June 2019 - 18 articles
Magnetically responsive fluid based on polymers of natural rubber (NR-latex) involves a magnetic compound fluid (MCF) rubber liquid. For a wide range of engineering applications of suspensions or liquids with particles, their electrical characteristi...
A new family of mixed valent, double salt spin crossover compounds containing anionic FeIII and cationic FeII compounds i.e., [FeII{(pz)3CH}2][FeIII(azp)2]2·2H2O (4), [FeII(TPPZ)2][FeIII(azp)2]2]·H2O (5) and [FeII(TPPZ)2][FeIII(azp)2]2]...
Cellulosic enzymes, including cellulase, play an important role in biotechnological processes in the fields of food, cosmetics, detergents, pulp, paper, and related industries. Low thermal and storage stability of cellulase, presence of impurities, e...
We report the synthesis and the characterization of six new heterometallic chloranilato-based ferrimagnets formulated as (NBu4)[MnCr(C6O4Cl2)3]·nG with n = 1 for G = C6H5Cl (1), C6H5I (3), and C6H5CH3 (4); n = 1.5 for G = C6H5Br (2) and n = 2...
The synthesis, structural characterization and magnetic study of novel CoII/4f and CoII/YIII clusters are described. In particular, the initial employment of di-2-pyridyl ketone, (py)2CO, in mixed metal Co/4f chemistry, provided access to four triang...
High-pressure (HP) structural and magnetic properties of a magnetic coordination polymer {[NiII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (Ni2Nb) are presented, discussed and compared with its two previously reported analogs {[MnII(pyrazole)4]2[NbIV(CN)8...
The degrees of spin labeling of a polyphenylene-based polymer and its graphitized derivative with a stable nitronyl nitroxide were evaluated by estimating the absolute numbers of spins in a set of samples using continuous wave (CW) electron spin reso...
Official reports to governments throughout the Western world attempt to allay public concern about the increasing inescapability of the microwaves (also known as radiofrequency radiation or RF) emitted by “smart” technologies, by repeating the dogma...
A series of chloralilate-bridged dinuclear lanthanide complexes of formula [{LnIII(Tp)2}2(μ-Cl2An)]·2CH2Cl2, where Cl2An2− and Tp− represent the chloranilate and hydrotris (pyrazolyl)borate ligands, respectively, and Ln = Gd (1)...
We report on the vacuum thermal deposition of bilayer thin films of the luminescent complex Ir(ppy)3, tris[2-phenylpyridinato-C2,N]iridium(III), and the spin crossover complex [Fe(HB(tz)3)2], bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II). Switchin...
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