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Polymers, Volume 11, Issue 3

2019 March - 185 articles

Cover Story: A new type of atropisomerism has recently been discovered in 1,3-benzoxazines, where the intramolecular repulsion between negatively charged oxygen atoms on the imide and the oxazine ring hinders the rotation about the C–N bond. This cover image schematically illustrates how the atropisomerization in ortho-imide functional benzoxazines can be switched on or off by the manipulation of the steric structure of the end caps. Additionally, the polymerization behavior of benzoxazine monomers and the properties of the corresponding polybenzoxazines can also be controlled well by the imide end caps. The high thermal stability of this series of ortho-imide functional polybenzoxazines indicates their great potential in applications such as fire-resistant materials, electronic encapsulation materials, and polymeric matrices for high-performance composites. View Paper here.
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Articles (185)

  • Article
  • Open Access
5 Citations
3,944 Views
7 Pages

26 March 2019

In this work, we characterized poly(quinacridone-diphenylquinoxaline) (PQCTQx). PQCTQx was synthesized by a Suzuki coupling reaction and the synthesized PQCTQx was used as a polymeric semiconducting material in organic field-effect transistors (OFETs...

  • Article
  • Open Access
18 Citations
5,802 Views
12 Pages

26 March 2019

The aim of this study was to explore the catalytic performance of the oxidative depolymerization of enzymatic hydrolysis lignin from cellulosic ethanol fermentation residue by different vanadium substituted Keggin-type polyoxometalates (K5[SiVW11O40]...

  • Article
  • Open Access
40 Citations
13,198 Views
20 Pages

26 March 2019

Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) is a promising bio-based and biodegradable thermoplastic with restricted industrial applications due to its brittleness and poor processability. Natural rubber (NR) has been used as a toughening age...

  • Article
  • Open Access
74 Citations
6,388 Views
10 Pages

26 March 2019

The application of techniques to improve the surface finish of pieces obtained by fused deposition modelling, as well as other functional aspects, is of great interest nowadays. Polylactic acid, a biodegradable material, has been considered a possibl...

  • Article
  • Open Access
12 Citations
5,414 Views
9 Pages

Comparison of Membrane Inlet and Capillary Introduction Miniature Mass Spectrometry for Liquid Analysis

  • Wenyan Shi,
  • Xinqiong Lu,
  • Jinbo Zhang,
  • Jianhong Zhao,
  • Lili Yang,
  • Quan Yu and
  • Xiaohao Wang

26 March 2019

Membrane inlet mass spectrometry (MIMS) is commonly used for detecting the components in liquid samples. When a liquid sample flows through a membrane, certain analytes will permeate into the vacuum chamber of a mass spectrometer from the solution. T...

  • Article
  • Open Access
78 Citations
7,157 Views
14 Pages

Core-Shell Structured HMX@Polydopamine Energetic Microspheres: Synergistically Enhanced Mechanical, Thermal, and Safety Performances

  • Congmei Lin,
  • Feiyan Gong,
  • Zhijian Yang,
  • Xu Zhao,
  • Yubin Li,
  • Chengcheng Zeng,
  • Jiang Li and
  • Shaoyun Guo

26 March 2019

The solid–solid phase transition, poor mechanical properties, and high sensitivity has impeded further practical applications of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane (HMX) based polymer bonded explosives (PBXs). To address these issues togeth...

  • Communication
  • Open Access
35 Citations
7,023 Views
10 Pages

Formulation and Characterization of a SIS-Based Photocrosslinkable Bioink

  • Julian A. Serna,
  • Sergio Leonardo Florez,
  • Vivian A. Talero,
  • Juan C. Briceño,
  • Carolina Muñoz-Camargo and
  • Juan C. Cruz

26 March 2019

Decellularized extracellular matrices (dECMs) represent a promising alternative as a source of materials to develop scaffolds that closely mimic the native environment of cells. As a result, dECMs have attracted significant attention for their applic...

  • Article
  • Open Access
12 Citations
4,986 Views
19 Pages

26 March 2019

Commercially available sorbent materials for solid-phase extraction are widely used in analytical laboratories. However, non-selective binding is a major obstacle for sample analysis. To overcome this problem, molecularly imprinted polymers (MIPs) we...

  • Article
  • Open Access
7 Citations
4,549 Views
18 Pages

26 March 2019

The thermal-responsive polymers, poly(alkane-1,#-diylbis(tri-n-butylphosphonium) 4-vinylbenzenesulfonate) (PSSBP#, # = 8, 6, and 4), where # is the number of carbon atoms in the central bridge structure of the dicationic phosphonium moiety, were synt...

  • Article
  • Open Access
1 Citations
3,542 Views
17 Pages

25 March 2019

In this work, a unique hybrid system is proposed for one-dimensional gratings comprising of poly(glycidyl methacrylate) (PGMA) brushes and CdS quantum dots (CQDs). Generally, the emission of QDs is too weak to be observed in a dry state. Plasmonic re...

  • Article
  • Open Access
22 Citations
4,694 Views
12 Pages

Influence of Various Climatic Conditions on the Structural Changes of Semicrystalline PLA Spun-Bonded Mulching Nonwovens during Outdoor Composting

  • Michał Puchalski,
  • Piotr Siwek,
  • Nicolay Panayotov,
  • Małgorzata Berova,
  • Stanisława Kowalska and
  • Izabella Krucińska

25 March 2019

This study analyzed the structural changes of semicrystalline polylactide (PLA) in the form of spun-bonded mulching nonwovens, during outdoor composting. The investigation was carried out at the microstructural, supramolecular and molecular levels us...

  • Review
  • Open Access
269 Citations
21,638 Views
18 Pages

Polymeric Antimicrobial Food Packaging and Its Applications

  • Tianqi Huang,
  • Yusheng Qian,
  • Jia Wei and
  • Chuncai Zhou

25 March 2019

Food corruption and spoilage caused by food-borne pathogens and microorganisms is a serious problem. As a result, the demand for antibacterial drugs in food packaging is growing. In this review, biodegradable and non-biodegradable materials for food...

  • Article
  • Open Access
18 Citations
5,853 Views
12 Pages

Polymer Pen Lithography-Fabricated DNA Arrays for Highly Sensitive and Selective Detection of Unamplified Ganoderma Boninense DNA

  • Ekta Rani,
  • Siti Akhtar Mohshim,
  • Muhammad Zamharir Ahmad,
  • Royston Goodacre,
  • Shahrul Ainliah Alang Ahmad and
  • Lu Shin Wong

25 March 2019

There is an increasing demand for lithography methods to enable the fabrication of diagnostic devices for the biomedical and agri-food sectors. In this regard, scanning probe lithography methods have emerged as a possible approach for this purpose, a...

  • Article
  • Open Access
28 Citations
5,327 Views
21 Pages

Multifunctional Nanocomposite Cellulose Fibers Doped in Situ with Silver Nanoparticles

  • Olga Rac-Rumijowska,
  • Irena Maliszewska,
  • Marta Fiedot-Toboła,
  • Iwona Karbownik and
  • Helena Teterycz

25 March 2019

This paper presents a method for the preparation of nanocomposite cellulose fibers doped with silver nanoparticles (AgNPs), as well as the effect of silver nanoparticles on the structure and properties of fibers. The fibers were obtained by an enviro...

  • Article
  • Open Access
21 Citations
7,557 Views
14 Pages

24 March 2019

Thermal bonding technology is the most commonly used approach in bonding injection-molded microfluidic chips. Although the bonding mechanism is still under debate, the molecular dynamics (MD) method can provide insight into the bonding process on a m...

  • Article
  • Open Access
19 Citations
4,626 Views
18 Pages

High-Performance TiO2 Nanotubes/Poly(aryl ether sulfone) Hybrid Self-Cleaning Anti-Fouling Ultrafiltration Membranes

  • Zhi Geng,
  • Xinyu Wang,
  • Hongchuan Jiang,
  • Leilei Zhang,
  • Zhiting Chen,
  • Yong Feng,
  • Wenzhe Geng,
  • Xia Yang,
  • Mingxin Huo and
  • Jing Sun

23 March 2019

A series of novel self-cleaning hybrid photocatalytic ultrafiltration (UF) membranes were fabricated to separate polyacrylamide, which is widely used as a commercial flocculant. To maximize the self-cleaning and anti-fouling properties of hybrid memb...

  • Article
  • Open Access
49 Citations
8,117 Views
15 Pages

Exploring Next-Generation Engineering Bioplastics: Poly(alkylene furanoate)/Poly(alkylene terephthalate) (PAF/PAT) Blends

  • Niki Poulopoulou,
  • Nejib Kasmi,
  • Maria Siampani,
  • Zoi N. Terzopoulou,
  • Dimitrios N. Bikiaris,
  • Dimitris S. Achilias,
  • Dimitrios G. Papageorgiou and
  • George Z. Papageorgiou

23 March 2019

Polymers from renewable resources and especially strong engineering partially aromatic biobased polyesters are of special importance for the evolution of bioeconomy. The fabrication of polymer blends is a creative method for the production of tailor-...

  • Article
  • Open Access
24 Citations
5,932 Views
17 Pages

Scaling and Interactions of Linear and Ring Polymer Brushes via DPD Simulations

  • Martin Jehser,
  • Gerhard Zifferer and
  • Christos N. Likos

22 March 2019

Single and double layers of polymer coated surfaces are investigated by means of Dissipative Particle Dynamics (DPD), focusing on the difference between grafted ring and linear chains. Several different surface coverages σ , as well as chain len...

  • Article
  • Open Access
53 Citations
4,853 Views
12 Pages

22 March 2019

This paper presents an experimental study about the influence of interfacial properties on the performance of fiber-reinforced asphalt. In this study, four types of fiber including one fiber-reinforced plastic (FRP), two lignin fibers, and one basalt...

  • Article
  • Open Access
17 Citations
8,329 Views
19 Pages

d-, l- and d,l-Tryptophan-Based Polyamidoamino Acids: pH-Dependent Structuring and Fluorescent Properties

  • Federica Lazzari,
  • Amedea Manfredi,
  • Jenny Alongi,
  • Daniele Marinotto,
  • Paolo Ferruti and
  • Elisabetta Ranucci

22 March 2019

Chiral polyamidoamino acids were obtained by polyaddition of N,N’-methylenebisacrylamide with d-, d,l- and l-tryptophan (M-d-Trp, M-d,l-Trp and M-l-Trp). l-tryptophan/glycine copolymers, M-G-l-Trp5, M-G-l-Trp10, M-G-l-Trp20 and M-G-l-Trp40, wer...

  • Article
  • Open Access
9 Citations
4,982 Views
11 Pages

Optimizing Polymer Solar Cells Using Non-Halogenated Solvent Blends

  • Guler Kocak,
  • Desta Gedefaw and
  • Mats R. Andersson

22 March 2019

More environmentally friendly polymer solar cells were constructed using a conjugated polymer, poly (2,5-thiophene-alt-4,9-bis(2-hexyldecyl)-4,9-dihydrodithieno[3,2-c:3′,2′h][1,5] naphthyridine-5,10-dione, PTNT, as a donor material in com...

  • Article
  • Open Access
15 Citations
4,697 Views
17 Pages

22 March 2019

To improve the flame retardancy and inhibit the smoke of poly(ethylene terephthalate) (PET), carbon microspheres (CMSs)-based melamine phosphate (MP) hybrids (MP-CMSs) were constructed in situ with the introduction of CMSs into the hydrothermal react...

  • Article
  • Open Access
33 Citations
5,490 Views
13 Pages

Facile Preparation of Highly Conductive Poly(amide-imide) Composite Films beyond 1000 S m−1 through Ternary Blend Strategy

  • Yanbin Wang,
  • Huang Yu,
  • Yongchao Li,
  • Teng Wang,
  • Tao Xu,
  • Jinxing Chen,
  • Zicheng Fan,
  • Yufeng Wang and
  • Biaobing Wang

22 March 2019

Highly conductive thin films with suitable mechanical performances play a significant role in modern electronic industry. Herein, a series of ternary conductive polymer composites were fabricated by incorporating carbon black (CB) into binary conduct...

  • Article
  • Open Access
19 Citations
5,425 Views
15 Pages

(Bio)degradable Polymeric Materials for Sustainable Future—Part 2: Degradation Studies of P(3HB-co-4HB)/Cork Composites in Different Environments

  • Sebastian Jurczyk,
  • Marta Musioł,
  • Michał Sobota,
  • Magdalena Klim,
  • Anna Hercog,
  • Piotr Kurcok,
  • Henryk Janeczek and
  • Joanna Rydz

22 March 2019

The degree of degradation of pure poly(3-hydroxybutyrate-co-4-hydroxybutyrate) [P(3HB-co-4HB)] and its composites with cork incubated under industrial and laboratory composting conditions was investigated. The materials were parallelly incubated in d...

  • Article
  • Open Access
34 Citations
4,727 Views
10 Pages

22 March 2019

Tannin/cellulose microspheres (T/C) were successfully prepared via a facile homogeneous reaction in a water/oil (W/O) emulsion for removing Pb(II) ions from aqueous solution. The structure of the microspheres was characterized by scanning electron mi...

  • Article
  • Open Access
108 Citations
9,557 Views
19 Pages

22 March 2019

The aim of the study was to improve the electrical and thermal conductivity of the polylactic acid/wood flour/thermoplastic polyurethane composites by Fused Deposition Modeling (FDM). The results showed that, when the addition amount of nano-graphite...

  • Article
  • Open Access
21 Citations
6,263 Views
13 Pages

Electrospinning of Ethylene Vinyl Acetate/Carbon Nanotube Nanocomposite Fibers

  • Mária Omastová,
  • Eliška Číková and
  • Matej Mičušík

22 March 2019

Nanocomposites, based on an ethylene vinyl acetate (EVA) copolymer with a vinyl acetate content of 34 wt % and varying amounts of multiwall carbon nanotubes (MWCNTs), were prepared by an electrospinning method. The dispersibility of the MWCNTs in the...

  • Article
  • Open Access
7 Citations
6,012 Views
12 Pages

22 March 2019

Olefin block copolymer (OBC), with its low hard segments, can form unique space-filling spherulites other than confined-crystallization morphologies, mainly due to its weak phase-separation. In this work, 1,3;2,4-Bis(3,4-dimethylbenzylidene) sorbitol...

  • Article
  • Open Access
27 Citations
6,748 Views
10 Pages

22 March 2019

A polyelectrolyte film-coated electrode for the quantitative detection of glucose was reported. Carbon nanotubes, graphene oxide and polyelectrolyte with a ferrocenyl group were used to modify an enzyme electrode to facilitate the electron transfer b...

  • Review
  • Open Access
62 Citations
12,334 Views
31 Pages

Polymer-Based Device Fabrication and Applications Using Direct Laser Writing Technology

  • Zhen-Lin Wu,
  • Ya-Nan Qi,
  • Xiao-Jie Yin,
  • Xin Yang,
  • Chang-Ming Chen,
  • Jing-Ying Yu,
  • Jia-Chen Yu,
  • Yu-Meng Lin,
  • Fang Hui and
  • Ming-Shan Zhao
  • + 3 authors

22 March 2019

Polymer materials exhibit unique properties in the fabrication of optical waveguide devices, electromagnetic devices, and bio-devices. Direct laser writing (DLW) technology is widely used for micro-structure fabrication due to its high processing pre...

  • Article
  • Open Access
18 Citations
7,433 Views
22 Pages

Ethylene-co-norbornene Copolymerization Using a Dual Catalyst System in the Presence of a Chain Transfer Agent

  • Laura Boggioni,
  • Diego Sidari,
  • Simona Losio,
  • Udo M. Stehling,
  • Finizia Auriemma,
  • Anna Malafronte,
  • Rocco Di Girolamo,
  • Claudio De Rosa and
  • Incoronata Tritto

22 March 2019

Ethylene-co-norbornene copolymers were synthesized by a dual catalyst system at three concentrations of norbornene in the feed and variable amounts of ZnEt2, as a possible chain transfer agent. The dual catalyst system consists of two ansa-metallocen...

  • Article
  • Open Access
25 Citations
6,830 Views
18 Pages

21 March 2019

Lanthanum sulfadiazine (LaSD) was synthesized from sulfadiazine and lanthanum nitrate using water as solvent under alkaline conditions, and was used as a novel rare earth thermal stabilizer to stabilize poly(vinyl chloride) (PVC). The structure of La...

  • Article
  • Open Access
5 Citations
3,429 Views
12 Pages

Preparation of Layered Polyethylene Oxide/rGO Composite: Flexible Lateral Heat Spreaders

  • Fubin Luo,
  • Pinping Yan,
  • Qingrong Qian,
  • Hongzhou Li,
  • Baoquan Huang and
  • Qinghua Chen

21 March 2019

In this paper, high thermal conductive polyethylene oxide (PEO)/reduced graphene oxide (rGO) composite is prepared via large-scale green reduction. Flexible layered PEO/GO composites are pre-prepared in aqueous solution. It is demonstrated that PEO c...

  • Article
  • Open Access
9 Citations
3,970 Views
14 Pages

21 March 2019

Single-chain polymer nanoparticles (SCNPs) obtained through chain collapse by intramolecular cross-linking are attracting increasing interest as components of all-polymer nanocomposites, among other applications. We present a dielectric relaxation st...

  • Article
  • Open Access
5 Citations
4,987 Views
14 Pages

21 March 2019

Responsive polymer-based sensors have attracted considerable attention due to their ability to detect the presence of analytes and convert the detected signal into a physical and/or chemical change. High responsiveness, fast response speed, good line...

  • Article
  • Open Access
14 Citations
7,903 Views
17 Pages

Inductive Heating Using a High-Magnetic-Field Pulse to Initiate Chemical Reactions to Generate Composite Materials

  • Cordelia Zimmerer,
  • Catalina Salazar Mejia,
  • Toni Utech,
  • Kerstin Arnhold,
  • Andreas Janke and
  • Joachim Wosnitza

21 March 2019

Induction heating is efficient, precise, cost-effective, and clean. The heating process is coupled to an electrically conducting material, usually a metal. As most polymers are dielectric and non-conducting, induction heating is not applicable. In or...

  • Article
  • Open Access
22 Citations
4,143 Views
15 Pages

21 March 2019

The composite structure, good porosity, and electrochemical behavior of proton exchange membranes (PEMs) are important characteristics, which can improve the performance of polymer electrolyte fuel cells (PEFCs). In this study, we designed and synthe...

  • Review
  • Open Access
283 Citations
29,230 Views
41 Pages

21 March 2019

Scientists from various different fields use organo-trialkoxysilanes and tetraalkoxysilanes in a number of applications. The silica-based materials are sometimes synthesized without a good understanding of the underlying reaction kinetics. This liter...

  • Article
  • Open Access
41 Citations
6,796 Views
17 Pages

The Impact of Lignin Structural Diversity on Performance of Cellulose Nanofiber (CNF)-Starch Composite Films

  • Yadong Zhao,
  • Ayumu Tagami,
  • Galina Dobele,
  • Mikael E. Lindström and
  • Olena Sevastyanova

21 March 2019

Lignin fractions having different molecular weights and varied chemical structures isolated from kraft lignins of both softwood and hardwood via a sequential solvent fractionation technique were incorporated into a tunicate cellulose nanofibers (CNF)...

  • Article
  • Open Access
17 Citations
4,143 Views
20 Pages

21 March 2019

Herein, we report the formation and characterization of novel amphiphilic linear-dendritic block copolymers (LDBCs) composed of hydrophilic dendritic poly(ether-ester), PEE, blocks and hydrophobic linear poly(styrene), PSt. The LDBCs are synthesized...

  • Article
  • Open Access
33 Citations
4,125 Views
16 Pages

Effect of a Modified Silicone as a Thickener on Rheology of Liquid CO2 and Its Fracturing Capacity

  • Qiang Li,
  • Yanling Wang,
  • Fuling Wang,
  • Qingchao Li,
  • Forson Kobina,
  • Hao Bai and
  • Lin Yuan

21 March 2019

The low viscosity of pure liquid CO2 hindered the development of CO2 fracturing technology. A modified silicone polymer was prepared as a CO2 thickener to investigate the effect of temperature, pressure, shear rate and thickener content (wt.%) on the...

  • Article
  • Open Access
20 Citations
6,555 Views
17 Pages

Ethylcellulose in Organic Solution or Aqueous Dispersion Form in Designing Taste-Masked Microparticles by the Spray Drying Technique with a Model Bitter Drug: Rupatadine Fumarate

  • Katarzyna Wasilewska,
  • Marta Szekalska,
  • Patrycja Ciosek-Skibinska,
  • Joanna Lenik,
  • Anna Basa,
  • Julia Jacyna,
  • Michal Markuszewski and
  • Katarzyna Winnicka

20 March 2019

The taste of drugs is an important factor affecting pharmacotherapy effectiveness, and obtaining formulations with acceptable organoleptic properties is still an ongoing issue in pharmaceutical technology. One of the innovative methods of taste maski...

  • Article
  • Open Access
30 Citations
5,257 Views
11 Pages

20 March 2019

Fiber-reinforced polymer composite structures are frequently used in industries where personal safety is critical; therefore, it is important to periodically estimate or monitor the condition of high value, load bearing structures. The digital image...

  • Article
  • Open Access
36 Citations
5,162 Views
17 Pages

20 March 2019

One of the major challenges in the removal of organic pollutants is to design a material with high efficiency and high flux that can remove both cationic and anionic dyes, oil-in-water (O/W) emulsion and heavy metal ions. Herein, we constructed novel...

  • Article
  • Open Access
10 Citations
4,539 Views
18 Pages

POSS Hybrid Robust Biomass IPN Hydrogels with Temperature Responsiveness

  • Yi Chen,
  • Yueyun Zhou,
  • Wenyong Liu,
  • Hejie Pi and
  • Guangsheng Zeng

20 March 2019

In order to improve the performance of traditional sodium alginate (SA) hydrogels cross-linked by Ca2+ ions to meet greater application demand, a strategy was designed to structure novel SA-based gels (named OP-PN gels) to achieve both stimulus respo...

  • Article
  • Open Access
22 Citations
6,723 Views
13 Pages

P(VDF-TrFE)/PMMA Blended Films with Enhanced Electrowetting Responses and Superior Energy Storage Performance

  • Jiayun Chen,
  • Xiaoying Xiong,
  • Qilong Zhang,
  • Lingling Shui,
  • Shitao Shen,
  • Hui Yang,
  • Zhicai Zhu and
  • Fang Zhang

20 March 2019

P(VDF-TrFE) (vinylidene fluoride-co-trifluoroethylene)/PMMA (PVT/PMMA) blended films synthesized through a facile solution-blending method show outstanding performance for practical electrowetting and energy storage applications. The van der Waals fo...

  • Article
  • Open Access
8 Citations
4,678 Views
17 Pages

20 March 2019

In this study, a butadiene-isoprene coordination polymerization was initiated by a binary molybdenum (Mo)-based catalytic system consisting of modified MoO2Cl2 as the primary catalyst, triethyl aluminum substituted by m-cresol as the co-catalyst and...

  • Article
  • Open Access
20 Citations
5,009 Views
15 Pages

Thermal and Mechanical Analysis of Polyethylene Homo-Composites Processed by Rotational Molding

  • Antonio Greco,
  • Francesca Ferrari,
  • Maria Grazia Buccoliero and
  • Greta Trono

20 March 2019

This work is aimed at studying the suitability of ultra-high molecular weight polyethylene (UHMWPE) fibers for the production of polyethylene homo-composites processed by rotational molding. Initially pre-impregnated bars were produced by co-extrusio...

  • Article
  • Open Access
10 Citations
4,588 Views
11 Pages

Toughening of Epoxy Resin: The Effect of Water Jet Milling on Worn Tire Rubber Particles

  • Peter Tamas-Benyei,
  • Eniko Bitay,
  • Hajime Kishi,
  • Satoshi Matsuda and
  • Tibor Czigany

20 March 2019

In this work a cycloaliphatic amine-cured epoxy (EP) resin was modified by micron-scale rubber particles (RP). Nominal RP, in sizes of 200 and 600 µm respectively, were produced using worn truck tires and ultra-high-pressure water jet cutting....

  • Communication
  • Open Access
29 Citations
6,626 Views
8 Pages

Fabrication of Ultrafine PPS Fibers with High Strength and Tenacity via Melt Electrospinning

  • Zuo-Ze Fan,
  • Hong-Wei He,
  • Xu Yan,
  • Ren-Hai Zhao,
  • Yun-Ze Long and
  • Xin Ning

20 March 2019

Electrospinning (e-spinning) is an emerging technique to prepare ultrafine fibers. Polyphenylene sulfide (PPS) is a high-performance resin which does not dissolve in any solvent at room temperature. Commercial PPS fibers are produced mainly by meltbl...

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Polymers - ISSN 2073-4360