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Polymers, Volume 13, Issue 16

2021 August-2 - 257 articles

Cover Story: Anionic nanocellulose-based hydrogels with entrapped T7 bacteriophages were crosslinked within polyHIPE particle scaffolds to protect hydrogels from mechanical stimuli and collapse, which enable successful phage protection in an acidic environment resembling the human stomach. Complete phage release was achieved when the hydrogel totally lost its network at a pH similar to that found in the human duodenum. Furthermore, due to a large surface-to-volume ratio, fast zero-order release was observed, making the polyHIPE/hydrogel system an ideal concept for biological drug delivery applications. View this paper.
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Articles (257)

  • Article
  • Open Access
13 Citations
4,074 Views
14 Pages

23 August 2021

A novel high-efficient flame retardant epoxy grafted poly-acrylic resin modified by phosphorus and nitrogen was successfully synthesized by radical grafting polymerization and solution polymerization simultaneously. The flame retardancy of copolymer...

  • Article
  • Open Access
12 Citations
4,317 Views
12 Pages

Blended Anion Exchange Membranes for Vanadium Redox Flow Batteries

  • Tae Yang Son,
  • Kwang Seop Im,
  • Ha Neul Jung and
  • Sang Yong Nam

23 August 2021

In this study, blended anion exchange membranes were prepared using polyphenylene oxide containing quaternary ammonium groups and polyvinylidene fluoride. A polyvinylidene fluoride with high hydrophobicity was blended in to lower the vanadium ion per...

  • Review
  • Open Access
230 Citations
20,741 Views
19 Pages

The State of the Art of Material Jetting—A Critical Review

  • Orhan Gülcan,
  • Kadir Günaydın and
  • Aykut Tamer

23 August 2021

Material jetting (MJ) technology is an additive manufacturing method that selectively cures liquid photopolymer to build functional parts. The use of MJ technology has increased in popularity and been adapted by different industries, ranging from bio...

  • Article
  • Open Access
30 Citations
5,323 Views
18 Pages

Characterization of Gelatin and Hydrolysates from Valorization of Farmed Salmon Skin By-Products

  • José Antonio Vázquez,
  • Carolina Hermida-Merino,
  • Daniel Hermida-Merino,
  • Manuel M. Piñeiro,
  • Johan Johansen,
  • Carmen G. Sotelo,
  • Ricardo I. Pérez-Martín and
  • Jesus Valcarcel

23 August 2021

Salmon processing commonly involves the skinning of fish, generating by-products that need to be handled. Such skin residues may represent valuable raw materials from a valorization perspective, mainly due to their collagen content. With this approac...

  • Article
  • Open Access
8 Citations
3,185 Views
21 Pages

23 August 2021

The membrane emulsification process (ME) using a metallic membrane was the first stage for preparing a spherical and monodisperse thermoresponsive molecularly imprinted polymer (TSMIP). In the second step of the preparation, after the ME process, the...

  • Article
  • Open Access
24 Citations
5,885 Views
14 Pages

23 August 2021

Crosslinking of polyolefin-based polymers can improve their thermal and mechanical properties, which can then be used in various applications. Radiation-induced crosslinking can be done easily and usefully by irradiation without a crosslinking agent....

  • Article
  • Open Access
24 Citations
4,737 Views
23 Pages

23 August 2021

Thermomechanical modeling of epoxy/graphene oxide under quasi-static and dynamic loading requires thermo-mechanical properties such as Young’s modulus, Poisson’s ratio, thermal conductivity, and frequency-temperature dependent viscoelastic properties...

  • Review
  • Open Access
13 Citations
4,730 Views
26 Pages

23 August 2021

The COVID-19 pandemic has driven a global research to uncover novel, effective therapeutical and diagnosis approaches. In addition, control of spread of infection has been targeted through development of preventive tools and measures. In this regard,...

  • Review
  • Open Access
32 Citations
7,902 Views
27 Pages

23 August 2021

Neural electrodes are essential for nerve signal recording, neurostimulation, neuroprosthetics and neuroregeneration, which are critical for the advancement of brain science and the establishment of the next-generation brain–electronic interface, cen...

  • Article
  • Open Access
23 Citations
3,634 Views
10 Pages

23 August 2021

Fly ash polymer composites are innovative high-performance materials that reduce the environmental worries and disposal complications of heavy industry produced fly ash. This study developed and characterized such composites of high-density polyethyl...

  • Article
  • Open Access
9 Citations
2,958 Views
18 Pages

23 August 2021

The proper choice of a material system for bioresorbable synthetic bone graft substitutes imposes strict requirements for mechanical properties, bioactivity, biocompatibility, and osteoconductivity. This study aims to characterize the effect of in-mo...

  • Article
  • Open Access
14 Citations
3,998 Views
31 Pages

Experimental—FEM Study on Effect of Tribological Load Conditions on Wear Resistance of Three-Component High-Strength Solid-Lubricant PI-Based Composites

  • Sergey V. Panin,
  • Jiangkun Luo,
  • Dmitry G. Buslovich,
  • Vladislav O. Alexenko,
  • Lyudmila A. Kornienko,
  • Svetlana A. Bochkareva and
  • Anton V. Byakov

23 August 2021

The structure, mechanical and tribological properties of the polyimide-based composites reinforced with chopped carbon fibers (CCF) and loaded with solid-lubricant commercially available fillers of various natures were investigated. The metal- and ce...

  • Article
  • Open Access
32 Citations
4,768 Views
20 Pages

22 August 2021

Every year, ceramic tile factories and the iron smelting industry produce huge amounts of waste ceramic tiles and blast furnace slag (BFS), respectively. In the field of construction materials, this waste can be used as a raw material for binders, th...

  • Article
  • Open Access
18 Citations
3,717 Views
18 Pages

A Negative Index Nonagonal CSRR Metamaterial-Based Compact Flexible Planar Monopole Antenna for Ultrawideband Applications Using Viscose-Wool Felt

  • Kabir Hossain,
  • Thennarasan Sabapathy,
  • Muzammil Jusoh,
  • Mahmoud A. Abdelghany,
  • Ping Jack Soh,
  • Mohamed Nasrun Osman,
  • Mohd Najib Mohd Yasin,
  • Hasliza A. Rahim and
  • Samir Salem Al-Bawri

22 August 2021

In this paper, a compact textile ultrawideband (UWB) planar monopole antenna loaded with a metamaterial unit cell array (MTMUCA) structure with epsilon-negative (ENG) and near-zero refractive index (NZRI) properties is proposed. The proposed MTMUCA w...

  • Article
  • Open Access
14 Citations
3,926 Views
15 Pages

22 August 2021

This paper describes the fabrication of a structural scaffold consisting of both randomly oriented nanofibers and triangular prism patterns on the scaffold surface using a combination technique of electrospinning and collector templates. The polycapr...

  • Article
  • Open Access
9 Citations
2,910 Views
16 Pages

DNA Interaction with a Polyelectrolyte Monolayer at Solution—Air Interface

  • Nikolay S. Chirkov,
  • Richard A. Campbell,
  • Alexander V. Michailov,
  • Petr S. Vlasov and
  • Boris A. Noskov

22 August 2021

The formation of ordered 2D nanostructures of double stranded DNA molecules at various interfaces attracts more and more focus in medical and engineering research, but the underlying intermolecular interactions still require elucidation. Recently, it...

  • Article
  • Open Access
3 Citations
2,956 Views
13 Pages

22 August 2021

We synthesized a series of polystyrene derivatives containing various side groups, such as the 4-(tert-butyl)-phenoxymethyl, 3-(tert-butyl)-phenoxymethyl, 2-(tert-butyl)-phenoxymethyl, 4-cumyl-phenoxymethyl, and 4-trityl-phenoxymethyl groups, through...

  • Article
  • Open Access
9 Citations
3,285 Views
14 Pages

22 August 2021

Epoxy resin with excellent mechanical properties, chemical stability, and corrosion resistance has been widely used in automotive and aerospace industries. A thin film of epoxy deposited on a substrate has great application in adhesive bonding and pr...

  • Article
  • Open Access
45 Citations
6,017 Views
11 Pages

Colorless Polyimides Derived from an Alicyclic Tetracarboxylic Dianhydride, CpODA

  • Hiroki Ozawa,
  • Eriko Ishiguro,
  • Yuri Kyoya,
  • Yasuaki Kikuchi and
  • Toshihiko Matsumoto

22 August 2021

An alicyclic tetracarboxylic dianhydride having cyclopentanone bis-spironorbornane structure (CpODA) was polycondensated with aromatic dianhydrides to form the corresponding poly(amic acid)s which possessed logarithmic viscosities in the range 1.47–0...

  • Article
  • Open Access
10 Citations
5,668 Views
22 Pages

22 August 2021

Pipes of polypropylene random (PP-R) copolymers are the best choice for hot- and cold-water networks. Validation of a severe test, accomplishing the ISO 1167 standard, is mandatory to assess their service lifetime expectancy. This work evaluates the...

  • Review
  • Open Access
368 Citations
27,644 Views
33 Pages

22 August 2021

Drug delivery through the skin offers many advantages such as avoidance of hepatic first-pass metabolism, maintenance of steady plasma concentration, safety, and compliance over oral or parenteral pathways. However, the biggest challenge for transder...

  • Article
  • Open Access
3 Citations
3,917 Views
19 Pages

Exohedral Functionalization of Fullerene by Substituents Controlling of Molecular Organization for Spontaneous C60 Dimerization in Liquid Crystal Solutions and in a Bulk Controlled by a Potential

  • Malgorzata Czichy,
  • Alessia Colombo,
  • Pawel Wagner,
  • Patryk Janasik,
  • Claudia Dragonetti,
  • Rathinam Raja,
  • David L. Officer and
  • Leeyih Wang

22 August 2021

A study was carried out on the possibility of orderly and spontaneous dimerization at room temperature of C60 cages in fullerene liquid crystal fullerene dyads (R-C60). For this purpose, dyads with a structural elements feature supporting π-stacking...

  • Article
  • Open Access
42 Citations
6,174 Views
16 Pages

Thermal Stability and Decomposition Mechanism of PLA Nanocomposites with Kraft Lignin and Tannin

  • Nina Maria Ainali,
  • Evangelia Tarani,
  • Alexandra Zamboulis,
  • Klementina Pušnik Črešnar,
  • Lidija Fras Zemljič,
  • Konstantinos Chrissafis,
  • Dimitra A. Lambropoulou and
  • Dimitrios N. Bikiaris

22 August 2021

Packaging applications cover approximately 40% of the total plastics production, whereas food packaging possesses a high proportion within this context. Due to several environmental concerns, petroleum-based polymers have been shifted to their biobas...

  • Article
  • Open Access
10 Citations
3,517 Views
14 Pages

21 August 2021

Anethole (AN) is widely used as an odor cleaner in daily necessities, and can also be applied in the fields of food additives, drug synthesis, natural preservatives, and polymeric materials’ preparation. Considering environmental and economic benefit...

  • Review
  • Open Access
29 Citations
6,110 Views
20 Pages

21 August 2021

The robotics design process can be complex with potentially multiple design iterations. The use of 3D printing is ideal for rapid prototyping and has conventionally been utilised in concept development and for exploring different design parameters th...

  • Article
  • Open Access
18 Citations
4,730 Views
13 Pages

Hydrophobic Modification of Chitosan via Reactive Solvent-Free Extrusion

  • Tatiana A. Akopova,
  • Tatiana S. Demina,
  • Mukhamed A. Khavpachev,
  • Tatiana N. Popyrina,
  • Andrey V. Grachev,
  • Pavel L. Ivanov and
  • Alexander N. Zelenetskii

21 August 2021

Hydrophobic derivatives of polysaccharides possess an amphiphilic behavior and are widely used as rheological modifiers, selective sorbents, and stabilizers for compositions intended for various applications. In this work, we studied the mechanochemi...

  • Article
  • Open Access
17 Citations
3,778 Views
13 Pages

Biomaterial-Assisted Anastomotic Healing: Serosal Adhesion of Pectin Films

  • Yifan Zheng,
  • Aidan F. Pierce,
  • Willi L. Wagner,
  • Hassan A. Khalil,
  • Zi Chen,
  • Charlotta Funaya,
  • Maximilian Ackermann and
  • Steven J. Mentzer

21 August 2021

Anastomotic leakage is a frequent complication of intestinal surgery and a major source of surgical morbidity. The timing of anastomotic failures suggests that leaks are the result of inadequate mechanical support during the vulnerable phase of wound...

  • Article
  • Open Access
63 Citations
6,666 Views
22 Pages

Bioinspired Design of Sericin/Chitosan/Ag@MOF/GO Hydrogels for Efficiently Combating Resistant Bacteria, Rapid Hemostasis, and Wound Healing

  • Meng Zhang,
  • Dong Wang,
  • Nana Ji,
  • Shaoxiang Lee,
  • Guohui Wang,
  • Yuqi Zheng,
  • Xin Zhang,
  • Lin Yang,
  • Zhiwei Qin and
  • Yang Yang

21 August 2021

Due to the spread of drug-resistant bacteria in hospitals, the development of antibacterial dressings has become a strategy to control wound infections caused by bacteria. Here, we reported a green strategy for in situ biomimetic syntheses of silver...

  • Article
  • Open Access
30 Citations
5,592 Views
15 Pages

Study of Different Chitosan/Sodium Carboxymethyl Cellulose Proportions in the Development of Polyelectrolyte Complexes for the Sustained Release of Clarithromycin from Matrix Tablets

  • Víctor Guarnizo-Herrero,
  • Carlos Torrado-Salmerón,
  • Norma Sofía Torres Pabón,
  • Guillermo Torrado Durán,
  • Javier Morales and
  • Santiago Torrado-Santiago

21 August 2021

This study investigated the combination of different proportions of cationic chitosan and anionic carboxymethyl cellulose (CMC) for the development of polyelectrolyte complexes to be used as a carrier in a sustained-release system. Analysis via scann...

  • Article
  • Open Access
3 Citations
2,983 Views
13 Pages

21 August 2021

The purpose of the study was to investigate the bacterial viability of the initial biofilm on the surface of experimental modified dental resin composites. Twenty-five healthy individuals with good oral hygiene were included in this study. In a split...

  • Article
  • Open Access
12 Citations
4,535 Views
17 Pages

Fully Bio-Based Elastomer Nanocomposites Comprising Polyfarnesene Reinforced with Plasma-Modified Cellulose Nanocrystals

  • Ilse Magaña,
  • Dimitrios Georgouvelas,
  • Rishab Handa,
  • María Guadalupe Neira Velázquez,
  • Héctor Ricardo López González,
  • Francisco Javier Enríquez Medrano,
  • Ramón Díaz de León and
  • Luis Valencia

21 August 2021

This article proposes a process to prepare fully bio-based elastomer nanocomposites based on polyfarnesene and cellulose nanocrystals (CNC). To improve the compatibility of cellulose with the hydrophobic matrix of polyfarnesene, the surface of CNC wa...

  • Article
  • Open Access
18 Citations
3,978 Views
11 Pages

Influence of Dental Glass Fibers and Orthopedic Mesh on the Failure Loads of Polymethyl Methacrylate Denture Base Resin

  • Muhammad H. Rana,
  • Sharaz Shaik,
  • Mohammad S. Hameed,
  • Samar Al-Saleh,
  • Eman M. AlHamdan,
  • Abdullah Alshahrani,
  • Abdulaziz Alqahtani,
  • Ahmed Heji Albaqawi,
  • Fahim Vohra and
  • Tariq Abduljabbar

20 August 2021

The aim of the present study was to evaluate the fracture loads of polymethyl methacrylate (PMMA) complete denture bases reinforced with glass-fiber mesh and orthopedic casting tape (OCT) in comparison to conventional PMMA dentures under artificial a...

  • Article
  • Open Access
63 Citations
7,100 Views
10 Pages

20 August 2021

Laser-induced graphene (LIG) has recently been receiving increasing attention due to its simple fabrication and low cost. This study reports a flexible laser-induced graphene-based electrochemical biosensor fabricated on a polymer substrate by the la...

  • Communication
  • Open Access
5 Citations
2,898 Views
11 Pages

Conformational Behavior, Topographical Features, and Antioxidant Activity of Partly De-Esterified Arabinoxylans

  • Yubia De Anda-Flores,
  • Elizabeth Carvajal-Millan,
  • Jaime Lizardi-Mendoza,
  • Agustin Rascon-Chu,
  • Judith Tanori-Cordova,
  • Ana Luisa Martínez-López,
  • Alexel J. Burgara-Estrella and
  • Martin R. Pedroza-Montero

20 August 2021

This study aimed to investigate the effect of arabinoxylans (AX) partial de-esterification with feruloyl esterase on the polysaccharide conformational behavior, topographical features, and antioxidant activity. After enzyme treatment, the ferulic aci...

  • Article
  • Open Access
17 Citations
3,587 Views
11 Pages

20 August 2021

This study investigates the impact of spent coffee biochar (Biochar) compared to carbon black (CB) as a partial replacement for carbon black in epoxidized natural rubber (ENR). Particle size and elemental analysis were used to characterize the biocha...

  • Article
  • Open Access
8 Citations
3,057 Views
10 Pages

20 August 2021

This study proposes and experimentally demonstrates a NOA61-polymer fiber Fizeau interferometer (PFFI) connected to a flexible NOA65-polymer taper (PT) for simultaneous measurement of tilt angle and temperature (T). The PT/PFFI fiber sensor consists...

  • Article
  • Open Access
18 Citations
4,366 Views
18 Pages

20 August 2021

Bubble growth in the polymer extrusion foaming process occurs under a dynamic melt flow. For non-Newtonian fluids, this work successfully coupled the dynamic melt flow simulation with the bubble growth model to realize bubble growth predictions in an...

  • Article
  • Open Access
15 Citations
3,689 Views
11 Pages

Influence of Citric Acid on the Bond Strength of Beech Wood

  • Goran Mihulja,
  • Vjekoslav Živković,
  • Dominik Poljak,
  • Bogoslav Šefc and
  • Tomislav Sedlar

20 August 2021

In this study, beech wood (Fagus silvatica L.) has been chemically modified with citric acid (Acidum citricum) and sodium hypophosphate (SHP) as the catalyst and gradually thermo-condensed in the dryer. Afterwards, wetting angle, surface energy, and...

  • Article
  • Open Access
7 Citations
2,824 Views
15 Pages

Hybrid Hosts Based on Sodium Alginate and Porous Clay Heterostructures for Drug Encapsulation

  • Anda Ionelia Voicu (Mihai),
  • Sorina Alexandra Gȃrea,
  • Eugeniu Vasile,
  • Adi Ghebaur and
  • Horia Iovu

20 August 2021

In this study, some hybrid materials based on sodium alginate (NaAlg) and porous clay heterostructures (PCHs) were investigated as new hosts for 5-Fluorouracil (5-FU) encapsulation. The hybrid hosts were prepared by ionotropic gelation technique usin...

  • Review
  • Open Access
51 Citations
8,944 Views
25 Pages

20 August 2021

The boosting of consumer electronics and 5G technology cause the continuous increment of the power density of electronic devices and lead to inevitable overheating problems, which reduces the operation efficiency and shortens the service life of elec...

  • Article
  • Open Access
10 Citations
3,608 Views
15 Pages

Charge Modification as a Mechanism for Tunable Properties in Polymer–Surfactant Complexes

  • Christopher Hill,
  • Wasiu Abdullahi,
  • Robert Dalgliesh,
  • Martin Crossman and
  • Peter Charles Griffiths

20 August 2021

Oppositely charged polymer–surfactant complexes are frequently explored as a function of phase space defined by the charge ratio Z, (where Z = [+polymer]/[surfactant]), commonly accessed through the surfactant concentration. Tuning the phase behavio...

  • Article
  • Open Access
30 Citations
5,590 Views
13 Pages

Synthesis, Characterization and Mechanical Properties of Novel Bio-Based Polyurethane Foams Using Cellulose-Derived Polyol for Chain Extension and Cellulose Citrate as a Thickener Additive

  • Loredana Maiuolo,
  • Fabrizio Olivito,
  • Vincenzo Algieri,
  • Paola Costanzo,
  • Antonio Jiritano,
  • Matteo Antonio Tallarida,
  • Antonio Tursi,
  • Corradino Sposato,
  • Andrea Feo and
  • Antonio De Nino

20 August 2021

A novel series of bio-based polyurethane composite foams was prepared, employing a cellulose-derived polyol for chain extension and cellulose-citrate as a thickener additive. The utilized polyol was obtained from the reduction reaction of cellulose-d...

  • Article
  • Open Access
7 Citations
4,045 Views
10 Pages

20 August 2021

2-Methacryloyloxyethyl phosphorylcholine (MPC) polymers have been used as a coating agent on medical devices and as a carrier in drug delivery systems (DDSs). Paclitaxel (PTX) is a water-insoluble anticancer drug whose solubilizer is necessary for ad...

  • Article
  • Open Access
22 Citations
4,186 Views
20 Pages

Shear-Thinning in Oligomer Melts—Molecular Origins and Applications

  • Ranajay Datta,
  • Leonid Yelash,
  • Friederike Schmid,
  • Florian Kummer,
  • Martin Oberlack,
  • Mária Lukáčová-Medvid’ová and
  • Peter Virnau

20 August 2021

We investigate the molecular origin of shear-thinning in melts of flexible, semiflexible and rigid oligomers with coarse-grained simulations of a sheared melt. Entanglements, alignment, stretching and tumbling modes or suppression of the latter all c...

  • Article
  • Open Access
15 Citations
3,649 Views
18 Pages

Novel High Flux Poly(m-phenylene isophtalamide)/TiO2 Membranes for Ultrafiltration with Enhanced Antifouling Performance

  • Mariia Dmitrenko,
  • Anna Kuzminova,
  • Andrey Zolotarev,
  • Vladislav Liamin,
  • Tatiana Plisko,
  • Katsiaryna Burts,
  • Alexandr Bildyukevich,
  • Sergey Ermakov and
  • Anastasia Penkova

20 August 2021

Wide application of ultrafiltration in different industrial fields requires the development of new membranes with tailored properties and good antifouling stability. This study is devoted to the improvement of ultrafiltration properties of poly(m-phe...

  • Article
  • Open Access
6 Citations
2,931 Views
14 Pages

Destruction of Chitosan and Its Complexes with Cobalt(II) and Copper(II) Tetrasulphophthalocyanines

  • Natalia Sh. Lebedeva,
  • Elena S. Yurina,
  • Sabir S. Guseinov,
  • Yury A. Gubarev and
  • Anatoly I. V’yugin

19 August 2021

Chitosan is a naturally occurring polysaccharide derived from chitin with a wide range of uses. Phthalocyanines are macroheterocyclic compounds that have a number of useful properties such as coloring and catalytic and antioxidant activity. Phthalocy...

  • Article
  • Open Access
26 Citations
4,708 Views
15 Pages

19 August 2021

A superabsorbent polymer (SAP) was synthesized by copolymerizing itaconic acid and vinyl sulfonic acid. The typically low absorbency of itaconic acid-based SAPs under mechanical loads was improved by introducing surface crosslinking. Fourier-transfor...

  • Article
  • Open Access
10 Citations
3,757 Views
11 Pages

Valorization and Mechanical Recycling of Heterogeneous Post-Consumer Polymer Waste through a Mechano-Chemical Process

  • Roberta Capuano,
  • Irene Bonadies,
  • Rachele Castaldo,
  • Mariacristina Cocca,
  • Gennaro Gentile,
  • Antonio Protopapa,
  • Roberto Avolio and
  • Maria Emanuela Errico

19 August 2021

In this paper, a sustainable strategy to valorize and recycle heterogeneous polymer-based post-consumer waste is proposed. This strategy is based on a high-energy mechano-chemical treatment and has been applied to a polyolefin-rich fraction, coded as...

  • Article
  • Open Access
10 Citations
3,160 Views
14 Pages

19 August 2021

The emergence of antibiotic-resistant “superbugs” in recent decades has led to widespread illness and death and is a major ongoing public health issue. Since traditional antimicrobials and antibiotics are in many cases showing limited or no effective...

  • Article
  • Open Access
9 Citations
3,944 Views
17 Pages

Influence of Home Composting on Tensile Properties of Commercial Biodegradable Plastic Films

  • Maja Rujnić Havstad,
  • Ljerka Juroš,
  • Zvonimir Katančić and
  • Ana Pilipović

19 August 2021

In recent years biodegradable plastic films have been increasingly used for various purposes, most often as grocery bags and for collecting bio-waste. Typically, the biodegradation of these films should take place in industrial compost facilities whe...

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Polymers - ISSN 2073-4360