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Review

23 Citations

8,445 Views

35 Pages

The Reciprocal Principle of Selectand-Selector-Systems in Supramolecular Chromatography †

Volker Schurig

Molecules2016, 21(11), 1535;https://doi.org/10.3390/molecules21111535

15 November 2016

In selective chromatography and electromigration methods, supramolecular recognition of selectands and selectors is due to the fast and reversible formation of association complexes governed by thermodynamics. Whereas the selectand molecules to be se...

(This article belongs to the Special Issue Chromatographic Separation of Enantiomers: Commemorative Issue in Honor of Professor Stig Allenmark on the Occasion of His 80th Birthday)

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Review

23 Citations

7,244 Views

18 Pages

Chiral Monolithic Silica-Based HPLC Columns for Enantiomeric Separation and Determination: Functionalization of Chiral Selector and Recognition of Selector-Selectand Interaction

Mufarreh Asmari,
Xiaoyu Wang,
Natalia Casado,
Marjan Piponski and ,
Sergiy Kovalenko,
Liliya Logoyda,
Rasha Sayed Hanafi and
Sami El Deeb
+ 3 authors+ 0 author

Molecules2021, 26(17), 5241;https://doi.org/10.3390/molecules26175241

29 August 2021

This review draws attention to the use of chiral monolithic silica HPLC columns for the enantiomeric separation and determination of chiral compounds. Properties and advantages of monolithic silica HPLC columns are also highlighted in comparison to c...

(This article belongs to the Special Issue Chiral Stationary Phases for Enantioseparations: Fundamentals, Preparation, Methods, Applications and Chiral Recognition Mechanisms)

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Article

9 Citations

3,267 Views

17 Pages

Enantiomeric Separation and Molecular Modelling of Bioactive 4-Aryl-3,4-dihydropyrimidin-2(1H)-one Ester Derivatives on Teicoplanin-Based Chiral Stationary Phase

Isabella Bolognino,
Antonio Carrieri,
Rosa Purgatorio,
Marco Catto and ,
Rocco Caliandro,
Benedetta Carrozzini,
Benny Danilo Belviso,
Maria Majellaro,
Eddy Sotelo and
Cosimo Damiano Altomare
+ 6 authors+ 1 author

Separations2022, 9(1), 7;https://doi.org/10.3390/separations9010007

28 December 2021

The enantiomeric separation of 15 racemic 4-aryl-3,4-dihydropyrimidin-2(1H)-one (DHP) alkoxycarbonyl esters, some of which proved to be highly active as A_2B adenosine receptor antagonists, was carried out by HPLC on Chirobiotic^TM TAG, a chiral statio...

(This article belongs to the Special Issue Separation, Extraction and Purification of Natural Products from Plants)

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Article

8 Citations

3,739 Views

10 Pages

HPLC Enantioseparation of Rigid Chiral Probes with Central, Axial, Helical, and Planar Stereogenicity on an Amylose (3,5-Dimethylphenylcarbamate) Chiral Stationary Phase

Simona Rizzo,
Tiziana Benincori,
Francesca Fontana,
Dario Pasini and
Roberto Cirilli

Molecules2022, 27(23), 8527;https://doi.org/10.3390/molecules27238527

3 December 2022

The chiral resolving ability of the commercially available amylose (3,5-dimethylphenylcarbamate)-based chiral stationary phase (CSP) toward four chiral probes representative of four kinds of stereogenicity (central, axial, helical, and planar) was in...

(This article belongs to the Special Issue Natural Polymers and Biopolymers III)

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