Table of Contents
Catalysts, Volume 9, Issue 4 (April 2019)
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Cover Story (view full-size image) In this paper (Catalysts 2019, 9, 321), Kirillov and co-workers report a self-assembly synthesis, [...] Read more. In this paper (Catalysts
2019, 9, 321), Kirillov and co-workers report a self-assembly synthesis, crystal structures, and characterization of three new tetracopper(II) coordination compounds derived from an unexplored trifunctional aminoalcohol sulfonic acid. The obtained bioinspired products act as efficient and versatile homogeneous catalysts for the oxidative C−H functionalization of alkanes (propane and cycloalkanes) under mild conditions. Two different model reactions were explored: oxidation of alkanes to give alcohols and ketones, and carboxylation of alkanes to give carboxylic acids. The effects of different parameters and mechanistic and selectivity features were investigated. View this paper.