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Crystals, Volume 8, Issue 9

2018 September - 35 articles

Cover Story: The last nitronyl nitroxide bearing azolyl-substituent, namely 2-(1Н-tetrazol-5-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1Н-imidazol-3-oxide-1-oxyl, was isolated in a neutral form. In the crystal state, these nitroxides form intermolecular H-bonds connecting the radicals, thus forming infinite chains. Inside the chains, there are short intermolecular contacts (3.096 Å) between O and C atoms possessing spin densities of opposite signs; this explains the occurrence of ferromagnetic exchange coupling (J  20 cm1) between the radicals inside the chain predicted by BS-DFT. View this paper
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Articles (35)

  • Article
  • Open Access
22 Citations
6,852 Views
14 Pages

Selective Area Growth and Structural Characterization of GaN Nanostructures on Si(111) Substrates

  • Alexana Roshko,
  • Matt Brubaker,
  • Paul Blanchard,
  • Todd Harvey and
  • Kris A. Bertness

16 September 2018

Selective area growth (SAG) of GaN nanowires and nanowalls on Si(111) substrates with AlN and GaN buffer layers grown by plasma-assisted molecular beam epitaxy was studied. For N-polar samples filling of SAG features increased with decreasing lattice...

  • Article
  • Open Access
4 Citations
4,186 Views
12 Pages

14 September 2018

The volume versus temperature relations for Ni 3 Si and Ni 3 Ge are obtained by using the first principles calculations combined with the quasiharmonic approach. Based on the equilibrium volumes at temperature T, the temperature depende...

  • Review
  • Open Access
159 Citations
15,978 Views
68 Pages

14 September 2018

This review paper focuses on the phenomenon of thermochemical expansion of two specific categories of conducting ceramics: Proton Conducting Ceramics (PCC) and Mixed Ionic-Electronic Conductors (MIEC). The theory of thermal expansion of ceramics is u...

  • Article
  • Open Access
22 Citations
5,188 Views
12 Pages

13 September 2018

Graphene as a type of novel additive significantly enhanced the tribological performance of blended lubricating oil. However, the dispersibility of graphene with long-term stability in lubricating oil is still a challenge. Chemical modification for g...

  • Article
  • Open Access
9 Citations
4,602 Views
12 Pages

Inducing Crystallinity of Metal Thin Films with Weak Magnetic Fields without Thermal Annealing

  • Stefan S. Ručman,
  • Winita Punyodom,
  • Jaroon Jakmunee and
  • Pisith Singjai

13 September 2018

Since the discovery of thin films, it has been known that higher crystallinity demands higher temperatures, making the process inadequate for energy-efficient and environmentally friendly methods of thin film fabrication. We resolved this problem by...

  • Article
  • Open Access
12 Citations
5,281 Views
10 Pages

Mosaicity of Spin-Crossover Crystals

  • Sabine Lakhloufi,
  • Elodie Tailleur,
  • Wenbin Guo,
  • Frédéric Le Gac,
  • Mathieu Marchivie,
  • Marie-Hélène Lemée-Cailleau,
  • Guillaume Chastanet and
  • Philippe Guionneau

13 September 2018

Real crystals are composed of a mosaic of domains whose misalignment is evaluated by their level of “mosaicity” using X-ray diffraction. In thermo-induced spin-crossover compounds, the crystal may be seen as a mixture of metal centres, so...

  • Article
  • Open Access
15 Citations
5,854 Views
12 Pages

11 September 2018

Real-time in situ neutron diffraction was used to characterize the crystal structure evolution in a transformation-induced plasticity (TRIP) sheet steel during annealing up to 1000 °C and then cooling to 60 °C. Based on the results of full-pa...

  • Article
  • Open Access
46 Citations
5,299 Views
12 Pages

8 September 2018

Two groups of coumarin derivatives, 4-methyl-2-oxo-2H-chromen-7-yl 4-alkoxybenzoates (coumarin esters), In, and 4-methyl-2-oxo-2H-chromen-7-yl 4-(2-(4-alkoxyphenyl)diazenyl) benzoates (coumarin azoesters), IIn, were synthesized and investigated for t...

  • Review
  • Open Access
93 Citations
16,371 Views
30 Pages

A Review of Current Development of Graphene Mechanics

  • Qiang Cao,
  • Xiao Geng,
  • Huaipeng Wang,
  • Pengjie Wang,
  • Aaron Liu,
  • Yucheng Lan and
  • Qing Peng

6 September 2018

Graphene, a two-dimensional carbon in honeycomb crystal with single-atom thickness, possesses extraordinary properties and fascinating applications. Graphene mechanics is very important, as it relates to the integrity and various nanomechanical behav...

  • Article
  • Open Access
8 Citations
8,027 Views
9 Pages

Investigation of Inverted Perovskite Solar Cells for Viscosity of PEDOT:PSS Solution

  • Pao-Hsun Huang,
  • Yeong-Her Wang,
  • Chien-Wu Huang,
  • Wen-Ray Chen and
  • Chien-Jung Huang

6 September 2018

In this paper, we demonstrate that the inverted CH3NH3PbI3 (perovskite) solar cells (PSCs) based on fullerene (C60) as an acceptor is fabricated by applying an improved poly(3,4-ethlyenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) solution as a...

  • Review
  • Open Access
98 Citations
15,590 Views
27 Pages

Microwave Liquid Crystal Technology

  • Holger Maune,
  • Matthias Jost,
  • Roland Reese,
  • Ersin Polat,
  • Matthias Nickel and
  • Rolf Jakoby

5 September 2018

Tunable Liquid Crystal (LC)-based microwave components are of increasing interest in academia and industry. Based on these components, numerous applications can be targeted such as tunable microwave filters and beam-steering antenna systems. With the...

  • Article
  • Open Access
7 Citations
3,997 Views
10 Pages

Microstructure and Mechanical Properties of Mg–6Al–1Sn–0.3Mn Alloy Sheet Fabricated through Extrusion Combined with Rolling

  • Peng Peng,
  • Aitao Tang,
  • Xianhua Chen,
  • Jia She,
  • Shibo Zhou,
  • Jiangfeng Song and
  • Fusheng Pan

5 September 2018

Hot rolling was carried out in this study to modify the microstructures of an extruded Mg–6Al–1Sn–0.3Mn alloy sheet and investigate its effects on mechanical properties. After hot rolling, the grains and second phase of the extruded...

  • Article
  • Open Access
2 Citations
5,651 Views
10 Pages

4 September 2018

Nano-porous polysilicon high-temperature resistant solar absorption films were prepared by a thin layer of silver nanoparticles catalytic chemical etching. The polysilicon films with average tiny grain size of approximately 30 nm were obtained by hig...

  • Article
  • Open Access
6 Citations
3,656 Views
10 Pages

3 September 2018

Two new three-dimensional (3D) coordination compounds, namely a lead(II) coordination polymer (CP) {[Pb35-cpta)(µ6-cpta)(phen)2]·2H2O}n (1) and a zinc(II) metal-organic framework (MOF) {[Zn24-cpta)(µ-OH)(µ-4,4...

  • Article
  • Open Access
8 Citations
4,803 Views
10 Pages

Improved Solubility of Vortioxetine Using C2-C4 Straight-Chain Dicarboxylic Acid Salt Hydrates

  • Lei Gao,
  • Xian-Rui Zhang,
  • Shao-Ping Yang,
  • Juan-Juan Liu and
  • Chao-Jie Chen

2 September 2018

The purpose of this study was to improve the solubility of vortioxetine by crystal engineering principles. In this paper, three C2-C4 straight-chain dicarboxylic acid salt hydrates of vortioxetine (VOT-OA, VOT-MA-H2O, and VOT-SUA-H2O, VOT = vortioxet...

  • Article
  • Open Access
7 Citations
4,047 Views
32 Pages

1 September 2018

Existing studies on elastic waves in periodically laminated piezoelectric structures mainly concerned the passive band properties, since the electrical boundaries in the considered structures cannot vary. This paper investigates the tuning of band pr...

  • Article
  • Open Access
1 Citations
2,953 Views
5 Pages

31 August 2018

In this study, the small-size and side-view LED packages used in the backlight modules were examined by performing the electrostatic discharge (ESD) process. The high voltages used for the ESD process were 2 kV, 3 kV, and 4 kV. After ESD, the current...

  • Article
  • Open Access
8 Citations
4,770 Views
12 Pages

Bending Behavior of a Wrought Magnesium Alloy Investigated by the In Situ Pinhole Neutron Diffraction Method

  • Wei Wu,
  • Alexandru D. Stoica,
  • Dunji Yu,
  • Matthew J. Frost,
  • Harley D. Skorpenske and
  • Ke An

30 August 2018

The tensile twinning and detwinning behaviors of a wrought magnesium alloy have been investigated during in situ four-point bending using the state-of-the-art high spatial resolution pinhole neutron diffraction (PIND) method. The PIND method allowed...

  • Article
  • Open Access
9 Citations
4,136 Views
8 Pages

29 August 2018

The microstructure and martensitic transformation behavior of Ni50−xTi50Lax (x = 0.1, 0.3, 0.5, 0.7) shape memory alloys were investigated experimentally. Results show that the microstructure of Ni50−xTi50Lax alloys consists of a near-equ...

  • Article
  • Open Access
13 Citations
3,985 Views
7 Pages

29 August 2018

Molecular dynamics simulations of the seeded solidification of silicon along <100>, <110>, <111> and <112> directions have been carried out. The Tersoff potential is adopted for computing atomic interaction. The control of uni...

  • Review
  • Open Access
8 Citations
6,134 Views
21 Pages

GaAs Nanowires Grown by Catalyst Epitaxy for High Performance Photovoltaics

  • Ying Wang,
  • Xinyuan Zhou,
  • Zaixing Yang,
  • Fengyun Wang,
  • Ning Han,
  • Yunfa Chen and
  • Johnny C. Ho

29 August 2018

Photovoltaics (PVs) based on nanostructured III/V semiconductors can potentially reduce the material usage and increase the light-to-electricity conversion efficiency, which are anticipated to make a significant impact on the next-generation solar ce...

  • Article
  • Open Access
4 Citations
6,080 Views
8 Pages

28 August 2018

We studied the thermal effects on the behavior of incommensurate solid 4He at low temperatures using the path integral Monte Carlo method. Below a certain temperature, depending on the density and the structure of the crystal, the vacancies delo...

  • Article
  • Open Access
13 Citations
4,364 Views
15 Pages

26 August 2018

We deposited zinc-based films with various ammonia (ammonium hydroxide; NH4OH) and selenourea concentrations, at the bath temperature of 80 °C, on soda-lime glass substrates using the chemical bath deposition (CBD) process. We analyzed the result...

  • Article
  • Open Access
20 Citations
7,708 Views
8 Pages

24 August 2018

The single-mode microring resonators on lithium niobate thin films were designed and simulated using 2.5-D variational finite difference time domain mode simulations from Lumerical mode Solutions. The single-mode conditions and the propagation losses...

  • Article
  • Open Access
28 Citations
6,424 Views
15 Pages

24 August 2018

Wafers from three heights and two different lateral positions (corner and centre) of four industrial multicrystalline silicon ingots were analysed with respect to their grain structure and dislocation density. Three of the ingots were non-seeded and...

  • Review
  • Open Access
37 Citations
10,872 Views
32 Pages

23 August 2018

Metal-organic framework (MOF) thin films are receiving increasing attention in a number of different application fields, such as optoelectronics, gas separation, catalysis electronic devices, and biomedicine. In particular, their tunable composition...

  • Article
  • Open Access
6 Citations
4,284 Views
8 Pages

Effects on the Surface and Luminescence Properties of GaAs by SF6 Plasma Passivation

  • Yumeng Xu,
  • Xin Gao,
  • Xiaolei Zhang,
  • Zhongliang Qiao,
  • Jing Zhang,
  • Lu Zhou and
  • Baoxue Bo

23 August 2018

The passivation effects of the SF6 plasma on a GaAs surface has been investigated by using the radio frequency (RF) plasma method. The RF’s power, chamber pressure, and plasma treatment time are optimized by photoluminescence (PL), atomic force...

  • Article
  • Open Access
3 Citations
5,457 Views
13 Pages

Novel Devices for Transporting Protein Crystals to the Synchrotron Facilities and Thermal Protection of Protein Crystals

  • Andrea Flores-Ibarra,
  • Camila Campos-Escamilla,
  • Yasel Guerra,
  • Enrique Rudiño-Piñera,
  • Nicola Demitri,
  • Maurizio Polentarutti,
  • Mayra Cuéllar-Cruz and
  • Abel Moreno

23 August 2018

In this article, we use novel and non-conventional devices, based on polyolefins that help to increase the thermal protection of protein crystals in their crystallization conditions for crystallographic applications. The present contribution deals wi...

  • Article
  • Open Access
9 Citations
5,887 Views
20 Pages

22 August 2018

The present work examined the effect of artificial aging on the microstructure, texture, and hardness homogeneity in aluminum alloy AA6082 subjected to friction stir processing (FSP). Aging was applied to FSP samples at three different temperatures (...

  • Article
  • Open Access
4 Citations
8,504 Views
10 Pages

Formation and Application of High Reflectivity Controllable Barium Sulfate Microspheres

  • Yuejiao Liu,
  • Xiaoyan Guo,
  • Qingyang Gu,
  • Guangxiang He,
  • Suohe Yang and
  • Haibo Jin

21 August 2018

This paper investigated the influence of reaction conditions on particle morphology. X-ray powder diffraction (XRD), particle size distribution (PSD), and scanning electron microscopy (SEM) were used to characterize the morphology of barium sulfate....

  • Communication
  • Open Access
7 Citations
4,092 Views
7 Pages

A Crystallographic Study of a Novel Tetrazolyl-Substituted Nitronyl Nitroxide Radical

  • Vasily E. Romanov,
  • Irina Yu. Bagryanskaya,
  • Dmitry E. Gorbunov,
  • Nina P. Gritsan,
  • Elena V. Zaytseva,
  • Dominique Luneau and
  • Evgeny V. Tretyakov

21 August 2018

Spin-labelled compounds are widely used in chemistry, physics, biology, and material sciences, but the directed synthesis of some functionalized organic radicals is still a challenge. We succeeded in the preparation of a tetrazolyl-substituted nitron...

  • Article
  • Open Access
4 Citations
4,964 Views
9 Pages

Design of a Secondary Freeform Lens of UV LED Mosquito-Trapping Lamp for Enhancing Trapping Efficiency

  • Wei-Hsiung Tseng,
  • Diana Juan,
  • Wei-Cheng Hsiao,
  • Cheng-Han Chan,
  • Hsin-Yi Ma and
  • Hsiao-Yi Lee

21 August 2018

In this study, our proposed ultraviolet light-emitting diode (UV LED) mosquito-trapping lamp is designed to control diseases brought by insects such as mosquitoes. In order to enable the device to efficiently catch mosquitoes in a wider area, a secon...

  • Article
  • Open Access
27 Citations
8,587 Views
12 Pages

Preparation and Characterization of Novel Pharmaceutical Co-Crystals: Ticagrelor with Nicotinamide

  • Muhammad Inam,
  • Jiajia Wu,
  • Jie Shen,
  • Chi Uyen Phan,
  • Guping Tang and
  • Xiurong Hu

21 August 2018

Two new co-crystals, Ticagrelor with Nicotinamide, have been prepared with improved solubility. Because Ticalegor has a poor solubility and dissolution rate, a novel co-crystallization method with structurally homogenous crystalline material, an acti...

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Crystals - ISSN 2073-4352