Skip Content
You are currently on the new version of our website. Access the old version .

Inorganics, Volume 13, Issue 4

2025 April - 31 articles

Cover Story: In this work, we present a comprehensive review of TiO2-based photocatalysts modified with metals and porphyrins for enhanced hydrogen evolution via solar-driven water splitting. The incorporation of noble and Earth-abundant metals improves charge separation and shifts the absorption edge toward the visible region, while porphyrin sensitizers extend visible light activity through their strong π-conjugated systems. Herein, we highlight key photocatalytic mechanisms and challenges and propose promising strategies for developing efficient, low-cost, and sustainable photocatalysts for clean energy generation. View this paper
  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
  • You may sign up for email alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.

Articles (31)

  • Article
  • Open Access
873 Views
13 Pages

Prediction of Thermal Transport Properties of Pristine and BN-Substituted Holey Graphynes

  • Qingchen Li,
  • Yujie Zhang,
  • Yanlong Liu,
  • Yan Gao and
  • Baoxia Deng

The merging of pore designs is a potential strategy for achieving ultra-low lattice thermal conductivity (κ), for which phonon anharmonicity and size effect are indispensable for discovering novel functional materials in thermal applications. I...

  • Article
  • Open Access
946 Views
11 Pages

Lanthanide Exposure In Vitro Differentially Diminishes MTT Cell Viability in Axenic Neuronal or Glial Cell Model Systems

  • David C. Platt,
  • Linda M. Ferrence,
  • Faith Breausche,
  • Katelyn Terry,
  • Gregory M. Ferrence and
  • Marjorie A. Jones

Applications of lanthanide chemistry have been successful in metallics and the petroleum industry. In the medical realm, lanthanides have shown utility in radiotherapy agents, photodynamic therapy agents, and magnetic resonance imaging (MRI) contrast...

  • Article
  • Open Access
1 Citations
2,163 Views
13 Pages

Uncooled Microbolometers Based on Nitrogen-Doped Hydrogenated Amorphous Silicon-Germanium (a-SiGe:H,N)

  • Oscar Velandia,
  • Alfonso Torres,
  • Alfredo Morales,
  • Luis Hernández,
  • Alberto Luna,
  • Karim Monfil,
  • Javier Flores,
  • Gustavo M. Minquiz,
  • Ricardo Jiménez and
  • Mario Moreno

An uncooled microbolometer is a thermal sensor consisting of a membrane suspended from the substrate to provide thermal insulation. Typically, the membrane is composed of a stack of three films integrated by a supporting film, an IR sensing film, and...

  • Review
  • Open Access
3 Citations
2,114 Views
29 Pages

Carbon Nanomaterials for Electrochemical Hydrogen Storage: Mechanisms and Advancements

  • Amir Reza Mashtizadeh,
  • Shahab Khameneh Asl,
  • Hossein Aghajani,
  • Seyed Morteza Masoudpanah and
  • Marek Wojnicki

This review article investigates the rising global energy demand, which is primarily driven by population growth and industrialization, raising significant environmental concerns due to the extensive reliance on fossil fuels. In response, hydrogen is...

  • Review
  • Open Access
2,560 Views
17 Pages

Zinc is an essential trace metal element in the human body, but it also constitutes a variety of proteins in the body of the important elements necessary; this element plays an important role in physiological metabolism. Disturbances in the metabolis...

  • Review
  • Open Access
13 Citations
6,813 Views
21 Pages

Halide perovskite solar cells (PSCs) exhibit remarkable potential for addressing global energy challenges due to their exceptional photovoltaic properties and cost-effectiveness. However, their widespread adoption is hindered by the presence of toxic...

  • Article
  • Open Access
3 Citations
1,214 Views
25 Pages

Exciton generation and separation play an important role in the photoelectric properties and the luminescence performance of materials. In order to tailor the defects and grain boundaries and improve the exciton separation and light harvesting of the...

  • Review
  • Open Access
6 Citations
4,479 Views
21 Pages

Exploring Metal- and Porphyrin-Modified TiO2-Based Photocatalysts for Efficient and Sustainable Hydrogen Production

  • Dimitrios Rafail Bitsos,
  • Apostolos Salepis,
  • Emmanouil Orfanos,
  • Athanassios G. Coutsolelos,
  • Ramonna I. Kosheleva,
  • Athanassios C. Mitropoulos and
  • Kalliopi Ladomenou

Photocatalytic H2 production is one of the most promising approaches for sustainable energy. The literature presents a plethora of carefully designed systems aimed at harnessing solar energy and converting it into chemical energy. However, the main d...

  • Article
  • Open Access
4 Citations
1,265 Views
26 Pages

Rhodamine B dye is a hazardous pollutant that poses significant risks to human health and aquatic ecosystems due to its toxic, carcinogenic nature and high chemical stability. To address this issue, analcime@nickel orthosilicate nanocomposites were s...

  • Article
  • Open Access
966 Views
18 Pages

Obtaining the dielectric constant and refractive index of the siloxane surface of montmorillonite (Mnt) and organic groups is difficult, limiting the study of Van der Waals (VDW) interactions between the hydrophilic end of quaternary ammonium surfact...

  • Article
  • Open Access
3 Citations
1,728 Views
15 Pages

Sulfamethoxazole (SMX) is a widely used antibiotic for bacterial infections and is frequently found in surface waters and wastewater treatment plant effluents, where it is commonly co-administered with trimethoprim. Because of its emerging ecological...

  • Article
  • Open Access
1 Citations
1,562 Views
12 Pages

The Effect of Localized Magnetic Fields on the Spatially Controlled Crystallization of Transition Metal Complexes

  • Ian R. Butler,
  • Rhodri M. Williams,
  • Alice Heeroma,
  • Peter N. Horton,
  • Simon J. Coles and
  • Leigh F. Jones

A series of nickel (II) bis-phosphine organometallic complexes along with two pseudo [M7] (M = Ni(II), Zn(II)) metallocalix[6]arene complexes and a dysprosium acetate coordination polymer have each been crystallised in the presence of localized magne...

  • Article
  • Open Access
2 Citations
1,535 Views
24 Pages

Cyanoguanidine-Modified Chitosan as an Efficacious Adsorbent for Removing Cupric Ions from Aquatic Solutions: Kinetics, Isotherms, and Mechanisms

  • Ard elshifa M. E. Mohammed,
  • Nouf F. Al-Harby,
  • Muneera Alrasheedi,
  • Shaimaa M. Ibrahim and
  • Nadia A. Mohamed

One of the most critical environmental needs is to remove metal ions from industrial wastewater. In this investigation, chitosan modified by cyanoguanidine (CCs) was employed for the first time to adsorb cupric ions. The optimal conditions for elimin...

  • Article
  • Open Access
3 Citations
1,938 Views
16 Pages

Realizing Environmentally Scalable Pre-Lithiation via Protective Coating of LiSi Alloys to Promote High-Energy-Density Lithium-Ion Batteries

  • Yinan Liu,
  • Wei Jiang,
  • Congcong Zhang,
  • Pingshan Jia,
  • Zhiyuan Zhang,
  • Yun Zheng,
  • Kunye Yan,
  • Jun Wang,
  • Yunxian Qian and
  • Huaiyu Shao
  • + 6 authors

Pre-lithiation using Li–Si alloy-type additives is a promising technical approach to address the drawbacks of Si-based anodes, such as a low initial Coulombic efficiency (ICE) and inevitable capacity decay during cycling. However, its commercia...

  • Article
  • Open Access
2 Citations
1,946 Views
17 Pages

Adsorption of CuSO4 on Anatase TiO2 (101) Surface: A DFT Study

  • Frank Maldonado,
  • Darwin Castillo,
  • Silvio Aguilar,
  • Javier Carrión and
  • Aramis Sánchez

The rapid growth of industrial activities has increased environmental pollution, and solar-driven heterogeneous photocatalysis using TiO2 has emerged as a promising solution. However, its wide band gap limits its efficiency, prompting research into v...

  • Article
  • Open Access
1,415 Views
17 Pages

Synthesis of Multiwalled Carbon Nanotubes on Different Cobalt Nanoparticle-Based Substrates

  • Nicolas Moreau,
  • Antonio Fonseca,
  • Danilo Vuono,
  • Joseph Delhalle,
  • Zineb Mekhalif,
  • Pierantonio De Luca and
  • Janos B.Nagy

The primary aim of this research was to identify the optimal experimental conditions for obtaining aligned carbon nanotubes, temporarily leaving aside aspects such as the purity of carbon nanotubes, which is nonetheless crucial for potential applicat...

  • Article
  • Open Access
17 Citations
1,553 Views
24 Pages

Crystal violet dye poses significant environmental and human health risks due to its toxicity, persistence, and bioaccumulative nature. It contributes to potential carcinogenicity, cytotoxicity, and systemic toxicity upon human exposure. To address t...

  • Article
  • Open Access
1,147 Views
15 Pages

Electrochemical Quartz Microbalance for Studying Electrodeposited Pt Catalysts for Methanol Oxidation Reaction

  • Bangfeng Zong,
  • Xiaojun Pan,
  • Bo Wei,
  • Lifang Zhang,
  • Xiangxiong Feng,
  • Chenggong Hou,
  • Hai Yan,
  • Wenju Xie,
  • Guicheng Liu and
  • Feng Ye

Pt catalysts are investigated for methanol oxidation in direct methanol fuel cells, utilizing the electrochemical quartz microbalance method (EQCM) with exceptional resolution and sensitivity. Pt catalysts were deposited onto the gas-diffusion layer...

  • Article
  • Open Access
2 Citations
1,608 Views
20 Pages

Copper Methacrylate Complexes with Benzimidazole Derivatives: Structural Characterization and Antimicrobial Assays

  • Andra-Georgeta Andrei,
  • Rodica Olar,
  • Cătălin Maxim,
  • Gina Vasile Scăețeanu,
  • Ioana-Cristina Marinas,
  • Madalina-Diana Gaboreanu and
  • Mihaela Badea

In order to design antimicrobial species, a series of methacrylate (Macr) complexes, [Cu(HBzIm)2(Macr)2] (1), [Cu2(HBzIm)2(Macr)4] (2), [Cu(2-MeBzIm)2(Macr)2] (3), [Cu2(2-MeBzIm)2(Macr)4] (4), and [Cu(5,6-Me2BzIm)2(Macr)2] (5) (HBzIm = benzimidazole,...

  • Article
  • Open Access
1 Citations
1,083 Views
18 Pages

Achieving Ultralong Room-Temperature Phosphorescence in Two-Dimensional Metal-Halide Perovskites by Tuning Alkyl Chain Length

  • Suqin Wang,
  • Hui Zhu,
  • Ming Sheng,
  • Bo Shao,
  • Yu He,
  • Zhuang Liu,
  • Min Li and
  • Guangtao Zhou

Two-dimensional (2D) metal-halide perovskites with highly efficient room-temperature phosphorescence (RTP) are rare due to their complex structures and intricate intermolecular interactions. In this study, by varying the alkyl chain length in organic...

  • Article
  • Open Access
1 Citations
944 Views
9 Pages

Electrical Features of Liquid Crystal Composition Doped with Cobalt Ferrite: Possible Sensing Applications

  • Yaroslav Barnash,
  • Sonja Jovanović,
  • Zoran Jovanović and
  • Natalia Kamanina

The effects of CoFe2O4 nanoparticles on the properties of an electro-optical liquid crystal cell based on the nematic composition of 4-Cyano-4′-pentylbiphenyl (5CB) under the influence of different forms of bias voltage were studied. Detailed r...

  • Article
  • Open Access
1,254 Views
25 Pages

Correlating the Characteristics and Catalytic Performance of Mn-Na-W-Ox/SiO2 for Oxidative Coupling of Methane

  • Hamid Reza Godini,
  • Stefan Berendts,
  • Rafael Kleba-Ehrhardt,
  • Asma Tufail Shah and
  • Oliver Görke

Chemical–structural characteristics of three differently synthesized research-benchmark Mn-Na-W-Ox/SiO2 catalysts for the Oxidative Coupling of Methane (OCM) were systematically studied in this research. XRD, EDX, ICP-OES, and SEM/FIB-SEM techn...

  • Article
  • Open Access
5 Citations
1,078 Views
17 Pages

This study explores the enhancement of antimicrobial and biomedical properties in Fe-based bulk metallic glasses (BMGs) through the addition of Ag. Fe55-xCr20Mo5P13C7Agx (x = 0, 1, 2, 3 at.%) master alloy ingots were synthesized by the induction melt...

  • Article
  • Open Access
1 Citations
1,376 Views
13 Pages

Coordination-driven Cu(I) complexes constitute an interesting class of materials with rich opto-electronic properties and diverse applications. Various homo- and heteroleptic Cu(I) complexes have been reported in the literature. In continuation with...

  • Review
  • Open Access
1,346 Views
18 Pages

The block layer situated between the active material and electrode in photoelectrochemical devices serves as a critical component for performance enhancement. Using dye-sensitized solar cells as a representative model, this review systematically exam...

  • Article
  • Open Access
1 Citations
1,040 Views
13 Pages

Boron nitride (BN) ceramic is an important support material in aerospace, arc discharge devices, and vacuum electronics. The electron emission properties of BN surfaces are of significance among various space applications. In this work, by preparing...

  • Article
  • Open Access
1 Citations
1,193 Views
23 Pages

Excessive levels of Zn(II) ions in aquatic environments pose significant risks to both ecosystems and human health. In aquatic systems, Zn(II) ions disrupt metabolic functions in organisms, leading to toxicity and bioaccumulation. For humans, prolong...

  • Review
  • Open Access
15 Citations
1,842 Views
29 Pages

We completed B3LYP and B3PW computations for AO- and BO2-terminated (001) as well as AO3- and B-terminated (111) surfaces of BSO, BTO, STO, PTO, CTO, BZO, SZO, and CZO perovskites. In particular, we performed the first B3LYP computations for polar BS...

  • Article
  • Open Access
3 Citations
1,232 Views
11 Pages

Effects of Zn Doping on Optical Properties of Polycrystalline β-Ga2O3

  • Yue Yan,
  • Shuai Zhu,
  • Jing Yang,
  • Yuanyuan Zhang,
  • Wei Bai and
  • Xiaodong Tang

In this study, Zn-doped Ga2O3 polycrystalline samples were prepared by solid-phase sintering, and the effects of Zn doping on the optical properties of Ga2O3 were investigated. It is found that the introduced Zn ions disrupted the Ga-O bonds and form...

  • Review
  • Open Access
9 Citations
2,520 Views
13 Pages

With the unprecedented progress of biomedical nanotechnology in the past few decades, traditional drug delivery systems (DDSs) have been incorporated into intelligent DDSs with stimulus responsive characteristics. Graphene oxide (GO) and Chitosan (CS...

Get Alerted

Add your email address to receive forthcoming issues of this journal.

XFacebookLinkedIn
Inorganics - ISSN 2304-6740