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Nanomaterials, Volume 9, Issue 2

2019 February - 180 articles

Cover Story: Natural extracts and essential oils were successfully encapsulated in ultrathin fibers of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) by electrospinning. The resultant electrospun mats were annealed to produce continuous layers and their antimicrobial and antioxidant activity was evaluated in both open and closed systems for up to 15 days. The electrospun PHBV layers containing oregano essential oil (OEO) showed the highest antimicrobial activity against two strains of food-borne bacteria as well as the most significant antioxidant performance, being therefore potential candidates to be applied as active layers in biopackaging structures to provide shelf life extension and food safety. View this paper.
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Articles (180)

  • Article
  • Open Access
60 Citations
8,600 Views
20 Pages

A Comparative Assessment of Nanotoxicity Induced by Metal (Silver, Nickel) and Metal Oxide (Cobalt, Chromium) Nanoparticles in Labeo rohita

  • Zakia Kanwal,
  • Muhammad Akram Raza,
  • Farkhanda Manzoor,
  • Saira Riaz,
  • Ghazala Jabeen,
  • Shafaq Fatima and
  • Shahzad Naseem

25 February 2019

In the present in vivo study, we provide a comparison of toxicological consequences induced by four different types of spherical nanoparticles (NPs)—silver nanoparticles (AgNPs, 40 ± 6 nm), nickel (NiNPs, 43 ± 6 nm), cobalt oxide...

  • Article
  • Open Access
8 Citations
4,918 Views
14 Pages

Graphene Oxide/Ferrocene-Containing Polymer/Gold Nanoparticle Triple Nanocomposite

  • Wenhao Qian,
  • Tao Song,
  • Mao Ye,
  • Haiyan Zhang,
  • Chun Feng,
  • Guolin Lu and
  • Xiaoyu Huang

25 February 2019

A facile strategy to prepare GO-based nanocomposites with both gold nanoparticles (AuNPs) and ferrocene (Fc) moieties was developed. The surface of GO was modified with PFcMAss homopolymer by surface-initiated atom transfer radical polymerization of...

  • Article
  • Open Access
18 Citations
4,404 Views
11 Pages

The Electronic and Magnetic Properties of Multi-Atom Doped Black Phosphorene

  • Ke Wang,
  • Hai Wang,
  • Min Zhang,
  • Wei Zhao,
  • Yan Liu and
  • Hongbo Qin

25 February 2019

Recently, substitutional doping is proved to be an effective route to induce magnetism to black phosphorene for its application in spintronics. Herein, we investigate the thermodynamic stability, electronic and magnetic properties of doped black phos...

  • Article
  • Open Access
26 Citations
4,367 Views
15 Pages

24 February 2019

In this study, a verified process of the "grafting from" approach using surface initiated atom transfer radical polymerization was applied for the modification of a graphene oxide (GO) surface. This approach provides simultaneous grafting of poly(2-(...

  • Article
  • Open Access
19 Citations
6,348 Views
15 Pages

Polypyrrole–Nickel Hydroxide Hybrid Nanowires as Future Materials for Energy Storage

  • Agnieszka Brzózka,
  • Krzysztof Fic,
  • Joanna Bogusz,
  • Anna M. Brudzisz,
  • Mateusz M. Marzec,
  • Marta Gajewska and
  • Grzegorz D. Sulka

24 February 2019

Hybrid materials play an essential role in the development of the energy storage technologies since a multi-constituent system merges the properties of the individual components. Apart from new features and enhanced performance, such an approach quit...

  • Article
  • Open Access
34 Citations
6,834 Views
11 Pages

Preparation and Characterization of Microsphere ZnO ALD Coating Dedicated for the Fiber-Optic Refractive Index Sensor

  • Paulina Listewnik,
  • Marzena Hirsch,
  • Przemysław Struk,
  • Matthieu Weber,
  • Mikhael Bechelany and
  • Małgorzata Jędrzejewska-Szczerska

23 February 2019

We report the fabrication of a novel fiber-optic sensor device, based on the use of a microsphere conformally coated with a thin layer of zinc oxide (ZnO) by atomic layer deposition (ALD), and its use as a refractive index sensor. The microsphere was...

  • Article
  • Open Access
31 Citations
5,597 Views
9 Pages

23 February 2019

A fluorescence and solid phase extraction (SPE) adsorption nanomaterials of molecularly imprinted polymers (MIPs) based on quantum dot-grafted covalent organic frameworks (QD-grafted COFs) was prepared by one-pot surface-imprinting synthesis method....

  • Article
  • Open Access
29 Citations
7,343 Views
9 Pages

Resorcinol Functionalized Gold Nanoparticles for Formaldehyde Colorimetric Detection

  • Carlos Martínez-Aquino,
  • Ana M. Costero,
  • Salvador Gil and
  • Pablo Gaviña

22 February 2019

Gold nanoparticles functionalized with resorcinol moieties have been prepared and used for detecting formaldehyde both in solution and gas phases. The detection mechanism is based on the color change of the probe upon the aggregation of the nanoparti...

  • Article
  • Open Access
34 Citations
5,948 Views
20 Pages

22 February 2019

Bacterial cellulose (BC)–gelatin (GEL) membranes were processed by successive periodate oxidation and a freeze-thawing/carbodiimide crosslinking procedure, first facilitating a Schiff-base reaction among respective aldehyde and hydroxyl groups,...

  • Article
  • Open Access
15 Citations
4,802 Views
27 Pages

22 February 2019

Influence of electrode potential on the electrochemical behavior of a 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF4) solution containing 5 wt % 1-ethyl-3-methylimidazolium bromide (EMImBr) has been investigated using electrochemical and sync...

  • Review
  • Open Access
140 Citations
13,960 Views
18 Pages

20 February 2019

Graphene, a single atom thick layer of two-dimensional closely packed honeycomb carbon lattice, and its derivatives have attracted much attention in the field of biomedical, due to its unique physicochemical properties. The valuable physicochemical p...

  • Article
  • Open Access
24 Citations
4,668 Views
17 Pages

20 February 2019

In this study, feather keratin/polyvinyl alcohol/tris(hydroxymethyl)aminomethane (FK/PVA/Tris) bionanocomposite films containing two types of nanoparticles, namely one-dimensional sodium montmorillonite (MMT) clay platelets (0.5, 1, 3, and 5 wt%) and...

  • Article
  • Open Access
12 Citations
5,051 Views
15 Pages

Metal-Support Cooperative Effects in Au/VPO for the Aerobic Oxidation of Benzyl Alcohol to Benzyl Benzoate

  • Sebastiano Campisi,
  • Michele Ferri,
  • Carine E. Chan-Thaw,
  • Felipe J. Sanchez Trujillo,
  • Davide Motta,
  • Tommaso Tabanelli,
  • Nikolaos Dimitratos and
  • Alberto Villa

20 February 2019

This paper studies the cooperative effect of Au nanoparticles deposited on vanadyl pyrophosphate oxide (VPO) in the liquid phase oxidation of benzyl alcohol. VPO was prepared using the classical method by thermally treating VOHPO4·0.5H2O precu...

  • Article
  • Open Access
21 Citations
5,661 Views
11 Pages

20 February 2019

Silica aerogels have attracted tremendous interest due to their high specific surface area and the physical, chemical, and mechanical properties as promising materials for thermal insulation, chemical sensors, and energy storage devices. However, lar...

  • Article
  • Open Access
35 Citations
5,030 Views
20 Pages

20 February 2019

In this work, we aim to study free vibration of functionally graded piezoelectric material (FGPM) cylindrical nanoshells with nano-voids. The present model incorporates the small scale effect and thermo-electro-mechanical loading. Two types of porosi...

  • Article
  • Open Access
24 Citations
4,495 Views
19 Pages

19 February 2019

Calcium leaching is a degradation progress inside hardened cement composites, where Ca2+ ions in cement pore solution can migrate into the aggressive solution. In this work, calcium leaching of graphene oxide (GO) reinforced cement composites was eff...

  • Article
  • Open Access
25 Citations
4,827 Views
10 Pages

Multi-Level Cell Properties of a Bilayer Cu2O/Al2O3 Resistive Switching Device

  • Jonas Deuermeier,
  • Asal Kiazadeh,
  • Andreas Klein,
  • Rodrigo Martins and
  • Elvira Fortunato

19 February 2019

Multi-level resistive switching characteristics of a Cu2O/Al2O3 bilayer device are presented. An oxidation state gradient in copper oxide induced by the fabrication process was found to play a dominant role in defining the multiple resistance states....

  • Article
  • Open Access
17 Citations
4,277 Views
11 Pages

19 February 2019

In this study, a series of HZSM-5 catalysts were prepared by the chemical liquid-phase deposition method, and low concentration toluene degradation was carried out in an atmospheric pressure dielectric barrier discharge (DBD) reactor. The catalysts w...

  • Article
  • Open Access
37 Citations
6,237 Views
10 Pages

Nonlinear Optical Studies of Gold Nanoparticle Films

  • Anuradha Rout,
  • Ganjaboy S. Boltaev,
  • Rashid A. Ganeev,
  • Yue Fu,
  • Sandeep Kumar Maurya,
  • Vyacheslav V. Kim,
  • Konda Srinivasa Rao and
  • Chunlei Guo

19 February 2019

Gold films are widely used for different applications. We present the results of third- and high-order nonlinear optical studies of the thin films fabricated from Au nanoparticle solutions by spin-coating methods. These nanoparticles were synthesized...

  • Article
  • Open Access
35 Citations
5,108 Views
14 Pages

19 February 2019

For the purposes of strength, military equipment camouflage, and protecting the health of organisms, electromagnetic wave absorbing materials have received a lot of attention and are widely studied. In addition to having a strong absorption intensity...

  • Article
  • Open Access
24 Citations
5,007 Views
11 Pages

Comparison of Frictional Properties of CVD-Grown MoS2 and Graphene Films under Dry Sliding Conditions

  • Dae-Hyun Cho,
  • Jaehyuck Jung,
  • Chan Kim,
  • Jinhwan Lee,
  • Se-Doo Oh,
  • Kwang-Seop Kim and
  • Changgu Lee

19 February 2019

In the present study, dry friction and wear properties of atomically thin CVD-grown graphene and MoS2 films on SiO2/Si substrates were compared at low (72 MPa) and high (378 MPa) contact pressures. Analysis of atomic force microscopy images of these...

  • Article
  • Open Access
13 Citations
3,611 Views
12 Pages

Morphology and Kinetics Evolution of Nanoscale Phase in Fe–Cr Alloys under External Strain

  • Lihui Zhu,
  • Yongsheng Li,
  • Shujing Shi,
  • Zhengwei Yan,
  • Jing Chen and
  • Shahid Maqbool

19 February 2019

Uniaxial strain was applied to aging Fe–Cr alloys to study the morphological orientation and kinetics of the nanoscale α′ phase by utilizing phase-field simulation. The effects of applied uniaxial compressive and tensile strain on t...

  • Article
  • Open Access
37 Citations
5,172 Views
13 Pages

Thioredoxin Reductase Activity Predicts Gold Nanoparticle Radiosensitization Effect

  • Sébastien Penninckx,
  • Anne-Catherine Heuskin,
  • Carine Michiels and
  • Stéphane Lucas

19 February 2019

Gold nanoparticles (GNPs) have been shown to be effective contrast agents for imaging and emerge as powerful radiosensitizers, constituting a promising theranostic agent for cancer. Although the radiosensitization effect was initially attributed to a...

  • Review
  • Open Access
167 Citations
18,263 Views
42 Pages

19 February 2019

Dietary supplements and foods for special medical purposes are special medical products classified according to the legal basis. They are regulated, for example, by the European Food Safety Authority and the U.S. Food and Drug Administration, as well...

  • Review
  • Open Access
118 Citations
18,301 Views
28 Pages

Transfer Printing and its Applications in Flexible Electronic Devices

  • Honglei Zhou,
  • Weiyang Qin,
  • Qingmin Yu,
  • Huanyu Cheng,
  • Xudong Yu and
  • Huaping Wu

18 February 2019

Flexible electronic systems have received increasing attention in the past few decades because of their wide-ranging applications that include the flexible display, eyelike digital camera, skin electronics, and intelligent surgical gloves, among many...

  • Article
  • Open Access
88 Citations
9,181 Views
19 Pages

Preparation of Self-Assembled Composite Films Constructed by Chemically-Modified MXene and Dyes with Surface-Enhanced Raman Scattering Characterization

  • Kaiyue Chen,
  • Xiaoya Yan,
  • Junkai Li,
  • Tifeng Jiao,
  • Chong Cai,
  • Guodong Zou,
  • Ran Wang,
  • Mingli Wang,
  • Lexin Zhang and
  • Qiuming Peng

18 February 2019

The effective functionalization and self-assembly of MXene are of crucial importance for a broad range of nanomaterial applications. In this work, we investigated the aggregates of sulfanilic acid-modified MXene (abbreviated as MXene-SO3H) with three...

  • Review
  • Open Access
135 Citations
16,226 Views
27 Pages

18 February 2019

Biomolecular self-assembly provides a facile way to synthesize functional nanomaterials. Due to the unique structure and functions of biomolecules, the created biological nanomaterials via biomolecular self-assembly have a wide range of applications,...

  • Article
  • Open Access
15 Citations
5,446 Views
14 Pages

Understanding the Impact of Cu-In-Ga-S Nanoparticles Compactness on Holes Transfer of Perovskite Solar Cells

  • Dandan Zhao,
  • Yinghui Wu,
  • Bao Tu,
  • Guichuan Xing,
  • Haifeng Li and
  • Zhubing He

18 February 2019

Although a compact holes-transport-layer (HTL) film has always been deemed mandatory for perovskite solar cells (PSCs), the impact their compactness on the device performance has rarely been studied in detail. In this work, based on a device structur...

  • Article
  • Open Access
30 Citations
5,945 Views
20 Pages

Elaboration of Trans-Resveratrol Derivative-Loaded Superparamagnetic Iron Oxide Nanoparticles for Glioma Treatment

  • Fadoua Sallem,
  • Rihab Haji,
  • Dominique Vervandier-Fasseur,
  • Thomas Nury,
  • Lionel Maurizi,
  • Julien Boudon,
  • Gérard Lizard and
  • Nadine Millot

18 February 2019

In this work, new nanohybrids based on superparamagnetic iron oxide nanoparticles (SPIONs) were elaborated and discussed for the first time as nanovectors of a derivative molecule of trans-resveratrol (RSV), a natural antioxidant molecule, which can...

  • Article
  • Open Access
109 Citations
10,310 Views
17 Pages

A Smart Nanovector for Cancer Targeted Drug Delivery Based on Graphene Quantum Dots

  • Daniela Iannazzo,
  • Alessandro Pistone,
  • Consuelo Celesti,
  • Claudia Triolo,
  • Salvatore Patané,
  • Salvatore V. Giofré,
  • Roberto Romeo,
  • Ida Ziccarelli,
  • Raffaella Mancuso and
  • Angela Di Pietro
  • + 3 authors

18 February 2019

Graphene quantum dots (GQD), the new generation members of graphene-family, have shown promising applications in anticancer therapy. In this study, we report the synthesis of a fluorescent and biocompatible nanovector, based on GQD, for the targeted...

  • Article
  • Open Access
55 Citations
6,849 Views
17 Pages

Electrospinning of Polystyrene/Polyhydroxybutyrate Nanofibers Doped with Porphyrin and Graphene for Chemiresistor Gas Sensors

  • Joshua Avossa,
  • Roberto Paolesse,
  • Corrado Di Natale,
  • Emiliano Zampetti,
  • Giovanni Bertoni,
  • Fabrizio De Cesare,
  • Giuseppe Scarascia-Mugnozza and
  • Antonella Macagnano

17 February 2019

Structural and functional properties of polymer composites based on carbon nanomaterials are so attractive that they have become a big challenge in chemical sensors investigation. In the present study, a thin nanofibrous layer, comprising two insulat...

  • Article
  • Open Access
96 Citations
8,863 Views
18 Pages

Preparation of Lignin Nanoparticles from Wood Waste for Wood Surface Treatment

  • Florian Zikeli,
  • Vittorio Vinciguerra,
  • Alessandro D’Annibale,
  • Donatella Capitani,
  • Manuela Romagnoli and
  • Giuseppe Scarascia Mugnozza

17 February 2019

Lignin was isolated from wood wastes comprising Iroko sawdust (IR) and mixed sawdust from Iroko and Norway spruce (IRNS), furnished by a local wood houses producer. The respective acidolysis lignin fractions were structurally characterized using pyro...

  • Article
  • Open Access
118 Citations
10,473 Views
13 Pages

Chitosan-Based Carbon Quantum Dots for Biomedical Applications: Synthesis and Characterization

  • Łukasz Janus,
  • Marek Piątkowski,
  • Julia Radwan-Pragłowska,
  • Dariusz Bogdał and
  • Dalibor Matysek

16 February 2019

Rapid development in medicine and pharmacy has created a need for novel biomaterials with advanced properties such as photoluminescence, biocompability and long-term stability. The following research deals with the preparation of novel types of N-dop...

  • Article
  • Open Access
54 Citations
6,061 Views
16 Pages

In Situ Synthesis of a Stable Fe3O4@Cellulose Nanocomposite for Efficient Catalytic Degradation of Methylene Blue

  • Quan Lu,
  • Yanjuan Zhang,
  • Huayu Hu,
  • Wen Wang,
  • Zuqiang Huang,
  • Dong Chen,
  • Mei Yang and
  • Jing Liang

16 February 2019

To rapidly obtain a stable Fe3O4@cellulose heterogeneous Fenton catalyst, a novel in situ chemical co-precipitation method was developed. Compared with mechanical activation (MA)-pretreated cellulose (MAC), MA + FeCl3 (MAFC)-pretreated cellulose (MAF...

  • Article
  • Open Access
27 Citations
5,516 Views
12 Pages

Removing Metal Ions from Water with Graphene–Bovine Serum Albumin Hybrid Membrane

  • Xiaoqing Yu,
  • Shuwei Sun,
  • Lin Zhou,
  • Zhicong Miao,
  • Xiaoyuan Zhang,
  • Zhiqiang Su and
  • Gang Wei

16 February 2019

Here we report the fabrication of graphene oxide (GO)-based membranes covalently combined with bovine serum albumin (BSA) for metal ions detection. In this system, BSA acts as a transporter protein in the membrane and endows the membrane with selecti...

  • Article
  • Open Access
48 Citations
7,279 Views
12 Pages

16 February 2019

Metal–organic framework (MOF)-based derivatives are attracting increased interest in various research fields. In this study, nano-cellulose MOF-derived carbon-doped CuO/Fe3O4 nanocomposites were successfully synthesized via direct calcination o...

  • Article
  • Open Access
12 Citations
3,855 Views
12 Pages

16 February 2019

In this work, an aggregation-induced emission (AIE) sensor for the detection of Fe3+ ions was fabricated through the electrostatic interaction between 1,1,2-triphenyl-2-[4-(3-sulfonatopropoxyl)-phenyl]-ethene sodium salt (SPOTPE) and quaternized cell...

  • Article
  • Open Access
24 Citations
3,953 Views
15 Pages

15 February 2019

Porous activated carbon with specific morphology and structure are of particular importance for waste water treatment, especially for the adsorption of toxic hexavalent chromium Cr(VI). However, the scalable and cheap production of such absorbents st...

  • Article
  • Open Access
126 Citations
6,693 Views
15 Pages

15 February 2019

Separation of impurities (CO2 and N2) from CH4 is an important issue for natural gas alternatives (such as coalbed gas, biogas, and landfill gas) upgrading. It is notably challenging to synthesize high N-doped porous carbon with an appropriate porous...

  • Article
  • Open Access
21 Citations
5,255 Views
18 Pages

Experimental Convection Heat Transfer Analysis of a Nano-Enhanced Industrial Coolant

  • Eva Álvarez-Regueiro,
  • Javier P. Vallejo,
  • José Fernández-Seara,
  • Josefa Fernández and
  • Luis Lugo

15 February 2019

Convection heat transfer coefficients and pressure drops of four functionalized graphene nanoplatelet nanofluids based on the commercial coolant Havoline® XLC Pre-mixed 50/50 were experimentally determined to assess its thermal performance. The p...

  • Article
  • Open Access
56 Citations
7,842 Views
9 Pages

Tunable Electronic Properties of Nitrogen and Sulfur Doped Graphene: Density Functional Theory Approach

  • Ji Hye Lee,
  • Sung Hyun Kwon,
  • Soonchul Kwon,
  • Min Cho,
  • Kwang Ho Kim,
  • Tae Hee Han and
  • Seung Geol Lee

15 February 2019

We calculated the band structures of a variety of N- and S-doped graphenes in order to understand the effects of the N and S dopants on the graphene electronic structure using density functional theory (DFT). Band-structure analysis revealed energy b...

  • Article
  • Open Access
14 Citations
3,840 Views
16 Pages

15 February 2019

In this work, the multiferroic property of Ba-deficient BaTiO3 (001) ultrathin film is studied employing the first-principles approach. The BaTiO3 (001) ultrathin film is more energetically stable and behaves as a semiconductor relative to the (111)...

  • Feature Paper
  • Article
  • Open Access
77 Citations
6,789 Views
18 Pages

15 February 2019

In this study, novel active films made of poly(ε-caprolactone) (PCL) containing a solid dispersion of sage extract (SE) were developed by means of the electrospinning technique and subsequent annealing treatment. Initially, the antioxidant an...

  • Article
  • Open Access
25 Citations
3,814 Views
25 Pages

15 February 2019

This article aims to investigate free vibration and buckling of functionally graded (FG) nanoporous metal foam (NPMF) nanoshells. The first-order shear deformation (FSD) shell theory is adopted and the theoretical model is formulated by using Mindlin...

  • Article
  • Open Access
58 Citations
7,144 Views
13 Pages

Highly Charged Cellulose Nanocrystals Applied as A Water Treatment Flocculant

  • Dana Morantes,
  • Efrén Muñoz,
  • Doron Kam and
  • Oded Shoseyov

15 February 2019

Various cellulosic materials have replaced petroleum-derived polymers, offering natural and sustainable alternatives. Among them, cellulose nanocrystals (CNC) feature an easily modifiable surface, enabling the exploration of a wide spectrum of applic...

  • Article
  • Open Access
7 Citations
3,441 Views
14 Pages

15 February 2019

Hierarchical nanostructures (HNs) are possibly endowed with novel properties due to their complex three-dimensional (3D) structures. Here, we provide a novel stepwise growth strategy of Coordination Complex Transformation-Assisted Growth for fabricat...

  • Article
  • Open Access
17 Citations
4,691 Views
13 Pages

CdSe/ZnS Quantum Dots Impaired the First Two Generations of Placenta Growth in an Animal Model, Based on the Shh Signaling Pathway

  • Wuding Hong,
  • Huijuan Kuang,
  • Xingping He,
  • Lin Yang,
  • Pengfei Yang,
  • Bolu Chen,
  • Zoraida P. Aguilar and
  • Hengyi Xu

14 February 2019

The toxicity, especially the transgenerational toxicity of quantum dots (QDs) in vivo, is still scarcely understood in spite of great promising applications of QDs in biomedicine. In this study, the maternal status, pregnancy outcome, and fetus devel...

  • Article
  • Open Access
11 Citations
4,077 Views
10 Pages

14 February 2019

Flash sintering is the most promising sintering method because of its high speed and large area of effect. However, current flash sintering processes exhibit poor stability and the conductive pattern surface is highly susceptible to damage during thi...

  • Review
  • Open Access
43 Citations
9,533 Views
24 Pages

14 February 2019

In recent years, matrix-assisted laser desorption/ionization (MALDI) has become the main tool for the study of biological macromolecules, such as protein nano-machines, especially in the determination of their molecular masses, structure, and post-tr...

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Nanomaterials - ISSN 2079-4991