Coatings

This study investigated the synergistic mechanisms of flame retardancy and smoke suppression exhibited by a novel ternary additive in warm-mix asphalt (WMA). The ternary additive consisted of aluminum hydroxide (ATH), organic montmorillonite (OMMT), and expandable graphite (EG). A comprehensive experimental program was conducted, encompassing limiting oxygen index (LOI) testing, cone calorimeter testing, thermogravimetric analysis (TGA), and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM–EDS). The results showed that incorporation of 6 wt% of the ternary additive (by mass of the asphalt binder) markedly improved the fire resistance of the WMA. The LOI increased from 19.8% (neat asphalt) to 25.2%. Cone calorimeter tests revealed a 23.9% increase in time to ignition, a 24.2% reduction in peak heat release rate, and a 47.5% decrease in total smoke production. These improvements are attributed to a synergistic mechanism involving the endothermic decomposition of ATH, the char-promoting effect of OMMT, and the intumescent expansion of expandable graphite (EG) forming a compact insulating barrier, which collectively inhibit combustion and smoke release. The ternary additive exhibits considerable promise as an effective flame-retardant modifier for enhancing the fire safety of warm-mix asphalt pavements, especially in high-risk scenarios such as tunnels.

Glazed tiles are a common component of ancient buildings, typically used for roofs and walls, serving decorative, protective, and waterproofing purposes. Currently, they are severely damaged and urgently require protection. This study investigated the preservation and damage status of glazed tile components in ancient buildings throughout Shanxi Province. Temperature and humidity variations and acid rain corrosion simulation experiments were conducted to investigate the causes of glazed tile damage. By characterizing morphological changes and corrosion products, the damage process of glazed tiles under the influence of external temperature, moisture, and acid rain was explained. For damage phenomena such as powdering of the tile body, hydroxyl-terminated PDMS–OH/TEOS was selected as the coating materials, and ethanol was used as the solvent to reinforce the glazed tile body. By characterizing indicators such as color difference, water resistance, and mechanical properties, a suitable coating materials formulation was selected. The reinforcement mechanism was investigated using infrared spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy. For glazed tiles with extremely severe damage, new glazed tiles with superior mechanical properties were fired by reducing the particle size of the raw material in the tile body to replace them.

The Macao rammed earth wall is a typical representative of cultural heritage in hot-humid regions. However, the spatial differentiation mechanisms of its surface deterioration remain unclear. This study, taking the Old Wall in Macao as a case, combined field investigation with terrestrial laser scanning (TLS) and thermal imaging to systematically reveal the spatial distribution patterns of surface pathologies and their hydrological driving mechanisms. Based on structural separations and deterioration characteristics, the wall was divided into three adjacent sections for comparative analysis. The main conclusions are as follows: (1) Quantitative analysis showed the section with a gentler slope (77%) experienced significant flatness deterioration due to uneven settlement, promoting internal water penetration that triggered severe undercutting (35% of its surface area); (2) The other two sections maintained steep slopes (86%) that promoted surface runoff, which combined with adjacent building drainage led to significant biological colonization (68% in the section most affected by nearby temple drainage); (3) Thermal imaging verified the correlation between water infiltration cores and temperature-flatness anomalies, enabling construction of a coupled “geometry-hydrology-pathology” model that elucidates the complete causal chain from foundation settlement to surface pathology. This study provides a theoretical basis and technical support for the differentiated protection of rammed earth heritage in hot-humid environments.