You are currently viewing a new version of our website. To view the old version click .

Crystals, Volume 15, Issue 4

April 2025 - 95 articles

Cover Story: Ferrocene derivatives and especially those incorporating the amide linkage are of interest across a wide range of scientific areas including bioorganometallic chemistry, molecular recognition and structural sciences. As such, five ferrocenylcarboxamide crystal structures (four of which contain fluorinated aromatic rings), show a diverse range of intermolecular interactions that influence molecular aggregation. Competition is noted between various intermolecular interactions with increasing aromatic fluorine content. This is particularly notable in the N-(ferrocenylmethyl)pentafluorobenzenecarboxamide structure where impressive cooperative amide–amide interactions and 1D columnar (Fc⋯C6F5R⋯)n stacking dominate in the crystal structure. View this paper
  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
  • You may sign up for email alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.

Articles (95)

  • Article
  • Open Access
712 Views
17 Pages

Band-like Inhomogeneity in Bulk ZnGeP2 Crystals, and Composition and Influence on Optical Properties

  • Alexey Lysenko,
  • Nikolay N. Yudin,
  • Margarita Khimich,
  • Mikhail Zinovev,
  • Elena Slyunko,
  • Sergey Podzyvalov,
  • Vladimir Kuznetsov,
  • Andrey Kalsin,
  • Maxim Kulesh and
  • Houssain Baalbaki
  • + 1 author

21 April 2025

The influence of intrinsic impurities on the formation of band-like inhomogeneities in ZGP single crystals containing two highly volatile elements has been analyzed. It has been shown that the formation of growth bands occurs due to the accumulation...

  • Article
  • Open Access
1 Citations
1,084 Views
15 Pages

21 April 2025

In the present work, we report the synthesis and characterization of 2-(4-(diphenylamino)benzylidene) malononitrile (DPAM) via a piperidine-catalyzed Knoevenagel condensation reaction. Two distinct crystal forms (A-1 and A-2) of this product were obt...

  • Article
  • Open Access
3 Citations
766 Views
10 Pages

Enhancement of Optoelectronic Properties of Multicrystalline Silicon Using Al-NPs and SiNx Layer

  • Mohamed Ben Rabha,
  • Ameny El Haj,
  • Achref Mannai,
  • Karim Choubani,
  • Mohammed A. Almeshaal and
  • Wissem Dimassi

21 April 2025

In this study, we investigated and compared the influence of alumina nanoparticles (Al-NPs) and silicon nitride (SiNx) layers individually deposited on multi-crystalline silicon (mc-Si) on mc-Si’s structural, optical, and optoelectronic characteristi...

  • Article
  • Open Access
2 Citations
791 Views
17 Pages

Study on Microstructure and Properties of Friction-Assisted Electrodeposition Cu-SiC Deposited Layer

  • Kang Qi,
  • Kun Li,
  • Youliang Yu,
  • Qinpeng Sun,
  • Xiaotong Yao and
  • Long Jiang

21 April 2025

Based on the friction phenomenon, this study proposes a new method for localized electrodeposition preparation and prepares Cu-SiC composite deposited layers on copper substrates. The morphology of the deposited layer was observed using optical micro...

  • Article
  • Open Access
634 Views
10 Pages

Ammonia Content in Natural Taranakite: An Experimental Study of Thermal Stability

  • Michael Casale,
  • Yuri Galliano,
  • Cristina Carbone and
  • Anna Maria Cardinale

20 April 2025

Taranakite is a mineral consisting of a hydrated layered aluminum phosphate, with the formula K3Al5(PO3OH)6(PO4)2·18H2O; its structure belongs to the R-3C group. If the mineral grows in an environment rich in bat and bird guano, the high nitro...

  • Article
  • Open Access
4 Citations
863 Views
25 Pages

Optimization of Spray Parameters and Corrosion Properties of Plasma-Sprayed Cr2O3 Coatings Using Response Surface Methodology

  • Minghui Liu,
  • Zhiwen Tan,
  • Yuantao Zhao,
  • Haoran Wang,
  • Shitao Zhang,
  • Rong Ma,
  • Tao Jiang,
  • Zhen Ma,
  • Ning Zhong and
  • Wenge Li

19 April 2025

In this study, the experimental design of response surface methodology was used to explore the interaction between spraying parameters to obtain an optimized process to reduce the porosity of the coating, and to prepare an excellent chromium oxide co...

  • Article
  • Open Access
1,125 Views
19 Pages

18 April 2025

The effect of the void defect on β−HMX−based polymer−bonded explosives (PBXs) for a comprehensive understanding of the deformation and fracture process is lacking. In this paper, the atomic scale model of the β−HMX c...

  • Article
  • Open Access
1 Citations
978 Views
11 Pages

18 April 2025

Among hole transport materials (HTMs), 2,2′,7,7′-Tetrakis(N,N-di-p-methoxyphenylamino)-9,9′-spirobifluorene (spiro-OMeTAD) is the most frequently adopted, due to its suitable energy band level in conventional-type perovskite solar c...

  • Review
  • Open Access
4 Citations
7,155 Views
39 Pages

Design and Processing of Metamaterials

  • Andrei Teodor Matei,
  • Anita Ioana Vișan and
  • Gianina Florentina Popescu-Pelin

18 April 2025

Metamaterials represent artificially structured materials that exhibit unusual properties, such as a negative refractive index, negative permeability and permittivity, negative cloaking by Poisson ratios and optical effects, etc., which are inaccessi...

  • Article
  • Open Access
1,066 Views
18 Pages

Electron Beam Welding of Dissimilar Ti6Al4V and Al6082-T6 Alloys Using Magnetron-Sputtered Cu Interlayers

  • Georgi Kotlarski,
  • Darina Kaisheva,
  • Maria Ormanova,
  • Milka Atanasova,
  • Angel Anchev,
  • Vladimir Dunchev,
  • Borislav Stoyanov and
  • Stefan Valkov

18 April 2025

In the present work, the influence of a magnetron-sputtered copper interlayer on the process of electron beam welding of Ti6Al4V and Al6082-T6 plates was investigated. A sample without a filler was also prepared as a control. The microstructure, micr...

of 10

Get Alerted

Add your email address to receive forthcoming issues of this journal.

XFacebookLinkedIn
Crystals - ISSN 2073-4352