Polymers, Volume 12, Issue 4
2020 April - 265 articles
Cover Story: The cycloaddition of CO2 to ethylene oxide takes place in a gaseous phase. Before the formation of the liquid phase of the product, the reaction rate can be very slow. Therefore, a new catalyst based on a hyperbranched polyether backbone, containing CO2-philic, trisiloxane groups that attract carbon dioxide and enhance the catalytic activity of trimethylammonium active sites, was designed. An analogous structure containing hydroxyl groups was also synthesized for comparison reasons. Surprisingly, the hydrophilic catalyst had a higher efficiency in the cycloaddition reaction. However, the siloxane containing catalyst was easily separable from the product and did not promote the formation of the ethylene glycol by-product. View this paper. - Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
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