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N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russia
Nanotechnology Education and Research Center, South Ural State University, 76 Lenina Avenue, 454080 Chelyabinsk, Russia
Author to whom correspondence should be addressed.
Academic Editor: Fawaz Aldabbagh
Molbank 2021, 2021(2), M1202;
Received: 27 March 2021 / Revised: 9 April 2021 / Accepted: 12 April 2021 / Published: 13 April 2021
(This article belongs to the Special Issue Heteroatom Rich Organic Heterocycles)
Dibromoderivatives of benzofused chalcogen-nitrogen heterocycles are important precursors in the synthesis of various photovoltaic materials. 4,7-Dibromobenzo[d][1,2,3]thiadiazole is a practically unexplored compound in this series. In this communication, it was shown that the nucleophilic substitution of 4,7-dibromobenzo[d][1,2,3]thiadiazole with morpholine gave selectively 4-substituted product—4-(7-bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine. The structure of the newly synthesized compound was established by means of elemental analysis, high resolution mass-spectrometry, 1H, 13C NMR, and IR spectroscopy, mass-spectrometry, and X-ray analysis. View Full-Text
Keywords: 4-(7-bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine; 4,7-dibromobenzo[d][1,2,3]thiadiazole; morpholine; nucleophilic substitution 4-(7-bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine; 4,7-dibromobenzo[d][1,2,3]thiadiazole; morpholine; nucleophilic substitution
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MDPI and ACS Style

Gudim, N.S.; Knyazeva, E.A.; Obruchnikova, N.V.; Rakitin, O.A.; Popov, V.V. 4-(7-Bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine. Molbank 2021, 2021, M1202.

AMA Style

Gudim NS, Knyazeva EA, Obruchnikova NV, Rakitin OA, Popov VV. 4-(7-Bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine. Molbank. 2021; 2021(2):M1202.

Chicago/Turabian Style

Gudim, Nikita S.; Knyazeva, Ekaterina A.; Obruchnikova, Natalia V.; Rakitin, Oleg A.; Popov, Vadim V. 2021. "4-(7-Bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine" Molbank 2021, no. 2: M1202.

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