activity of the material. Photocatalytic degradation experiments of Methylene Blue (MB), Methyl orange (MO), orange G (OG), Violet and Rhodamine B (RhB) performed on top of BBFO2 thin films under solar light showed the degradation of all pollutants in varying discoloration efficiencies, ranging from 81% (RhB) to 54% (OG), 53% (Violet), 47% (MO) and 43% (MB). Full article
(This article belongs to the Special Issue Halide Perovskite Crystal Materials and Optoelectronic Devices)
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