Towards a Miniaturized Photoacoustic Detector for the Infrared Spectroscopic Analysis of SO₂F₂ and Refrigerants

Sulfuryl fluoride (SO₂F₂) is a toxic and potent greenhouse gas that is currently widely used as a fumigant insecticide in houses, food, and shipping containers. Though it poses a major hazard to humans, its detection is still carried out manually and only on a random basis. In this paper, we present a two-chamber photoacoustic approach for continuous SO₂F₂ sensing. Because of the high toxicity of SO₂F₂, the concept is to use a non-toxic substituent gas with similar absorption characteristics in the photoacoustic detector chamber, i.e., to measure SO₂F₂ indirectly. The refrigerants R227ea, R125, R134a, and propene were identified as possible substituents using a Fourier-transform infrared (FTIR) spectroscopic analysis. The resulting infrared spectra were used to simulate the sensitivity of the substituents of a photoacoustic sensor to SO₂F₂ in different concentration ranges and at different optical path lengths. The simulations showed that R227ea has the highest sensitivity to SO₂F₂ among the substituents and is therefore a promising substituent detector gas. Simulations concerning the possible cross-sensitivity of the photoacoustic detectors to H₂O and CO₂ were also performed. These results are the first step towards the development of a miniaturized, sensitive, and cost-effective photoacoustic sensor system for SO₂F₂.