Catalysts, Volume 12, Issue 6

The replacement of noble metal catalysts by abundant iron as an active compound in CO oxidation is of ecologic and economic interest. However, improvement of their catalytic performance to the same level as state-of-the-art noble metal catalysts requ...

CuCe mixed oxide is one of the most studied catalytic systems for preferential CO oxidation (CO-PrOx) for the purification of hydrogen-rich gas stream. In this study, a series of ceria supports were prepared via a citrates-hydrothermal route by alter...

The photocatalytic transformation of CO₂ to valuable man-made feedstocks is a promising method for balancing the carbon cycle; however, it is often hampered by the consumption of extra hole scavengers. Here, a synergistic redox system using photogene...

Activated bentonites are low-cost acid catalysts used in several reactions. However, their application at an industrial scale is affected by the formation of colloidal suspensions when these bentonites are in aqueous solutions. In order to overcome t...

Photoelectro-Fenton (PEF) process can continuously promote the occurrence of Fenton reaction and the generation of active species, which is an advanced oxidation technology for pollutant degradation. However, the lack of bifunctional catalysts restri...

Sodium-ion batteries (SIBs) are promising candidates for the replacement of lithium-ion batteries (LIBs) because of sodium’s abundant reserves and the lower cost of sodium compared to lithium. This is a topic of interest for developing novel an...

The water pollution caused by industry emissions makes effluent treatment a serious matter that needs to be settled. Heterogeneous Fenton oxidation has been recognized as an effective means to degrade pollutants in water. Attapulgite can be used as a...

A morphological strategy consisting of nanocasting synthesis of nickel aluminate spinel precursor was addressed. Two nanocasted catalysts were synthesized involving different template-removal procedures (i.e., Teflon-assisted calcination vs. NaOH was...

The COVID-19 pandemic has been transformed into one of the main worldwide challenges, in recent years. For controlling symptoms that are caused by this disease (e.g., chills or fever, shortness of breath and/or difficulty in breathing, cough, sore th...

Sodium titanate nanorods were synthesized by a hydrothermal method and subsequently modified with an iron precursor. For comparison, Fe₂O₃ nanocubes were also obtained through a similar hydrothermal treatment. Pristine, Fe-modified nanorods and Fe₂O₃...

In a batch reactor, the EF advanced oxidation decolorization of aqueous solutions of methyl orange MO, a commercial azo reactive textile dye, was investigated in the presence of two different electrodes. The evaluation included various operational va...

The solvent effect in the catalytic depolymerization of the three-dimensional network of lignin is discussed based on recent reports in this field. Also, the results of an experimental study on the depolymerization of kraft lignin are presented. The...

Densely aligned CoS₂ nanowires (NWs) on chemically durable stainless steel fibers felt (SSF) substates were synthesized by thermal sulfuring Co₃O₄ NWs, which were oxidized from hydrothermal synthesized Co(OH)_y(CO₃)_(1−0.5y)·nH₂O NWs precu...

MnO₂-CeO₂/PG-FA catalysts were prepared by supporting MnO₂-CeO₂ to PG-FA and used to remove Hg⁰ in simulated flue gas. The results show that MnO₂-CeO₂/PG-FA catalyst had excellent and stable Hg⁰ removal activity, which was mainly due to the combinati...

The ISO standard 22197-1:2016 used for the evaluation of the photocatalytic nitric oxide removal has a main drawback, which allows only the decrease of nitric oxide to be determined specifically. The remaining amount, expressed as “NO₂”,...

The multicomponent reaction of aldehydes, amines, and alkynes, known as A³ coupling, yields propargylamines, a valuable organic scaffold, and has received significant interest and attention in the last years. In order to fully realise the potential o...

The economic uncertainty associated with cellulosic bioethanol can be overcome through the inclusion of cheap substrates and methodologies that can extend the shelf life of cellulolytic enzymes. In this study, wild Trichoderma viride was used to prod...

The iridium(Ir) (triNHC = tri-N-heterocyclic carbene)-catalyzed transfer hydrogenation of glycerol carbonate (GC) is described in the absence of additional hydride sources. The described reduction provides a sustainable route to produce industrially-...

The dynamic growth in green organic synthetic methodologies for diverse heterocyclic scaffolds has substantially contributed to the field of medicinal chemistry over the last few decades. The use of hybrid metal nanocatalysts (NCs) is one such benign...

In this study, three solid acid catalysts, namely mesoporous aluminophosphate-supported 12-tungstophosphoric heteropoly acid (HPW/MAP), mesoporous aluminosilicate-supported 12-tungstophosphoric heteropoly acid (HPW/MAS), and gamma alumina-supported 1...

Biofuels produced via thermochemical conversions of waste biomass could be sustainable alternatives to fossil fuels but currently require costly downstream upgrading to be used in existing infrastructure. In this work, we explore how a low-cost, abun...

The mechanism in palladium-catalyzed carboxylation of thiophene and CO₂ is investigated using the density functional theory (DFT) calculations, including three consecutive steps of the formation of carbanion through breaking the C–H bond(s) via...

Chitin is one of the most abundant biopolymers on Earth but under-utilized. The effective conversion of chitin biomass to useful chemicals is a promising strategy to make full use of chitin. Among chitin-derived compounds, some furan derivatives, typ...

Natural bearing (raw and calcined at 500 °C) and iron-enriched (impregnation and pillaring) montmorillonitic clay samples were prepared. The obtained samples were characterized (X-ray diffraction, Fourier Transformed Infrared Spectroscopy, Scanni...

Compressed natural gas (CNG) and liquefied petroleum gas (LPG) are included in the group of promoted transport fuel alternatives in Europe. Most studies on emissions factors are based on old technology CNG and LPG fueled vehicles. Furthermore, there...

Phospholipase B (PLB) harbors three distinct activities with broad substrate specificities and application fields. Its hydrolyzing of sn-1 and sn-2 acyl ester bonds enables it to catalyze the production of L-alpha-glycerylphosphorylcholine (L-α...

It has been shown that structured lipids, formed in the process of enzymatic modification of natural hard fat with walnut oil, are capable of stabilizing emulsion systems without the need to add additional emulsifiers. This is especially true for emu...

HCN catalytic hydrolysis mechanism over Cu-ZSM-5 was investigated based on the density functional theory (DFT) with 6-31++g (d, p) basis set. Five paths (A, B, C, D, and E) were designed. For path A and path B, the first step is the nucleophilic atta...

Exploring new raw starch-hydrolyzing α-amylases and understanding their biochemical characteristics are important for the utilization of starch-rich materials in bio-industry. In this work, the biochemical characteristics of a novel raw starch-...

Cu and Co have shown superior catalytic performance to other transitional elements, and layered double hydroxides (LDHs) have presented advantages over other heterogeneous Fenton catalysts. However, there have been few studies about Co–Cu LDHs...

The counter electrode (CE) is an important and vital part of dye-sensitized solar cells (DSSCs). Pt CEs show high-performance in DSSCs using iodide-based electrolytes. However, the high cost of Pt CEs restricts their large-scale application in DSSCs...

This paper is a kinetic study that compares the rate of decolorization and subsequently the mineralization of Acid Blue 80 in model dyeworks wastewater, both in the homogeneous phase using the Fenton and photo-Fenton reactions, UV-C and UVC/H₂O₂ proc...

A new method of producing butyrylcholinesterase (BChE) preparations, stable in storage and use, has been proposed. The BChE preparation is the enzyme co-immobilized with 0.2 M 5-5′-dithiobis (2-nitrobenzoic acid) in starch or gelatin gel. All e...

Conventional anaerobic digestion is currently challenged by limited degradability and low methane production. Herein, it is proposed that magnetic nanoparticles (Fe₃O₄-NPs) and bioelectrochemical systems can be employed for the improvement of organic...

The main objective of this research was a systematic development of advanced micro/nanostructured materials based on the most used metal-oxides for ORR and metal-oxides with an extremely low-loading of Pt for comparison. Hybrid composites compared we...

Coke formation on n-butene cracking catalyst is the main reason for the reducing of its lifetime. To study the effects of acidity and textural properties on the coke formation process, a series of HY zeolite-type catalysts were prepared by ammonium h...

Enzymatic synthesis of short-chain esters (flavours) might enable their labelling as natural, increasing their value. Covalently immobilised Rhizopus oryzae lipase (EO-proROL) was used to synthesise isoamyl butyrate and acetate. In cyclohexane, the b...

This review considers the features of the catalysts with different nanoparticle structures architecture transformation under the various pre-treatment types. Based on the results of the publications analysis, it can be concluded that the chemical or...

Manganese alumina composited oxides (MnAlO_x) catalysts with ordered mesoporous structure prepared by evaporation-induced self-assembly (EISA) method was designed for the selective catalytic reduction (SCR) of NO_x with NH₃ at low temperature. The effe...

Cu/ZnO catalysts were synthesized via an impregnation method on an Al₂O₃-ZrO₂ support and modified by the addition of manganese and niobium as promoters. The effect of the selected promoters on the physicochemical properties and performance toward th...

The decomposition of toluene as a tar imitator in a gas composition similar to the gas after biomass pyrolysis was studied in a plasma–catalytic system. Nickel catalysts and the plasma from gliding arc discharge under atmospheric pressure were...

Herein we report the addition of acidic γ-butenolide and N-Boc-pyrrolidone to 4-nitro-5-styrylisoxazoles, a popular class of cinnamic ester synthetic equivalent. The reactions proceeded under the catalysis of Cinchona-based phase-transfer catal...

A novel and simple HCl-mediated, photocatalytic method for quinoxaline(on)es C3-H arylation with arylhydrazine under transition metal catalyst- and oxidant-free conditions is presented. Various quinoxaline(on)es underwent this transformation smoothly...

For the production of cyclic carbonates from the cycloaddition of CO₂ with epoxides, halogen pollution and product purity are two of the most common problems due to the usage of homogeneous halogen-containing catalysts such as ammonium salt and alkal...

The cascade catalysis of old yellow enzyme, alcohol dehydrogenase and glucose dehydrogenase has become a promising approach for one pot, two-step reduction of (E/Z)-citral to (S)-citronellol, serving as a chiral alcohol with rose fragrance. During th...

The direct hydrogenation of ${\mathrm{CO}}_2$ to long-chain hydrocarbons, so called ${\mathrm{CO}}_2$-based Fischer–Tropsch synthesis (FTS), is a viable future production route for various hydrocarbons used in the chemical industry or fuel applications. The detailed model...

To meet current economic demands enforcing the replacement of platinum-group metals, extensively used in three-way-catalytic converters (TWC), research is driven towards low-cost and widely available base metals. However, to cope with their lower act...

The development of effective, environmentally friendly catalysts for the Baeyer–Villiger reaction is becoming increasingly important in applied catalysis. In this work, we synthesized a 3D composite consisting of silica spheres coated with Mg/A...

Graphene-encapsulated nickel nanoclusters are a feasible strategy to inhibit the nickel deactivation of nickel-based catalysts. In this work, graphene-encapsulated catalysts (Ni@C/HZSM-5) were prepared by a compression forming process, using pseudo-b...

Sulfonated polymer-based materials, among heterogeneous catalysts, are frequently utilized in chemical transformations due to their outstanding chemical and physical durability. In this regard, a magnetic sulfonated melamine–formaldehyde resin...