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Advanced Catalysts for Energy and Environmental Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: 10 August 2024 | Viewed by 4623

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Guest Editor
Department of Inorganic & Organic Chemistry, Biochemistry and Catalysis, Faculty of Chemistry, University of Bucharest, 4-12, Blvd. Regina Elisabeta, 030018 Bucharest, Romania
Interests: layered double hydroxides; mixed oxides; nickel molybdate; red mud; catalytic oxidation
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Special Issue Information

Dear Colleagues,

In recent decades, humankind has been confronted with two important issues: (i) the increased need for cheap and sustainable energy sources and (ii) the intensification of environmental pollution. Therefore, all around the world, researchers are constantly trying to transform renewable raw materials into fuels with high caloric power and to eliminate pollutants from air, water, and soil by designing and applying selective catalytic processes. Oxides, mixed oxides, composites containing oxide components, and metals supported on oxide carriers are among the most utilized catalysts for these processes. Other advanced catalysts for such processes are inorganic–organic hybrid structures such as biomimetic metal complexes confined in inorganic lattices or functionalized graphene oxide.

This Special Issue aims to update the findings related to oxide-containing materials, and on hybrid materials employed as catalysts for the production of ecological fuels and in environmental protection, respectively. Special attention is directed at the development of such catalysts by waste valorization, since this sustainable approach would enable both an economy of natural resources and a diminution of energy consumption in the synthesis of these materials. The design of modified layered double hydroxides and perovskite structures, including thin-film heterostructures, also leads to a wide range of new materials which can act as catalysts for the production of hydrogen and other ecological fuels, and for the degradation of organic pollutants from liquid and gaseous effluents. Moreover, progresses in the synthesis of supported metal catalysts with nanodispersed metal active species are thought to bring important contributions to the increase of catalytic efficiency.

Taking into account the aforementioned aspects, I cordially invite you to contribute your recent works (review articles, original papers, and communications) to this Special Issue on oxide catalysts for energy and environmental applications, including but not limited to the following materials-oriented categories:

  • LDH-derived mixed oxides and/or LDHs-composites;
  • Perovskites and/or perovskite composites;
  • Catalysts obtained from waste materials;
  • Oxometallate-based materials;
  • Supported metal catalysts;
  • Inorganic–organic hybrid materials.

Dr. Rodica Zavoianu
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • ecologic fuels
  • decontamination
  • metal oxides catalysts
  • supported metal catalysts
  • waste valorization

Published Papers (3 papers)

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Research

18 pages, 4177 KiB  
Article
Cobalt Impregnation on Titania Photocatalysts Enhances Vis Phenol Photodegradation
by Soukayna Belekbir, Mohammed El Azzouzi, Laura Rodríguez-Lorenzo, Adnane El Hamidi, Juan Arturo Santaballa and Moisés Canle
Materials 2023, 16(11), 4134; https://doi.org/10.3390/ma16114134 - 01 Jun 2023
Cited by 3 | Viewed by 1394
Abstract
One of the main challenges of photocatalysis is to find a stable and effective photocatalyst, that is active and effective under sunlight. Here, we discuss the photocatalytic degradation of phenol as a model pollutant in aqueous solution using NUV-Vis (>366 nm) and UV [...] Read more.
One of the main challenges of photocatalysis is to find a stable and effective photocatalyst, that is active and effective under sunlight. Here, we discuss the photocatalytic degradation of phenol as a model pollutant in aqueous solution using NUV-Vis (>366 nm) and UV (254 nm) in the presence of TiO2-P25 impregnated with different concentrations of Co (0.1%, 0.3%, 0.5%, and 1%). The modification of the surface of the photocatalyst was performed by wet impregnation, and the obtained solids were characterized using X-ray diffraction, XPS, SEM, EDS, TEM, N2 physisorption, Raman and UV-Vis DRS, which revealed the structural and morphological stability of the modified material. BET isotherms are type IV, with slit-shaped pores formed by nonrigid aggregate particles and no pore networks and a small H3 loop near the maximum relative pressure. The doped samples show increased crystallite sizes and a lower band gap, extending visible light harvesting. All prepared catalysts showed band gaps in the interval 2.3–2.5 eV. The photocatalytic degradation of aqueous phenol over TiO2-P25 and Co(X%)/TiO2 was monitored using UV-Vis spectrophotometry: Co(0.1%)/TiO2 being the most effective with NUV-Vis irradiation. TOC analysis showed ca. 96% TOC removal with NUV-Vis radiation, while only 23% removal under UV radiation. Full article
(This article belongs to the Special Issue Advanced Catalysts for Energy and Environmental Applications)
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19 pages, 7959 KiB  
Article
Mo-LDH-GO Hybrid Catalysts for Indigo Carmine Advanced Oxidation
by Octavian Dumitru Pavel, Alexandra-Elisabeta Stamate, Rodica Zăvoianu, Anca Cruceanu, Alina Tirsoaga, Ruxandra Bîrjega, Ioana Andreea Brezeștean, Alexandra Ciorîță, Daniela Cristina Culiță and Ana Paula Soares Dias
Materials 2023, 16(8), 3025; https://doi.org/10.3390/ma16083025 - 11 Apr 2023
Cited by 2 | Viewed by 1436
Abstract
This paper is focused on the utilization of hybrid catalysts obtained from layered double hydroxides containing molybdate as the compensation anion (Mo-LDH) and graphene oxide (GO) in advanced oxidation using environmentally friendly H2O2 as the oxidation agent for the removal [...] Read more.
This paper is focused on the utilization of hybrid catalysts obtained from layered double hydroxides containing molybdate as the compensation anion (Mo-LDH) and graphene oxide (GO) in advanced oxidation using environmentally friendly H2O2 as the oxidation agent for the removal of indigo carmine dye (IC) from wastewaters at 25 °C using 1 wt.% catalyst in the reaction mixture. Five samples of Mo-LDH-GO composites containing 5, 10, 15, 20, and 25 wt% GO labeled as HTMo-xGO (where HT is the abbreviation used for Mg/Al in the brucite type layer of the LDH and x stands for the concentration of GO) have been synthesized by coprecipitation at pH 10 and characterized by XRD, SEM, Raman, and ATR-FTIR spectroscopy, determination of the acid and base sites, and textural analysis by nitrogen adsorption/desorption. The XRD analysis confirmed the layered structure of the HTMo-xGO composites and GO incorporation in all samples has been proved by Raman spectroscopy. The most efficient catalyst was found to be the catalyst that contained 20%wt. GO, which allowed the removal of IC to reach 96.6%. The results of the catalytic tests indicated a strong correlation between catalytic activity and textural properties as well as the basicity of the catalysts. Full article
(This article belongs to the Special Issue Advanced Catalysts for Energy and Environmental Applications)
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18 pages, 6040 KiB  
Article
Construction of Bouquet-like Bi2Se3/Bi2O3@Bi Composites with High Interfacial Charge Separation for the Degradation of Atrazine
by Juncheng Han, Menghan Pang, Donghuan Meng, Jianrong Qiu and Dongbo Wang
Materials 2023, 16(5), 1896; https://doi.org/10.3390/ma16051896 - 24 Feb 2023
Cited by 3 | Viewed by 1326
Abstract
Using low-density solar energy in the environment and converting it into chemical energy that can drive the degradation of organic pollutants is considered to be a very promising strategy for solving the problem of environmental pollution. The efficacy of photocatalytic destruction of organic [...] Read more.
Using low-density solar energy in the environment and converting it into chemical energy that can drive the degradation of organic pollutants is considered to be a very promising strategy for solving the problem of environmental pollution. The efficacy of photocatalytic destruction of organic contaminants is nonetheless constrained by the high composite rate of photogenic carriers, insufficient light absorption and utilization impact, and sluggish charge transfer rate. In this work, we created a new type of heterojunction photocatalyst with a spherical Bi2Se3/Bi2O3@Bi core–shell structure and investigated its degrading properties of organic pollutants in the environment. Interestingly, benefiting from the fast electron transfer capability of the Bi0 electron bridge, the charge separation and transfer efficiency between Bi2Se3 and Bi2O3 is greatly improved. In this photocatalyst, Bi2Se3 not only has a photothermal effect to speed up the process of photocatalytic reaction, but also has fast electrical conductivity of topological materials at the surface, which speeds up the transmission efficiency of photogenic carriers. As expected, the removal performance of the Bi2Se3/Bi2O3@Bi photocatalyst to atrazine is 4.2 and 5.7 times higher than that of the original Bi2Se3 and Bi2O3. Meanwhile, the best samples Bi2Se3/Bi2O3@Bi showed 98.7%, 97.8%, 69.4%, 90.6%, 91.2%, 77.2%, 97.7%, and 98.9% removal of ATZ, 2,4-DCP, SMZ, KP, CIP, CBZ, OTC-HCl, and RhB, and 56.8%, 59.1%, 34.6%, 34.5%, 37.1%, 73.9%, and 78.4% mineralization. Through characterization such as XPS and electrochemical workstations, it is proved that the photocatalytic properties of Bi2Se3/Bi2O3@Bi catalysts are far superior to other materials, and a suitable photocatalytic mechanism is proposed. A novel form of bismuth-based compound photocatalyst is anticipated to be produced as a result of this research in order to address the increasingly critical problem of environmental water pollution in addition to presenting fresh avenues for the creation of adaptable nanomaterials for additional environmental applications. Full article
(This article belongs to the Special Issue Advanced Catalysts for Energy and Environmental Applications)
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