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Crystals, Volume 15, Issue 4

April 2025 - 95 articles

Cover Story: Ferrocene derivatives and especially those incorporating the amide linkage are of interest across a wide range of scientific areas including bioorganometallic chemistry, molecular recognition and structural sciences. As such, five ferrocenylcarboxamide crystal structures (four of which contain fluorinated aromatic rings), show a diverse range of intermolecular interactions that influence molecular aggregation. Competition is noted between various intermolecular interactions with increasing aromatic fluorine content. This is particularly notable in the N-(ferrocenylmethyl)pentafluorobenzenecarboxamide structure where impressive cooperative amide–amide interactions and 1D columnar (Fc⋯C6F5R⋯)n stacking dominate in the crystal structure. View this paper
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Articles (95)

  • Review
  • Open Access
8 Citations
5,582 Views
26 Pages

Cellulose Nanomaterials: Characterization Methods, Isolation Techniques, and Strategies

  • Bogdan-Marian Tofanica,
  • Aleksandra Mikhailidi,
  • Maria E. Fortună,
  • Răzvan Rotaru,
  • Ovidiu C. Ungureanu and
  • Elena Ungureanu

9 April 2025

Nanocellulose, including cellulose nanofibers (CNFs), cellulose nanocrystals (CNCs), and bacterial nanocellulose (BNC), represents a promising class of bio-based nanomaterials derived from natural sources. These materials, derived from plant-based ce...

  • Article
  • Open Access
4 Citations
848 Views
17 Pages

Effect of Accumulative High-Pressure Torsion on Structure and Electrochemical Behavior of Biodegradable Fe-30Mn-5Si (wt.%) Alloy

  • Pulat Kadirov,
  • Yulia Zhukova,
  • Dmitry Gunderov,
  • Maria Antipina,
  • Tatyana Teplyakova,
  • Natalia Tabachkova,
  • Alexandra Baranova,
  • Sofia Gunderova,
  • Yury Pustov and
  • Sergey Prokoshkin

9 April 2025

A high-pressure torsion (HPT) with a number of revolutions (n) of up to 10 and an advanced method of accumulative HPT (AccHPT), n = 10 with subsequent post-deformation annealing (PDA) at 500 and 600 °C, were applied to a biodegradable Fe-30Mn-5Si...

  • Article
  • Open Access
887 Views
16 Pages

A Novel Formulation of Fosamprenavir Calcium: Therapeutic Deep Eutectic Solvent with Enhanced Properties

  • Jasna Prlić Kardum,
  • Iva Zokić,
  • Aleksandra Sander and
  • Patricija Pelin

9 April 2025

In the pharmaceutical industry, deep eutectic solvents can be used to enhance the solubility, permeability, and absorption of active pharmaceutical ingredients. In this paper, deep eutectic solvents were prepared by combining the active pharmaceutica...

  • Article
  • Open Access
2 Citations
1,505 Views
21 Pages

A Novel Zinc-Based MOF Featuring 2,4,6-Tris-(4-carboxyphenoxy)-1,3,5-triazine: Structure, Adsorption, and Photocatalytic Activity

  • Magdalena Angelova,
  • Hristina Lazarova,
  • Vanya Kurteva,
  • Rositsa Nikolova,
  • Rusi Rusew and
  • Boris Shivachev

8 April 2025

A metal–organic framework, MOF-S1, was synthesized via a solvothermal reaction between 2,4,6-tris-(4-carboxyphenoxy)-1,3,5-triazine (TCPT) and zinc nitrate hexahydrate. Single-crystal and powder X-ray diffraction analyses confirmed the formatio...

  • Article
  • Open Access
1,043 Views
28 Pages

8 April 2025

The water contents and geochemical evidence of nominally anhydrous minerals in peridotite xenoliths provide critical insights into lithospheric mantle features, offering a deep understanding of cratonic destruction and mantle evolution processes. Dam...

  • Article
  • Open Access
1 Citations
1,096 Views
23 Pages

Revisiting the Relation Between Magnesium and Heterogeneous Nucleation of Spheroidal Graphite

  • Ida Adhiwiguna,
  • Silke Rink,
  • Julian Kuschewski,
  • Marius Großarth and
  • Rüdiger Deike

7 April 2025

This research presents an innovative method for revisiting heterogeneous nucleation in the formation of spheroidal graphite during the production of ductile cast iron. This study incorporates controlled melting at a temperature of 1200 °C, follow...

  • Article
  • Open Access
27 Citations
1,083 Views
14 Pages

Rationally Designed PPy-Coated Fe2O3 Nanoneedles Anchored on N-C Nanoflakes as a High-Performance Anode for Aqueous Supercapacitors

  • Zhiqiang Cui,
  • Siqi Zhan,
  • Yatu Luo,
  • Yunfeng Hong,
  • Zexian Liu,
  • Guoqiang Tang,
  • Dongming Cai and
  • Rui Tong

7 April 2025

Flexible supercapacitors have emerged as pivotal energy storage components in wearable smart electronic systems, owing to their exceptional electrochemical performance. However, the widespread application of flexible supercapacitors in smart electron...

  • Article
  • Open Access
1 Citations
791 Views
23 Pages

Unveiling the Electrochemical Kinetics of an FeWO4-NiFeOOH Anode: Electrolyte Effects on Energy Conversion

  • Itheereddi Neelakanta Reddy,
  • Sarath Chandra Veerla,
  • Bhargav Akkinepally,
  • Moorthy Dhanasekar,
  • Jaesool Shim and
  • Cheolho Bai

6 April 2025

This study aims to determine the electrochemical performance of FeWO4 (Fe), NiFeOOH (Ni), and FeWO4/NiFeOOH (FeNi) electrodes in 0.1 M Na2SO4 and 0.1 M NaOH electrolytes, highlighting the impact of SO42− and OH− ions. Nyquist analysis dem...

  • Article
  • Open Access
3 Citations
1,064 Views
14 Pages

6 April 2025

To address the critical applications of heterogeneous structures involving nickel-based superalloys (IN718) and copper alloys (CuSn10) under extreme operating conditions, and to address the limitations of traditional joining techniques in terms of in...

  • Article
  • Open Access
3 Citations
1,133 Views
18 Pages

High Optical Performance TiO₂- and SiO₂-Based Composites with CuO and SrO Additions

  • Mioara Zagrai,
  • Izabell Craciunescu,
  • Alexandrina Nan,
  • Septimiu Tripon,
  • Alexandru Turza and
  • Vasile Rednic

5 April 2025

Our research aims to determine the optical properties of binary composites based on TiO2 and SiO2 oxides combined with additional metal oxides such as CuO and SrO. The inclusion of CuO and SrO together with TiO2 and SiO2 nanoparticles is driven by th...

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Crystals - ISSN 2073-4352