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Organics, Volume 2, Issue 3

2021 September - 6 articles

Cover Story: The reactivity of a series of pairs of bent and linear three-atom-component (B-TACs and L-TACs) participating in [3 + 2] cycloaddition (32CA) reactions towards ethylene and electrophilic dicyanoethylene (DCE) have been studied within the Molecular Electron Density Theory. While the pseudodiradical structure of B-TACs changes to that of pseudoradical or carbenoid L-TACs upon dehydrogenation, zwitterionic B-TACs remain unchanged. Conceptual Density Functional Theory (CDFT) indices characterize five of the nine TACs as strong nucleophiles participating in polar reactions towards electrophilic ethylenes. View this paper
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Articles (6)

  • Review
  • Open Access
8 Citations
4,759 Views
25 Pages

14 September 2021

Conjugated azapolyenes (azabuta-1,3-dienes, aza-/diaza-/oxaza-/oxadiazahexa-1,3,5-trienes) are highly reactive in electrocyclization reactions, which makes them convenient precursors for the synthesis of a wide range of four-, five-, and six-membered...

  • Communication
  • Open Access
6 Citations
5,335 Views
7 Pages

2 September 2021

Illisimonin A is a new sesquiterpene isolated from Illicium simonsii, and it possesses a novel 5/5/5/5/5 pentacyclic skeleton. The tricyclic skeleton of illisimonin A, tricyclo[5.2.1.01,5]decane, is presumed to be biosynthesized from allo-cedranes vi...

  • Review
  • Open Access
8 Citations
5,578 Views
19 Pages

Ring-Opening of Cyclodextrins: An Efficient Route to Pure Maltohexa-, Hepta-, and Octaoses

  • Matthieu Pélingre,
  • Dindet Steve-Evanes Koffi Teki,
  • Jamal El-Abid,
  • Vincent Chagnault,
  • José Kovensky and
  • Véronique Bonnet

25 August 2021

Many preparations of maltooligosaccharides have been described in literature, essentially using enzymatic or biotechnological processes. These compounds, derived from starch, are well-known as prebiotic agents. The use of maltohexa-, hepta-, and octa...

  • Article
  • Open Access
15 Citations
3,741 Views
13 Pages

13 August 2021

The reactivity of a series of pairs of bent and linear three-atom-component (B-TACs and L-TACs) participating in [3 + 2] cycloaddition (32CA) reactions towards ethylene and electrophilic dicyanoethylene (DCE) have been studied within the Molecular El...

  • Feature Paper
  • Review
  • Open Access
34 Citations
15,996 Views
113 Pages

Design, Synthesis, and Utility of Defined Molecular Scaffolds

  • Daisuke Sato,
  • Zhiyuan Wu,
  • Hikaru Fujita and
  • Jonathan S. Lindsey

11 July 2021

A growing theme in chemistry is the joining of multiple organic molecular building blocks to create functional molecules. Diverse derivatizable structures—here termed “scaffolds” comprised of “hubs”—provide the foundation for systematic covalent orga...

  • Review
  • Open Access
4 Citations
7,133 Views
19 Pages

8 July 2021

para-Selective processes for the chlorination of phenols using sulphuryl chloride in the presence of various sulphur-containing catalysts have been successfully developed. Several chlorinated phenols, especially those derived by para-chlorination of...

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Organics - ISSN 2673-401X