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Inorganics, Volume 9, Issue 10

2021 October - 5 articles

Cover Story: A sterically hindered spirogermabifluorene was successfully synthesized via the reaction of a dilithiated 3,3’,5,5’-tetra-t-butylbiphenyl ligand with an equimolar amount of GeCl2·(dioxane). Theoretical calculations suggested that the spirogermabifluorene would be generated by the biphenyl-migration from the 5H-dibenzogermole-5-ylidene dimer initially generated in situ, along with the elimination of Ge(0). Its solid-state structure and redox behavior were examined by single-crystal X-ray diffraction analysis and electrochemical measurements, respectively. The sterically hindered biphenyl ligands endow the spirogermabifluorene with high redox stability and increased electron affinity. We believe that several families of spirogermabifluorenes can be accessed using the synthetic methodology described in this paper, which may lead to new applications of spirogermabifluorenes on account of their unique optoelectronic features.View this paper

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Article

12 Citations

5,096 Views

13 Pages

Nanostructure and Luminescent Properties of Bimetallic Lanthanide Eu/Gd, Tb/Gd and Eu/Tb Coordination Polymers

Helena Brunckova,
Erika Mudra,
Lucas Rocha,
Eduardo Nassar,
Willian Nascimento,
Hristo Kolev,
Maksym Lisnichuk,
Alexandra Kovalcikova,
Zuzana Molcanova and
Lubomir Medvecky
+ 1 author

Inorganics2021, 9(10), 77;https://doi.org/10.3390/inorganics9100077

15 October 2021

This study presents the synthesis, structural and luminescence properties for lanthanide metal–organic frameworks (LnMOFs), which belong to the sub-class of coordination polymers. The series of nanosized LnMOFs (Ln = Eu, Gd, Tb, Eu_0.5Gd_0.5, Tb_0.5Gd_0....

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Article

1 Citations

3,466 Views

10 Pages

Synthesis of N,O-Chelating Hydrazidopalladium Complexes from 1,2-Bis(trifluoroacetyl)hydrazine

Yoshihito Kayaki,
Tomohiro Hayakawa and
Takao Ikariya

Inorganics2021, 9(10), 76;https://doi.org/10.3390/inorganics9100076

7 October 2021

N,O-chelating dicarbonylhydrazido-palladium complexes were synthesized by treatment of 1,2-bis(trifluoroacetyl)hydrazine with a mixture of a Pd(0) source, [Pd(dba)₂] (DBA = dibenzylideneacetone), and four-electron donors including 1,3-bis(diphenylpho...

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Article

4,287 Views

10 Pages

Facile Synthesis and Redox Behavior of an Overcrowded Spirogermabifluorene

Shogo Morisako,
Kohsuke Noro and
Takahiro Sasamori

Inorganics2021, 9(10), 75;https://doi.org/10.3390/inorganics9100075

6 October 2021

A spirogermabifluorene that bears sterically demanding 3,3′,5,5′-tetra(t-butyl)-2,2′-biphenylene groups (1) was obtained from the reaction of in-situ-generated 2,2′-dilithiobiphenylene with GeCl₂·(dioxane). The solid-state structure and the redox beh...

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Article

16 Citations

4,455 Views

14 Pages

Diverse Coordination Numbers and Geometries in Pyridyl Adducts of Lanthanide(III) Complexes Based on β-Diketonate

Franz A. Mautner,
Florian Bierbaumer,
Roland C. Fischer,
Ana Torvisco,
Ramon Vicente,
Mercè Font-Bardía,
Ànnia Tubau,
Saskia Speed and
Salah S. Massoud

Inorganics2021, 9(10), 74;https://doi.org/10.3390/inorganics9100074

30 September 2021

Ten mononuclear rare earth complexes of formula [La(btfa)₃(H₂O)₂] (1), [La(btfa)₃(4,4′-Mt₂bipy)] (2), [La(btfa)₃(4,4′-Me₂bipy)₂] (3), [La(btfa)₃(5,5′-Me₂bipy)₂] (4), [La(btfa)₃(terpy)] (5), [La(btfa)₃(phen)(EtOH)] (6), [La(btfa)₃(4,4′-Me₂bipy)(EtOH)]...

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Article

5 Citations

3,749 Views

20 Pages

Vanadium(V) Complexes with Siderophore Vitamin E-Hydroxylamino-Triazine Ligands

Maria Loizou,
Ioanna Hadjiadamou,
Chryssoula Drouza,
Anastasios D. Keramidas,
Yannis V. Simos and
Dimitrios Peschos

Inorganics2021, 9(10), 73;https://doi.org/10.3390/inorganics9100073

29 September 2021

Novel vitamin E chelate siderophore derivatives and their V^V and Fe^III complexes have been synthesised and the chemical and biological properties have been evaluated. In particular, the α- and δ-tocopherol derivatives with bis-methyldroxylamino triaz...

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