Anode Materials for Sodium-Ion Batteries

A special issue of Batteries (ISSN 2313-0105). This special issue belongs to the section "Battery Materials and Interfaces: Anode, Cathode, Separators and Electrolytes or Others".

Deadline for manuscript submissions: closed (10 July 2023) | Viewed by 8262

Special Issue Editors

School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Interests: sodium-ion batteries
Faculty of Arts and Sciences, Beijing Normal University, Zhuhai 519087, China
Interests: sodium ion battery; functional electrolytes; energy storage

Special Issue Information

Dear Colleagues,

Sodium-ion batteries (SIBs) have sparked intense interest in next-generation energy storage technologies such as smart grids and low-speed electric vehicles due to their advantages in resource abundance and cost. The prime problem encountered in the application of large-scale SIBs is the low effectiveness of appropriate anode materials. Furthermore, the current understanding of the electrochemical storage and capacity degradation mechanisms of various systems of anode materials is still unsatisfactory.

This Special Issue of Batteries features a collection of Anode Materials for Sodium-Ion Batteries. We would like to welcome researchers from all over the world to share their latest findings and perspectives here.  Articles, letters, reviews, and perspective views are acceptable. We hope that readers will gain a better understanding of the future directions of anode materials for SIBs through this Special Issue.

Topics of interest include but are not limited to:

  • Carbon-based materials (hard carbon, graphitic carbon, biomass derivatives)
  • Titanium-based oxides (titanium dioxides, sodium-titanate compounds)
  • Conversion materials (transition metal oxide/sulfide/phosphide)
  • Alloying reaction materials
  • Sodium metal anodes
  • Organic materials
  • Theoretical computation/simulation

Dr. Yu Li
Dr. Qiao Ni
Guest Editors

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Keywords

  • energy storage
  • sodium-ion batteries
  • anode materials
  • computation
  • practical analysis

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Published Papers (3 papers)

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Research

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12 pages, 2798 KiB  
Article
A Solid Redox Mediator Analog as a Highly Efficient Catalyst for Na–O2 Batteries
by Qin-yin Shen, Jin-ling Ma, Ming-lu Li, Wei He, Ying-yue Tan, Peng-yu Zhou and Yu Wang
Batteries 2022, 8(11), 227; https://doi.org/10.3390/batteries8110227 - 9 Nov 2022
Cited by 3 | Viewed by 2067
Abstract
During the discharge of Na–O2 batteries, O2 is reduced and combines with Na+ to form an insulating solid sodium oxide on the cathode, which severely hinders the mass transfer path, resulting in high polarization voltage, low energy efficiency, and short [...] Read more.
During the discharge of Na–O2 batteries, O2 is reduced and combines with Na+ to form an insulating solid sodium oxide on the cathode, which severely hinders the mass transfer path, resulting in high polarization voltage, low energy efficiency, and short battery life. Hereby, we proposed a novel illumination-assisted Na–O2 battery in which bismuth vanadate (BiVO4) with few defects and high surface areas was used as the catalyst. It showed that the charge overpotential under photo assistance reduced by 1.11 V compared with that of the dark state one. Additionally, the insolating sodium oxide discharge products were completely decomposed, which was the key to running Na–O2 batteries over 200 cycles with a charge potential of no more than 3.65 V, while its counterpart (under dark condition) at 200 cycles had the charge potential higher than 4.25 V. The experiment combined with theoretical calculation shows that few defects, high surface areas, the altered electron transfer kinetics, and the low energy gap and low oxygen absorption energy of the (040) crystal face of monoclinic BiVO4 play an important role in catalyzing oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Full article
(This article belongs to the Special Issue Anode Materials for Sodium-Ion Batteries)
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14 pages, 2043 KiB  
Article
Constructing Robust Solid Electrolyte Interface via ZrO2 Coating Layer for Hard Carbon Anode in Sodium-Ion Batteries
by Yuteng Gong, Chengxin Yu, Yu Li, Ji Qian, Chuan Wu and Ying Bai
Batteries 2022, 8(9), 115; https://doi.org/10.3390/batteries8090115 - 6 Sep 2022
Cited by 6 | Viewed by 2766
Abstract
Hard carbon (HC) has attracted extensive attention due to its rich material source, environmental non-toxicity, superior sodium storage capacity, and lower sodium storage potential, and is considered most likely to be a commercial anode material for sodium-ion batteries (SIBs). Nevertheless, the limited initial [...] Read more.
Hard carbon (HC) has attracted extensive attention due to its rich material source, environmental non-toxicity, superior sodium storage capacity, and lower sodium storage potential, and is considered most likely to be a commercial anode material for sodium-ion batteries (SIBs). Nevertheless, the limited initial Coulombic efficiency (ICE) of HC is the main bottleneck hindering its practical application. To alleviate this issue, herein, a ZrO2 coating was skillfully constructed by using a facile liquid phase coating method. The ZrO2 coating can act as a physical barrier to prevent direct contact between the HC surface and the electrolyte, thus effectively reducing irreversible sodium adsorption and inhibiting the continuous decomposition of the electrolyte. Meanwhile, this fresh interface can contribute to the generation of a thinner solid electrolyte interface (SEI) with high ionic conductivity. As a result, the ICE of the ZrO2-coated HC electrode can be optimized up to 79.2% (64.4% for pristine HC). Furthermore, the ZrO2-coated HC electrode delivers outstanding cyclic stability so that the capacity retention rate can reach 82.6% after 2000 cycles at 1 A g−1 (55.8% for pristine HC). This work provides a flexible and versatile surface modification method to improve the electrochemical property of HC, and hopefully accelerate the practical application of HC anodes for SIBs. Full article
(This article belongs to the Special Issue Anode Materials for Sodium-Ion Batteries)
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Review

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20 pages, 5598 KiB  
Review
Anode-Free Rechargeable Sodium-Metal Batteries
by Qiao Ni, Yuejiao Yang, Haoshen Du, Hao Deng, Jianbo Lin, Liu Lin, Mengwei Yuan, Zemin Sun and Genban Sun
Batteries 2022, 8(12), 272; https://doi.org/10.3390/batteries8120272 - 5 Dec 2022
Cited by 14 | Viewed by 6911
Abstract
Due to the advantages of rich resources, low cost, high energy conversion efficiency, long cycle life, and low maintenance fee, sodium–ion batteries have been regarded as a promising energy storage technology. However, their relatively low energy density compared with the commercialized lithium–ion batteries [...] Read more.
Due to the advantages of rich resources, low cost, high energy conversion efficiency, long cycle life, and low maintenance fee, sodium–ion batteries have been regarded as a promising energy storage technology. However, their relatively low energy density compared with the commercialized lithium–ion batteries still impedes their application for power systems. Anode–free rechargeable sodium–metal batteries (AFSMBs) pose a solution to boost energy density and tackle the safety problems of metal batteries. At present, researchers still lack a comprehensive understanding of the anode-free cells in terms of electrolytes, solid–electrolyte interphase (SEI), and current collectors. This review is devoted to the field of AFSMBs, and outlines the breakthroughs that have been accomplished along with our perspective on the direction of future development for AFSMBs and the areas that warrant further investigation. Full article
(This article belongs to the Special Issue Anode Materials for Sodium-Ion Batteries)
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