Search Results (793)

Widely employed in diverse engineering applications, stiffened steel plates are often subjected to biaxial compressive loads. Under these conditions, buckling may occur, initially within the elastic range but potentially progressing into the elasto-plastic domain, which can lead to permanent deformations or structural collapse. To increase the ultimate buckling stress of plates, the implementation of longitudinal and transverse stiffeners is effective; however, this complexity makes analytical stress calculations challenging. As a result, numerical methods like the Finite Element Method (FEM) are attractive alternatives. In this study, the Constructal Design method and the Exhaustive Search technique were employed and associated with the FEM to optimize the geometric configuration of stiffened plates. A steel plate without stiffeners was considered, and 30% of its volume was redistributed into stiffeners, creating multiple configuration scenarios. The objective was to investigate how different arrangements and geometries of stiffeners affect the ultimate buckling stress under biaxial compressive loading. Among the configurations evaluated, the optimal design featured four longitudinal and two transverse stiffeners, with a height-to-thickness ratio of 4.80. This configuration significantly improved the performance, achieving an ultimate buckling stress 472% higher than the unstiffened reference plate. In contrast, the worst stiffened configuration led to a 57% reduction in performance, showing that not all stiffening strategies are beneficial. These results demonstrate that geometric optimization of stiffeners can significantly enhance the structural performance of steel plates under biaxial compression, even without increasing material usage. The approach also revealed that intermediate slenderness values lead to better stress distribution and delayed local buckling. Therefore, the methodology adopted in this work provides a practical and effective tool for the design of more efficient stiffened plates. Full article

Crack damage can significantly reduce the ultimate strength of marine structures, potentially leading to progressive collapse. This study employs finite element analysis to investigate how cracks affect the strength of plates and stiffened panels under uniaxial and biaxial compression, providing insights essential for robust structural design. The effects of crack size and orientation are explored through a systematic evaluation of longitudinal, transverse, and bidirectional cracks—sized at 10%, 25%, and 50% of structural dimensions (plate length and plate breadth/web height)—in both plates and unstiffened panels. The analysis identifies key parameters governing strength degradation and reveals that stiffened panels are more resistant to cracking, whereas plates are more sensitive to crack orientation and loading direction. These findings underscore the role of crack characteristics and structural reinforcement in maintaining residual strength and provide guidance for improving the accuracy and reliability of ultimate strength predictions. Full article

Inspired by the active site of methane monooxygenase, we designed a Cu₂O cluster anchored in the six-membered nitrogen cavity of a C₂N monolayer (Cu₂O@C₂N) as a stable and efficient enzyme-like catalyst. Density functional theory (DFT) calculations reveal that the bridged Cu-O-Cu structure within C₂N exhibits strong electronic coupling, which is favorable for methanol formation. Two competing mechanisms—the concerted and radical-rebound pathways—were systematically investigated, with the former being energetically preferred due to lower energy barriers and more stable intermediate states. Furthermore, strain engineering was employed to tune the geometric and electronic structure of the Cu-O-Cu site. Biaxial strain modulates the Cu-O-Cu bond angle, adsorption properties, and d-band center alignment, thereby selectively enhancing the concerted pathway. A volcano-like trend was observed between the applied strain and the methanol formation barrier, with 1% tensile strain yielding the overall energy barrier to methanol formation (ΔG_overall) as low as 1.31 eV. N₂O effectively regenerated the active site and demonstrated strain-responsive kinetics. The electronic descriptor Δε (ε_d − ε_p) captured the structure–activity relationship, confirming the role of strain in regulating catalytic performance. This work highlights the synergy between geometric confinement and mechanical modulation, offering a rational design strategy for advanced C1 activation catalysts. Full article

The aim of translucency-enhancing liquids (TEL) is to locally influence the phase composition of zirconia in order to increase its translucency. This study aimed to determine the influence of TEL on 3Y- and 4Y-TZP zirconia concerning roughness, hardness, wear, flexural strength, dynamic stability and fracture force of fixed dental prostheses after thermal cycling and mechanical loading. Two zirconia materials (4Y-TZP; 3Y-TZP-LA, n = 8 per material and test) were investigated with and without prior application of TEL. Two-body wear tests were performed in a pneumatic pin-on-block design (50 N, 120,000 cycles, 1.6 Hz) with steatite balls (r = 1.5 mm) as antagonists. Mean and maximum vertical loss as well as roughness (Ra, Rz) were measured with a 3D laser-scanning microscope (KJ 3D, Keyence, J). Antagonist wear was determined as percent area of the projected antagonist area. Martens hardness (HM; ISO 14577-1) and biaxial flexural strength (BFS; ISO 6872) were investigated. The flexural fatigue limit BFSdyn was determined under cyclic loading in a staircase approach with a piston-on-three-ball-test. Thermal cycling and mechanical loading (TCML: 2 × 3000 × 5 °C/55 °C, 2 min/cycle, H₂O dist., 1.2 × 10⁶ force á 50 N) was performed on four-unit fixed dental prostheses (FDPs) (n = 8 per group) and the fracture force after TCML was determined. Statistics: ANOVA, Bonferroni test, Kaplan–Meier survival, Pearson correlation; α = 0.05. TEL application significantly influences roughness, hardness, biaxial flexural strength, dynamic performance, as well as fracture force after TCML in 3Y-TZP. For 4Y-TZP, a distinct influence of TEL was only identified for BFS. The application of TEL on 3Y- or 4Y-TZP did not affect wear. TEL application has a strong effect on the mechanical properties of 3Y-TZP and minor effects on 4Y-TZP. All effects of the TEL application are of a magnitude that is unlikely to restrict clinical application. Full article

Since the definitions of the two-dimensional (2D) optical absorption coefficient and photoconductivity are independent of the thickness of 2D materials, they are more suitable than the dielectric function to describe the optical properties of 2D materials. Based on the many-body GW method and the Bethe–Salpeter equation, we calculated the quasiparticle electronic structure, optical absorbance, and complex photoconductivity of 2D InSe from a single layer (1L) to three layers (3L). The calculation results show that the energy difference between the direct and indirect band gaps in 1L, 2L, and 3L InSe is so small that strain can readily tune its electronic structure. The 2D optical absorbance results calculated taking into account exciton effects show that light absorption increases rapidly near the band gap. Strain modulation of 1L InSe shows that it transforms from an indirect bandgap semiconductor to a direct bandgap semiconductor in the biaxial compressive strain range of −1.66 to −3.60%. The biaxial compressive strain causes a slight blueshift in the energy positions of the first and second absorption peaks in monolayer InSe while inducing a measurable redshift in the energy positions of the third and fourth absorption peaks. Full article

Significant progress has been made in the low-temperature toughness and crack resistance of polypropylene fiber-reinforced composites. However, there is still a gap in the research on damage evolution under freeze–thaw cycles and complex stress ratios. To solve the problem of durability degradation of traditional rubble masonry in cold regions, this paper focuses on the study of polypropylene fiber-mortar-masonry blocks with different fiber contents. Using acoustic emission and digital image technology, the paper conducts a series of tests on the scaled-down polypropylene fiber-mortar-masonry structure, including uniaxial compressive tests, three-point bending tests, freeze–thaw cycle tests, and tests with different stress ratios. Based on the Kupfer criterion, a biaxial failure criterion for polypropylene fiber mortar-masonry stone (PPF-MMS) was established under different freeze–thaw cycles. A freeze–thaw damage evolution model was also developed under different stress ratios. The failure mechanism of PPF-MMS structures was analyzed using normalized average deviation (NAD), RA-AF, and other parameters. The results show that when the dosage of PPF is 0.9–1.1 kg/m³, it is the optimal content. The vertical stress shows a trend of increasing first and then decreasing with the increase in the stress ratio, and when α = 0.5, the degree of strength increase reaches the maximum. However, the freeze–thaw cycle has an adverse effect on the internal structure of the specimens. Under the same number of freeze–thaw cycles, the strength of the specimens without fiber addition decreases more rapidly than that with fiber addition. The NAD evolution rate exhibits significant fluctuations during the middle loading period and near the damage failure, which can be considered precursors to specimen cracking and failure. RA-AF results showed that the specimens mainly exhibited tensile failure, but the occurrence of tensile failure gradually decreased as the stress ratio increased. Full article

Thin plates are commonly used in mechanical structures such as ship hulls, offshore platforms, aircraft, automobiles, and bridges. When subjected to in-plane compressive loads, these structures may experience buckling. In some applications, perforations are introduced, altering membrane stress distribution and buckling behavior. This study investigates the elasto-plastic buckling behavior of perforated plates using the Finite Element Method (FEM), Constructal Design (CD), and Exhaustive Search (ES) techniques. Simply supported thin rectangular plates with central elliptical perforations were analyzed under biaxial elasto-plastic buckling. Three shapes of holes were considered—circular, horizontal elliptical, and vertical elliptical—along with sixteen aspect ratios and two different materials. Results showed that higher yield stress leads to higher ultimate stress for perforated plates. Regardless of material, plates exhibited a similar trend: ultimate stress decreased as the aspect ratio dropped from 1.00 to around 0.40 and then increased from 0.35 to 0.25. A similar pattern was observed in the stress components along both horizontal (x) and vertical (y) directions, once the y-component became considerably higher than the x-component for the same range of 0.40 to 0.25. For longer plates, in general, the vertical elliptical hole brings more benefits in structural terms, due to the facility in the distribution of y-components of stress. Full article

The sustainable development of geotechnical infrastructure necessitates using durable, efficient, and environmentally resilient reinforcement materials. This study investigates the pullout performance of geostraps to assess their potential as a sustainable alternative to conventional geosynthetics. This study focuses on the pullout performance of geostraps, flexible, polymeric reinforcement materials. There has not been a thorough study of their pullout resistance, which directly affects the stability and durability of reinforced soil structures. Pullout tests were conducted on sandy soil in a controlled environment. The experimental findings from the pullout test were then validated in a numerical model. The model was used to determine the pullout resistance of different grades of geostraps for comparative analysis. This helped to identify the possible application areas based on the pullout capacity of various grades. The results obtained for the geostraps were then compared with those in the established literature on geogrids. Initially, the pullout resistance of the M65 geostrap was up to 20% higher than that of a biaxial geogrid. This makes it a suitable option for reinforced earth applications. However, the maximum pullout resistance of geogrids was up to 8% higher than that of geostraps when subjected to a surcharge of 17 kN m⁻² in poorly graded sand. This study highlights the potential of geostraps as reinforcement materials, particularly in challenging environments where conventional geosynthetics may underperform. Future research may explore their behaviour with different soil types and other controlled environmental factors to establish their broader applicability and design charts. Full article

Flexible inflatable film wings have many functional advantages that traditional fixed rigid wings do not possess, such as foldability, small size, light weight, convenient storage, transportation, and so on. More and more scholars and engineers are paying attention to flexible inflatable wings, which have gradually become a new hot research topic. However, flexible wings rely on inflation pressure to maintain the shape and rigidity of the skin film, and the inflation pressure has a significant influence on the strain deformation and wing bearing characteristics of flexible wing skin film. Here, based on the flexible mechanics theory and balance principle of flexible inflatable film, a theoretical model of structural deformation and internal inflation pressure was constructed, and finite element simulation analysis under different internal inflation pressure conditions was carried out as well. The results demonstrate that the biaxial deformation of flexible wing skin film is closely related to internal inflation pressure, local size, configuration, and film material properties. However, strain deformation along the wingspan direction is quite distinguishing, skin films work under the condition of biaxial plane deformation, and the strain deformation of the spanning direction is obviously higher than that of the chord direction, which all increases with internal inflation pressure. Therefore, it is necessary to pay more attention to bearing strain deformation characteristics to meet the bearing stiffness requirements, which could effectively provide a theoretical reference for the structural optimization design and inflation scheme setting of flexible inflatable wings. Full article

China generates substantial construction and demolition (C&D) waste, owing to rapid urbanization. However, the resource utilization rate of C&D waste remains low. This work is devoted to promoting the application of C&D waste in reinforced soil structures. In this research, the physical and mechanical properties of C&D waste recycled aggregate, biaxial geogrids and triaxial geogrids were first clarified. Then, a series of pullout tests were carried out based on the large-size pullout test setup. With the help of macroscopic indicators, including pullout resistance, horizontal displacement and interface friction coefficient, the effects of normal stress, pullout rate and reinforcement type on the characteristics of the reinforcement–C&D waste recycled aggregate interface were clarified. The test results show that normal stress has the greatest influence on pullout resistance. The pullout rate has the lowest effect on pullout resistance. In addition, the interface effect between the triaxial geogrid and the C&D waste recycled aggregate is more significant than that in biaxial geogrid–C&D waste recycled aggregate. The interface friction angle of triaxial geogrids is 18.1% higher than that of biaxial geogrids (11.6° vs. 9.82°), correlating with an enhanced particle interlocking mechanism. Full article

The new mineral achyrophanite (K,Na)₃(Fe³⁺,Ti,Al,Mg)₅O₂(AsO₄)₅ was found in high-temperature sublimates of the Arsenatnaya fumarole at the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Tolbachik volcano, Kamchatka, Russia. It is associated with aphthitalite-group sulfates, hematite, alluaudite-group arsenates (badalovite, calciojohillerite, johillerite, nickenichite, hatertite, and khrenovite), ozerovaite, pansnerite, arsenatrotitanite, yurmarinite, svabite, tilasite, katiarsite, yurgensonite, As-bearing sanidine, anhydrite, rutile, cassiterite, and pseudobrookite. Achyrophanite occurs as long-prismatic to acicular or, rarer, tabular crystals up to 0.02 × 0.2 × 1.5 mm, which form parallel, radiating, bush-like, or chaotic aggregates up to 3 mm across. It is transparent, straw-yellow to golden yellow, with strong vitreous luster. The mineral is brittle, with (001) perfect cleavage. D_calc is 3.814 g cm^–3. Achyrophanite is optically biaxial (+), α = 1.823(7), β = 1.840(7), γ = 1.895(7) (589 nm), 2V (meas.) = 60(10)°. Chemical composition (wt.%, electron microprobe) is: Na₂O 3.68, K₂O 9.32, CaO 0.38, MgO 1.37, MnO 0.08, CuO 0.82, ZnO 0.48, Al₂O₃ 2.09, Fe₂O₃ 20.42, SiO₂ 0.12, TiO₂ 7.35, P₂O₅ 0.14, V₂O₅ 0.33, As₂O₅ 51.88, SO₃ 1.04, and total 99.40. The empirical formula calculated based on 22 O apfu is Na_1.29K_2.15Ca_0.07Mg_0.34Mn_0.01Cu_0.11Zn_0.06Al_0.44Fe³⁺_2.77Ti_1.00Si_0.02P_0.02S_0.14V_0.04As_4.90O₂₂. Achyrophanite is orthorhombic, space group P222₁, a = 6.5824(2), b = 13.2488(4), c = 10.7613(3) Å, V = 938.48(5) ų and Z = 2. The strongest reflections of the PXRD pattern [d,Å(I)(hkl)] are 5.615(59)(101), 4.174(42)(022), 3.669(31)(130), 3.148(33)(103), 2.852(43)(141), 2.814(100)(042, 202), 2.689(29)(004), and 2.237(28)(152). The crystal structure of achyrophanite (solved from single-crystal XRD data, R = 4.47%) is unique. It is based on the octahedral-tetrahedral M-T-O pseudo-framework (M = Fe³⁺ with admixed Ti, Al, Mg, Na; T = As⁵⁺). Large-cation A sites (A = K, Na) are located in the channels of the pseudo-framework. The achyrophanite structure can be described as stuffed, with the defect heteropolyhedral pseudo-framework derivative of the orthorhombic Fe³⁺AsO₄ archetype. The mineral is named from the Greek άχυρον, straw, and φαίνομαι, to appear, in allusion to its typical straw-yellow color and long prismatic habit of crystals. Full article

Type IV hydrogen storage cylinders are pivotal for high-pressure hydrogen storage and transportation, offering advantages such as lightweight design, high hydrogen storage density, and cost efficiency. Polyamide 6 (PA6) has emerged as a promising liner material due to its excellent mechanical strength, chemical resistance, and gas barrier properties. However, challenges remain, including high hydrogen permeability and insufficient mechanical performance under extreme temperature and pressure conditions. This review systematically summarizes recent advances in modification strategies to enhance PA6’s suitability for Type IV hydrogen storage cylinders. Incorporating nanofillers (e.g., graphene, montmorillonite, and carbon nanotubes) significantly reduces hydrogen permeability. In situ polymerization and polymer blending techniques improve toughness and interfacial adhesion (e.g., ternary blends achieve a special increase in impact strength). Multiscale structural design (e.g., biaxial stretching) and process optimization further enhance PA6’s overall performance. Future research should focus on interdisciplinary innovation, standardized testing protocols, and industry–academia collaboration to accelerate the commercialization of PA6-based composites for hydrogen storage applications. This review provides theoretical insights and engineering guidelines for developing high-performance liner materials. Full article

Plastic forming in magnesium alloy sheet products is becoming a hot topic because of its potential in light-weight structural designs. Due to the special anisotropic and tension–compression asymmetrical properties of magnesium alloys, traditional modeling methods based on the von Mises yield criterion and using only uniaxial tensile properties for bending-dominated process simulations are not able to produce accurate predictions. In this study, two kinds of tensile tests (uniaxial and biaxial) and some compressive tests were performed along three material directions to obtain anisotropic and asymmetric properties, based on which the parameters of the Hill48 and Verma yield criteria were obtained. Then, the user subroutine VUMAT was developed, and the roll-forming process for magnesium alloys was simulated with the established anisotropic and asymmetric yield criteria. Finally, a roll-forming experiment on AZ31 magnesium alloy was performed. Compared with the experiments, it was found that roll-forming and springback predictions based on the Verma yield criterion had higher accuracy than those based on the von Mises and Hill48 yield criteria FEM models, which ignore anisotropy and asymmetry. This study provides an important FEM modeling idea that considers not only anisotropy but also asymmetry in the bending-dominated forming processes of magnesium alloys in which tension and compression exist simultaneously. Full article

This study focuses on optimizing cruciform specimen configurations for the biaxial tensile testing of soft composite materials used in the aerospace industry under conditions of large deformation. A comprehensive evaluation system based on stress–strain uniformity and load transfer efficiency was established, and the stability of these metrics during the tensile process was analyzed. Using finite element simulation and multi-parameter analysis, the main parameter set affecting specimen performance was identified. The influence of different parameters on stress–strain uniformity and load transfer efficiency was investigated. Based on the optimization criteria, an optimized planar cross-shaped specimen configuration was developed. This configuration demonstrated excellent performance stability during deformation, with final stress uniformity error controlled to within 2.2%. The final strain uniformity error was maintained at 2.9%. The fluctuation range of load transfer efficiency did not exceed 1.5%. This study provides guidelines for designing specimens for large deformation testing of soft composite materials and can be used as a reference for future work on optimizing specimens. Full article

Traditional fiber-reinforced polymer (FRP) retrofit methods can restore the strength of reinforced concrete columns well, but stiffness is also partly restored. To increase the initial stiffness of retrofitted columns, this study investigated the seismic behavior of retrofitted resilient reinforced concrete (RRC) columns that were retrofitted by different methods, including high-strength mortar retrofit, carbon fiber-reinforced polymer (CFRP) retrofit, and CFRP and steel plate retrofit. In addition, the effect of the axial load was also considered. Quasi-static tests were conducted twice on five specimens, i.e., before and after repairing. The first test was used to create earthquake damage, and the second test was used to compare the seismic behavior of the retrofitted columns. The experimental results indicated that the CFRP retrofit method, whether with a steel plate or not, can restore the lateral resistance capacity well; furthermore, the drift-hardening behavior and self-centering performance were well maintained. The residual drift ratio of the CFRP-retrofitted column was less than 0.5%, even at a drift ratio of 3.5%, and less than 1% at the 6% drift ratio. However, the initial stiffness was only partly restored using the CFRP sheet. The introduction of steel plates was beneficial in restoring the initial stiffness, and the stiffness recovery rate remained above 90% when CFRP sheets and steel plates were used simultaneously. The strain distribution of the CFRP sheet showed that the steel plate did work at the initial loading stage, but the effect was limited. By using the steel plate, the CFRP hoop strain on the south side was reduced by 68% at the 6% drift ratio in the push direction and 38% in the pull direction. The axial strain of CFRP cannot be ignored due to the larger value than the hoop strain, which means that the biaxial stress condition should be considered when using an FRP sheet to retrofit RC columns. Full article