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Inorganics, Volume 9, Issue 3

2021 March - 3 articles

Cover Story: Organotin derivatives resulting from the insertion of carbon dioxide into Sn-X bonds (X = N, H, P) have been reviewed from a structural point of view. Notably, the synthetic aspects and X-ray structures of carbamato, formato and phosphinoformato tin complexes are successively described and discussed. In addition, the last chapter is devoted to bimetallic transition-metal/tin complexes with bridging carbon dioxide, also named metallocarboxylato tin complexes. Completing a previous review dedicated to hemicarbonato and carbonato derivatives, this new inventory continues to show that CO2 derivatives of molecular tin compounds can truly be considered as a class of compounds in their own right. View this paper.
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Articles (3)

  • Article
  • Open Access
10 Citations
4,593 Views
12 Pages
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Photoluminescent Coordination Polymers Based on Group 12 Metals and 1H-Indazole-6-Carboxylic Acid

  • Antonio A. García-Valdivia,
  • Estitxu Echenique-Errandonea,
  • Gloria B. Ramírez-Rodríguez,
  • José M. Delgado-López,
  • Belén Fernández,
  • Sara Rojas,
  • Javier Cepeda and
  • Antonio Rodríguez-Diéguez
Inorganics2021, 9(3), 20;https://doi.org/10.3390/inorganics9030020

22 March 2021

Two new coordination polymers (CPs) based on Zn(II) and Cd(II) and 1H-indazole-6-carboxylic acid (H2L) of general formulae [Zn(L)(H2O)]n (1) and [Cd2(HL)4]n (2) have been synthesized and fully characterized by elemental analyses, Fourier transformed...

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  • Article
  • Open Access
2 Citations
2,928 Views
12 Pages
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Synthesis and Characterization of NaCd0.92Sn1.08, Na(Cd0.28Sn0.72)2 and Na2CdSn5 with Three-Dimensional Cd-Sn Frameworks

  • Yuki Asamiya,
  • Takahiro Yamada and
  • Hisanori Yamane
Inorganics2021, 9(3), 19;https://doi.org/10.3390/inorganics9030019

6 March 2021

The crystal structures of three new ternary compounds, NaCd0.92Sn1.08 (I), Na(Cd0.28Sn0.72)2 (II), and Na2CdSn5 (III) synthesized in a sodium-cadmium-tin system were determined by single-crystal X-ray analysis to be the following: (I) LiGeZn-type str...

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  • Review
  • Open Access
4 Citations
3,670 Views
32 Pages
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CO2 Derivatives of Molecular Tin Compounds. Part 2: Carbamato, Formato, Phosphinoformato and Metallocarboxylato Complexes

  • Laurent Plasseraud
Inorganics2021, 9(3), 18;https://doi.org/10.3390/inorganics9030018

24 February 2021

Single-crystal X-ray diffraction structures of organotin compounds bearing hemicarbonate and carbonate ligands were recently reviewed by us—“CO2 Derivatives of Molecular Tin Compounds. Part 1: Hemicarbonato and Carbonato Complexes”, Inorganics 2020,...

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