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Open AccessShort Note

4-(7-Bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine

1
N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russia
2
Nanotechnology Education and Research Center, South Ural State University, 76 Lenina Avenue, 454080 Chelyabinsk, Russia
*
Author to whom correspondence should be addressed.
Academic Editor: Fawaz Aldabbagh
Molbank 2021, 2021(2), M1202; https://doi.org/10.3390/M1202
Received: 27 March 2021 / Revised: 9 April 2021 / Accepted: 12 April 2021 / Published: 13 April 2021
(This article belongs to the Special Issue Heteroatom Rich Organic Heterocycles)
Dibromoderivatives of benzofused chalcogen-nitrogen heterocycles are important precursors in the synthesis of various photovoltaic materials. 4,7-Dibromobenzo[d][1,2,3]thiadiazole is a practically unexplored compound in this series. In this communication, it was shown that the nucleophilic substitution of 4,7-dibromobenzo[d][1,2,3]thiadiazole with morpholine gave selectively 4-substituted product—4-(7-bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine. The structure of the newly synthesized compound was established by means of elemental analysis, high resolution mass-spectrometry, 1H, 13C NMR, and IR spectroscopy, mass-spectrometry, and X-ray analysis. View Full-Text
Keywords: 4-(7-bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine; 4,7-dibromobenzo[d][1,2,3]thiadiazole; morpholine; nucleophilic substitution 4-(7-bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine; 4,7-dibromobenzo[d][1,2,3]thiadiazole; morpholine; nucleophilic substitution
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MDPI and ACS Style

Gudim, N.S.; Knyazeva, E.A.; Obruchnikova, N.V.; Rakitin, O.A.; Popov, V.V. 4-(7-Bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine. Molbank 2021, 2021, M1202. https://doi.org/10.3390/M1202

AMA Style

Gudim NS, Knyazeva EA, Obruchnikova NV, Rakitin OA, Popov VV. 4-(7-Bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine. Molbank. 2021; 2021(2):M1202. https://doi.org/10.3390/M1202

Chicago/Turabian Style

Gudim, Nikita S.; Knyazeva, Ekaterina A.; Obruchnikova, Natalia V.; Rakitin, Oleg A.; Popov, Vadim V. 2021. "4-(7-Bromobenzo[d][1,2,3]thiadiazol-4-yl)morpholine" Molbank 2021, no. 2: M1202. https://doi.org/10.3390/M1202

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