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Liquid-Phase Catalytic Oxidation of Limonene to Carvone over ZIF-67(Co)

National Center for International Research on Photoelectric and Energy Materials, Yunnan Provincial Collaborative Innovation Center of Green Chemistry for Lignite Energy, Yunnan Province Engineering Research Center of Photocatalytic Treatment of Industrial Wastewater, The Universities’ Center for Photocatalytic Treatment of Pollutants in Yunnan Province, School of Chemical Sciences & Technology, Yunnan University, Kunming 650091, China
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Catalysts 2019, 9(4), 374; https://doi.org/10.3390/catal9040374
Received: 15 March 2019 / Revised: 6 April 2019 / Accepted: 16 April 2019 / Published: 21 April 2019
(This article belongs to the Special Issue Iron and Cobalt Catalysts)
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Abstract

Liquid-phase catalytic oxidation of limonene was carried out under mild conditions, and carvone was produced in the presence of ZIF-67(Co), cobalt based zeolitic imidazolate framework, as catalyst, using t-butyl hydroperoxide (t-BHP) as oxidant and benzene as solvent. As a heterogeneous catalyst, the zeolitic imidazolate framework ZIF-67(Co) exhibited reasonable substrate–product selectivity (55.4%) and conversion (29.8%). Finally, the X-ray diffraction patterns of the catalyst before and after proved that ZIF-67(Co) acted as a heterogeneous catalyst, and can be reused without losing its activity to a great extent. View Full-Text
Keywords: liquid-phase catalytic oxidation; limonene; carvone; zeolitic imidazolate frameworks liquid-phase catalytic oxidation; limonene; carvone; zeolitic imidazolate frameworks
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Li, Y.; Yang, Y.; Chen, D.; Luo, Z.; Wang, W.; Ao, Y.; Zhang, L.; Yan, Z.; Wang, J. Liquid-Phase Catalytic Oxidation of Limonene to Carvone over ZIF-67(Co). Catalysts 2019, 9, 374.

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