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Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups

Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, Germany
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Molecules 2014, 19(12), 21022-21033; https://doi.org/10.3390/molecules191221022
Received: 24 October 2014 / Revised: 7 December 2014 / Accepted: 8 December 2014 / Published: 15 December 2014
(This article belongs to the Section Organic Chemistry)
A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR. View Full-Text
Keywords: sulfonic acid esters; primary alcohols; phenols; acylation; reaction kinetics sulfonic acid esters; primary alcohols; phenols; acylation; reaction kinetics
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MDPI and ACS Style

Idzik, K.R.; Nödler, K.; Maier, F.; Licha, T. Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups. Molecules 2014, 19, 21022-21033.

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