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Polymers, Volume 12, Issue 4

2020 April - 265 articles

Cover Story: The cycloaddition of CO2 to ethylene oxide takes place in a gaseous phase. Before the formation of the liquid phase of the product, the reaction rate can be very slow. Therefore, a new catalyst based on a hyperbranched polyether backbone, containing CO2-philic, trisiloxane groups that attract carbon dioxide and enhance the catalytic activity of trimethylammonium active sites, was designed. An analogous structure containing hydroxyl groups was also synthesized for comparison reasons. Surprisingly, the hydrophilic catalyst had a higher efficiency in the cycloaddition reaction. However, the siloxane containing catalyst was easily separable from the product and did not promote the formation of the ethylene glycol by-product. View this paper.
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Articles (265)

  • Article
  • Open Access
4 Citations
4,241 Views
14 Pages

Selective Vapor Permeation Behavior of Crosslinked PAMPS Membranes

  • Ye Ji Son,
  • So Jeong Kim,
  • Young-Jin Kim and
  • Kyung-Hye Jung

24 April 2020

The effect of crosslinking on vapor permeation behavior of polyelectrolyte membranes was studied. Poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS) membranes were crosslinked by using crosslinkers with different lengths between the reactive...

  • Article
  • Open Access
30 Citations
4,887 Views
13 Pages

Surface Modification of Staple Carbon Fiber by Dopamine to Reinforce Natural Latex Composite

  • Xiaolong Tian,
  • Shuang Han,
  • Qianxiao Zhuang,
  • Huiguang Bian,
  • Shaoming Li,
  • Changquan Zhang,
  • Chuansheng Wang and
  • Wenwen Han

24 April 2020

Carbon fiber significantly enhances the mechanical, thermal and electrical properties of rubber composites, which are widely used in aerospace, military, national defense and other cutting-edge fields. The preparation of a high-performance carbon fib...

  • Article
  • Open Access
2 Citations
4,341 Views
12 Pages

Diblock, Triblock and Cyclic Amphiphilic Copolymers with CO2 Switchability: Effects of Topology

  • Yuting Jiang,
  • Tong Zhang,
  • Zheng Yi,
  • Yixiu Han,
  • Xin Su and
  • Yujun Feng

24 April 2020

The combination of topology and CO2 switchability could provide new options for amphiphilic copolymers. Cyclic molecules supply novel topologies, and CO2 switching provides stimulus responsiveness. Cyclic poly(2–(diethylamino)ethyl methacrylate...

  • Article
  • Open Access
13 Citations
4,302 Views
17 Pages

Aberration-Based Quality Metrics in Holographic Lenses

  • Tomás Lloret,
  • Víctor Navarro-Fuster,
  • Manuel G. Ramírez,
  • Marta Morales-Vidal,
  • Augusto Beléndez and
  • Inmaculada Pascual

24 April 2020

Aberrations and the image quality of holographic lenses were evaluated by a Hartmann–Shack (HS) wavefront sensor. Two lenses, one recorded with a symmetrical configuration and the other with an asymmetrical one, were stored in a photopolymer ca...

  • Article
  • Open Access
37 Citations
5,733 Views
20 Pages

24 April 2020

Inspired by the growing demand for smart and environmentally friendly polymer materials, we employed 2,2′-disulfanediyldianiline (22DTDA) as a chain extender to synthesize a waterborne polyurethane (WPUR). Due to the ortho-substituted structure...

  • Article
  • Open Access
33 Citations
4,655 Views
9 Pages

Enhanced Operating Temperature Stability of Organic Solar Cells with Metal Oxide Hole Extraction Layer

  • Donggu Lee,
  • Junmo Kim,
  • Gyeongtae Park,
  • Hyeong Woo Bae,
  • Myungchan An and
  • Jun Young Kim

24 April 2020

Organic solar cells (OSCs) are promising renewable energy sources for replacing fossil fuels. The power conversion efficiency (PCE) of OSCs has increased based on tremendous effort in material and device engineering. Still, the stability of OSC, such...

  • Article
  • Open Access
18 Citations
4,826 Views
14 Pages

A Smart Strategy to Improve t-Resveratrol Production in Grapevine Cells Treated with Cyclodextrin Polymers Coated with Magnetic Nanoparticles

  • Lorena Almagro,
  • Alicia De Gea-Abellán,
  • María Isabel Rodríguez-López,
  • Estrella Núñez-Delicado,
  • José Antonio Gabaldón and
  • María Angeles Pedreño

24 April 2020

One of the most successfully procedures used to increase the production of t-resveratrol in Vitis vinifera suspension-cultured cells is the application of cyclodextrins (CDs) and methyl jasmonate (MJ) as elicitors. In particular, β-CDs are chara...

  • Article
  • Open Access
5 Citations
4,191 Views
11 Pages

A Silk Fibroin Based Hydration Accelerator for Root Canal Filling Materials

  • Ching-Shuan Huang,
  • Sung-Chih Hsieh,
  • Nai-Chia Teng,
  • Wei-Fang Lee,
  • Poonam Negi,
  • Wendimi Fatimata Belem,
  • Hsuan-Chen Wu and
  • Jen-Chang Yang

24 April 2020

Mineral trioxide aggregate (MTA) is widely used in various dental endodontic applications such as root-end filling, furcal perforation repair, and vital pulp therapy. In spite of many attempts to improve handling properties and reduce the discolorati...

  • Article
  • Open Access
10 Citations
3,869 Views
12 Pages

24 April 2020

Oriental lacquer is a natural polymeric coating with a satiny texture and excellent characteristics, such as chemical resistance and durability. However, the poor lightfastness resulted in the natural aromatic structures of the urushiol structures li...

  • Article
  • Open Access
10 Citations
4,652 Views
18 Pages

Copolymacrolactones Grafted with l-Glutamic Acid: Synthesis, Structure, and Nanocarrier Properties

  • Ernesto Tinajero-Díaz,
  • Antxon Martínez de Ilarduya and
  • Sebastián Muñoz-Guerra

24 April 2020

The enzymatic ring-opening copolymerization (eROP) of globalide (Gl) and pentadecalactone (PDL) was performed in solution from mixtures of the two macrolactones at ratios covering the whole range of comonomeric compositions. The resulting P(Glx-r-PDL...

  • Article
  • Open Access
11 Citations
3,803 Views
9 Pages

23 April 2020

To prepare a porous cellulose acetate (CA) for application as a battery separator, Cd(NO3)2·4H2O was utilized with water-pressure as an external physical force. When the CA was complexed with Cd(NO3)2·4H2O and exposed to external water-...

  • Article
  • Open Access
23 Citations
4,831 Views
17 Pages

Tuning Functional Behavior of Humic Acids through Interactions with Stöber Silica Nanoparticles

  • Giulio Pota,
  • Virginia Venezia,
  • Giuseppe Vitiello,
  • Paola Di Donato,
  • Valentina Mollo,
  • Aniello Costantini,
  • Joshua Avossa,
  • Assunta Nuzzo,
  • Alessandro Piccolo and
  • Giuseppina Luciani
  • + 1 author

23 April 2020

Humic acids (HA) exhibit fascinating multifunctional features, yet degradation phenomena as well as poor stability in aqueous environments strongly limit their use. Inorganic nanoparticles are emerging as a powerful interface for the development of r...

  • Article
  • Open Access
14 Citations
4,802 Views
13 Pages

23 April 2020

Dynamic crosslinking networks based on Diels–Alder (DA) chemistry and ionic interactions were introduced to maleic anhydride modified ethylene-vinyl acetate copolymer (mEVA) via in situ melt processing. The dual dynamic crosslinking networks we...

  • Article
  • Open Access
6 Citations
4,076 Views
14 Pages

Effect of Gear Pump Extrusion Processing on the Properties of Fiber Reinforced Rubber Composites

  • Xiaolong Tian,
  • Lin Zhu,
  • Kunling Li,
  • Kongshuo Wang,
  • Huiguang Bian,
  • Lin Li,
  • Shaoming Li and
  • Chuansheng Wang

23 April 2020

Short fiber reinforced rubber composites have been widely used in rubber products attributed to their excellent wear resistance. However, there are still some serious problems in the processing of short fiber reinforced rubber composites, such as Moo...

  • Article
  • Open Access
35 Citations
4,873 Views
14 Pages

3D Printed Laminated CaCO3-Nanocellulose Films as Controlled-Release 5-Fluorouracil

  • Denesh Mohan,
  • Nur Fatin Khairullah,
  • Yan Ping How,
  • Mohd Shaiful Sajab and
  • Hatika Kaco

23 April 2020

Drug delivery constitutes the formulations, technologies, and systems for the transport of pharmaceutical compounds to specific areas in the body to exert safe therapeutic effects. The main criteria for selecting the correct medium for drug delivery...

  • Article
  • Open Access
35 Citations
6,552 Views
19 Pages

Research on the Strengthening Advantages on Using Cellulose Nanofibers as Polyvinyl Alcohol Reinforcement

  • Quim Tarrés,
  • Helena Oliver-Ortega,
  • Manel Alcalà,
  • F. Xavier Espinach,
  • Pere Mutjé and
  • Marc Delgado-Aguilar

22 April 2020

The present work aims to combine the unique properties of cellulose nanofibers (CNF) with polyvinyl alcohol (PVA) to obtain high-performance nanocomposites. CNF were obtained by means of TEMPO-mediated ((2,2,6,6-Tetramethylpiperidin-1-yl)oxyl) oxidat...

  • Article
  • Open Access
19 Citations
6,392 Views
19 Pages

UV-Casting on Methacrylated PCL for the Production of a Peripheral Nerve Implant Containing an Array of Porous Aligned Microchannels

  • Ruth Diez-Ahedo,
  • Xabier Mendibil,
  • Mari Carmen Márquez-Posadas,
  • Iban Quintana,
  • Francisco González,
  • Francisco Javier Rodríguez,
  • Leyla Zilic,
  • Colin Sherborne,
  • Adam Glen and
  • Santos Merino
  • + 6 authors

22 April 2020

Peripheral nerves are basic communication structures guiding motor and sensory information from the central nervous system to receptor units. Severed peripheral nerve injuries represent a large clinical problem with relevant challenges to successful...

  • Article
  • Open Access
25 Citations
4,982 Views
13 Pages

22 April 2020

A series of well-defined antimicrobial polymers composed of comonomers bearing thiazole ring (2-(((2-(4-methylthiazol-5-yl)ethoxy)carbonyl)oxy)ethyl methacrylate monomer (MTZ)) and non-hemotoxic poly(ethylene glycol) side chains (poly(ethylene glycol...

  • Article
  • Open Access
62 Citations
7,819 Views
15 Pages

Mechanical and Strain-Sensing Capabilities of Carbon Nanotube Reinforced Composites by Digital Light Processing 3D Printing Technology

  • Alejandro Cortés,
  • Xoan F. Sánchez-Romate,
  • Alberto Jiménez-Suárez,
  • Mónica Campo,
  • Alejandro Ureña and
  • Silvia G. Prolongo

22 April 2020

Mechanical and strain sensing capabilities of carbon nanotube (CNT) reinforced composites manufactured by digital light processing (DLP) 3D printing technology have been studied. Both CNT content and a post-curing treatment effects have been analyzed...

  • Article
  • Open Access
15 Citations
6,843 Views
13 Pages

Development and Validation of a Test Mold for Thermoplastic Resin Transfer Molding of Reactive PA-6

  • Róbert Boros,
  • Ilya Sibikin,
  • Tatyana Ageyeva and
  • József Gábor Kovács

22 April 2020

Thermoplastic resin transfer molding (T-RTM) is a cutting-edge manufacturing technique for high-volume production of composites with a recyclable thermoplastic matrix. Although a number of reactive thermoplastic matrices as well as industrial manufac...

  • Article
  • Open Access
19 Citations
6,222 Views
16 Pages

22 April 2020

Hydrogel materials with a gel-sol conversion due to external environmental changes have potential applications in a wide range of fields, including controlled drug delivery. Succinoglycans are anionic extracellular polysaccharides produced by various...

  • Article
  • Open Access
64 Citations
4,976 Views
14 Pages

Effects of Different Conditions on Co-Pyrolysis Behavior of Corn Stover and Polypropylene

  • Fengze Wu,
  • Haoxi Ben,
  • Yunyi Yang,
  • Hang Jia,
  • Rui Wang and
  • Guangting Han

22 April 2020

The pyrolysis behavior of corn stover and polypropylene during co-pyrolysis was studied using a tube furnace reactor. The effects of mixing ratio of corn stover and polypropylene, pyrolysis temperature, addition amount of catalyst (HZSM-5) and reacti...

  • Article
  • Open Access
23 Citations
3,777 Views
13 Pages

22 April 2020

In the present paper, we investigate the effectiveness of nanocomposites (composed of ultra-high molecular weight polyethylene (UHMWPE) mixed with carbon nano-filler (CNF) and medical grade paraffin oil (PO), from the biological point of view. Wear m...

  • Article
  • Open Access
14 Citations
7,786 Views
18 Pages

22 April 2020

In this work, we have used low-molecular-weight (PEG12-b-PCL6, PEG12-b-PCL9 or PEG16-b-PLA38; MW, 1.25–3.45 kDa) biodegradable block co-polymers to construct nano- and micron-scaled hybrid (polymer/lipid) vesicles, by solvent dispersion and ele...

  • Article
  • Open Access
25 Citations
5,939 Views
15 Pages

22 April 2020

In the field of polymer chemistry, tremendous efforts have been made over the last decade to replace petrochemical monomers with building blocks from renewable resources. In this respect, itaconic acid has been used as an alternative to acrylic acid...

  • Article
  • Open Access
8 Citations
4,240 Views
21 Pages

21 April 2020

Free-formed frameworks are architecturally appealing constructions. They allow for maximum creative freedom as well as for a structural optimization of the support structure. The design and construction of these kind of structures is complex however,...

  • Review
  • Open Access
34 Citations
8,683 Views
14 Pages

Gradient Hydrogels—The State of the Art in Preparation Methods

  • Natalia Zinkovska,
  • Jiri Smilek and
  • Miloslav Pekar

21 April 2020

Gradient hydrogels refer to hydrogel materials with a gradual or abrupt change in one or some of their properties. They represent examples of more sophisticated gel materials in comparison to simple, native gel networks. Here, we review techniques us...

  • Article
  • Open Access
18 Citations
3,679 Views
21 Pages

Effect of Subtropical Natural Exposure on the Bond Behavior of FRP-Concrete Interface

  • Xinyan Guo,
  • Shenyunhao Shu,
  • Yilin Wang,
  • Peiyan Huang,
  • Jiaxiang Lin and
  • Yongchang Guo

21 April 2020

Subtropical natural exposure may significantly affect the bonding behavior of fiber reinforced polymer (FRP) externally bonded to concrete. To study the effect of subtropical natural climates on the FRP-concrete interface, natural exposure tests and...

  • Article
  • Open Access
32 Citations
6,185 Views
13 Pages

Fear of the Relapse: Effect of Composite Type on Adhesion Efficacy of Upper and Lower Orthodontic Fixed Retainers: In Vitro Investigation and Randomized Clinical Trial

  • Andrea Scribante,
  • Simone Gallo,
  • Benedetta Turcato,
  • Federico Trovati,
  • Paola Gandini and
  • Maria Francesca Sfondrini

21 April 2020

The aim of this laboratory and clinical study is to determine the reliability of the flowable nanocomposite Filtek Supreme XTE (FL) for the adhesion of orthodontic retainers, compared to highly filled orthodontic resin Transbond XT (XT). Portions of...

  • Article
  • Open Access
1 Citations
3,014 Views
8 Pages

21 April 2020

A cost-effective, simple, and time-saving method to fabricate mono-dispersed periodic microsphere structures on substrates with patterned sites is very meaningful due to their significance on various biological studies. Herein, a simple and facile me...

  • Article
  • Open Access
23 Citations
5,276 Views
11 Pages

A Heterocyclic Polyurethane with Enhanced Self-Healing Efficiency and Outstanding Recovery of Mechanical Properties

  • Jinsil Kim,
  • Pyong Hwa Hong,
  • Kiwon Choi,
  • Gyeongmin Moon,
  • Jungsoon Kang,
  • Seoyun Lee,
  • Sungkoo Lee,
  • Hyun Wook Jung,
  • Min Jae Ko and
  • Sung Woo Hong

21 April 2020

A functional polyurethane based on the heterocyclic group was synthesized and its self-healing and mechanical properties were examined. To synthesize a heterocyclic polyurethane, a polyol and a heterocyclic compound with di-hydroxyl groups at both en...

  • Article
  • Open Access
39 Citations
5,437 Views
18 Pages

Protection of Poly(Vinyl Chloride) Films against Photodegradation Using Various Valsartan Tin Complexes

  • Alaa Mohammed,
  • Gamal A. El-Hiti,
  • Emad Yousif,
  • Ahmed A. Ahmed,
  • Dina S. Ahmed and
  • Mohammad Hayal Alotaibi

21 April 2020

Poly(vinyl chloride) is a common plastic that is widely used in many industrial applications. Poly(vinyl chloride) is mixed with additives to improve its mechanical and physical properties and to enable its use in harsh environments. Herein, to prote...

  • Article
  • Open Access
26 Citations
5,440 Views
15 Pages

The Effect of Environmental Conditions on the Degradation Behavior of Biomass Pellets

  • Hamid Gilvari,
  • Luis Cutz,
  • Urša Tiringer,
  • Arjan Mol,
  • Wiebren de Jong and
  • Dingena L. Schott

21 April 2020

Biomass pellets provide a pivotal opportunity in promising energy transition scenarios as a renewable source of energy. A large share of the current utilization of pellets is facilitated by intensive global trade operations. Considering the long dist...

  • Article
  • Open Access
8 Citations
3,108 Views
13 Pages

Reversible Nonlinear I-V Behavior of ZnO-Decorated Graphene Nanoplatelets/Epoxy Resin Composites

  • Yang Yuan,
  • Zhaoming Qu,
  • Qingguo Wang,
  • Xiaoning Sun and
  • Erwei Cheng

20 April 2020

With the more serious threats from complex electromagnetic environments, composites composed of conductive or semiconductive fillers and polymeric matrices could exhibit excellent nonlinear I-V characteristics, and have drawn significant attention in...

  • Article
  • Open Access
56 Citations
7,552 Views
16 Pages

20 April 2020

The operating temperature and the ampacity are important parameters to reflect the operating state of cross-linked polyethylene (XLPE) submarine high voltage (HV) cables, and it is of great significance to study the electrothermal coupling law of sub...

  • Article
  • Open Access
25 Citations
4,950 Views
15 Pages

Morphology Dependence Degradation of Electro- and Magnetoactive Poly(3-hydroxybutyrate-co-hydroxyvalerate) for Tissue Engineering Applications

  • Luis Amaro,
  • Daniela M. Correia,
  • Pedro M. Martins,
  • Gabriela Botelho,
  • Sónia A. C. Carabineiro,
  • Clarisse Ribeiro and
  • Senentxu Lanceros-Mendez

20 April 2020

Poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV) is a piezoelectric biodegradable and biocompatible polymer suitable for tissue engineering applications. The incorporation of magnetostrictive cobalt ferrites (CFO) into PHBV matrix enables the producti...

  • Article
  • Open Access
45 Citations
4,690 Views
18 Pages

Drag Reduction Performance and Mechanism of Hydrophobic Polymers in Fresh Water and Brine

  • Hongzhong Tan,
  • Jincheng Mao,
  • Wenlong Zhang,
  • Bo Yang,
  • Xiaojiang Yang,
  • Yang Zhang,
  • Chong Lin,
  • Jianfa Feng and
  • Hao Zhang

20 April 2020

Three kinds of drag reducer were synthesized by inverse emulsion polymerization and named PHWAM-1, PHWAM-2, and PHWAM-3. Drag reduction (DR) tests showed that the three drag reducers have different DR characteristics in fresh water and various saline...

  • Article
  • Open Access
17 Citations
4,199 Views
10 Pages

20 April 2020

Soybean meal-based adhesive is a good wood adhesive mainly due to its renewable, degradable, and environmentally friendly features. To improve the enhancement efficiency for adhesives, diglycidyl resorcinol ether (DRE) containing a benzene ring and f...

  • Article
  • Open Access
10 Citations
3,219 Views
10 Pages

20 April 2020

Stimuli-responsive polymers have attracted significant interest in the fields of advanced materials and biomaterials. Herein, temperature- and pH-responsive glycopolymers, which are composed of N-isopropylacrylamide, methacrylic acid, and an acrylami...

  • Article
  • Open Access
68 Citations
7,141 Views
13 Pages

20 April 2020

More than 10 million tons of textile waste are disposed through landfill every year in North America. The disposal of textile waste via landfill or incineration causes environmental problems and represents a waste of useful resources. In this work, w...

  • Article
  • Open Access
7 Citations
4,189 Views
16 Pages

20 April 2020

In processes using the ultrashort pulsed laser, the phenomenon that the ablation efficiency is reduced due to the increase of the shielding effect of the generated plume is increasingly caused by the use of the high power and high repetition rate. A...

  • Article
  • Open Access
14 Citations
3,889 Views
15 Pages

Study on Adsorption and Aggregation in the Mixed System of Polyacrylamide, Cu(II) Ions and Innovative Carbon–Silica Composite

  • Katarzyna Szewczuk-Karpisz,
  • Viktor M. Bogatyrov,
  • Mariia Galaburda and
  • Zofia Sokołowska

20 April 2020

The paper presents an original study on adsorption and aggregation phenomena in a mixed system consisting of a macromolecular compound, heavy metal ions and an innovative adsorbent. The authors used ionic polyacrylamides (PAM), Cu(II) ions and carbon...

  • Article
  • Open Access
25 Citations
4,970 Views
16 Pages

20 April 2020

In the present study, we investigated the removal of an emerging pesticide lindane from aqueous solution using synthesized aluminum hydroxide Al(OH)3 (bayerite) nanomaterials with surface modification by an anionic surfactant sodium dodecyl sulfate (...

  • Article
  • Open Access
11 Citations
3,691 Views
20 Pages

20 April 2020

A facile method combining micro-molding with thermally-induced phase separation (TIPS) to prepare superhydrophobic isotacticpolypropylene (iPP) microporous membranes with micron-submicron hierarchical structures is proposed in this paper. In this stu...

  • Article
  • Open Access
35 Citations
5,913 Views
19 Pages

19 April 2020

Adhesive bonding is widely used in the joining of metals and carbon fiber-reinforced plastics (CFRPs). Ultrasonic vibration was used to improve adhesive bonding of CFRP/Al alloy joints grafted with silane coupling agent, and the effect of the ultraso...

  • Article
  • Open Access
29 Citations
5,911 Views
26 Pages

19 April 2020

Pre-hydrolysed/condensed tetraethyl orthosilicate (TEOS) was added to a solution of methyl methacrylate (MMA) and 3-methacryloxypropyltrimethoxysilane (MAPTMS), and then copolymerised for various times to study the influence of the latter on the stru...

  • Article
  • Open Access
11 Citations
4,958 Views
11 Pages

Preparation and Characteristics of Wet-Spun Filament Made of Cellulose Nanofibrils with Different Chemical Compositions

  • Chan-Woo Park,
  • Ji-Soo Park,
  • Song-Yi Han,
  • Eun-Ah Lee,
  • Gu-Joong Kwon,
  • Young-Ho Seo,
  • Jae-Gyoung Gwon,
  • Sun-Young Lee and
  • Seung-Hwan Lee

19 April 2020

In this study, wet-spun filaments were prepared using lignocellulose nanofibril (LCNF), with 6.0% and 13.0% of hemicellulose and lignin, respectively, holocellulose nanofibril (HCNF), with 37% hemicellulose, and nearly purified-cellulose nanofibril (...

  • Article
  • Open Access
42 Citations
5,805 Views
11 Pages

Silane Effect of Universal Adhesive on the Composite–Composite Repair Bond Strength after Different Surface Pretreatments

  • Gioia Michelotti,
  • Maria Niedzwiecki,
  • Darius Bidjan,
  • Phoebe Dieckmann,
  • Shengjile Deari,
  • Thomas Attin and
  • Tobias T. Tauböck

19 April 2020

This study investigated the impact of a separate silanization step on the repair bond strength of composite substrates using a universal adhesive after various mechanical surface treatments. Composite specimens were aged and exposed to the following...

  • Review
  • Open Access
131 Citations
18,809 Views
22 Pages

18 April 2020

Tissue adhesives have attracted more attention to the applications of non-invasive wound closure. The purpose of this review article is to summarize the recent progress of developing tissue adhesives, which may inspire researchers to develop more out...

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Polymers - ISSN 2073-4360