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Keywords = Neoproterozoic

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32 pages, 14836 KB  
Article
Petrogenesis of Serpentinites and Chromitites in the Neoproterozoic Bou Azzer Ophiolite, Morocco: From Mantle Depletion to High-Pressure Exhumation
by Amina Wafik, Mohamed Ben Massoude, Youssef Atif, Atman Ait Lamqadem, Reza Rooki, Aref Shirazi, Adel Shirazy and Amin Beiranvand Pour
Minerals 2026, 16(5), 460; https://doi.org/10.3390/min16050460 - 29 Apr 2026
Abstract
Serpentinites and associated chromitites of the Neoproterozoic Bou Azzer ophiolite (Central Anti-Atlas, Morocco) provide key constraints on mantle depletion, melt–rock interaction, and the tectono-metamorphic evolution of a supra-subduction zone (SSZ) system. This study integrates field observations, petrography, Raman spectroscopy, and whole-rock/mineral chemistry to [...] Read more.
Serpentinites and associated chromitites of the Neoproterozoic Bou Azzer ophiolite (Central Anti-Atlas, Morocco) provide key constraints on mantle depletion, melt–rock interaction, and the tectono-metamorphic evolution of a supra-subduction zone (SSZ) system. This study integrates field observations, petrography, Raman spectroscopy, and whole-rock/mineral chemistry to decipher the history of this highly dismembered ultramafic suite. The mantle sequence is dominated by antigorite-bearing serpentinites derived primarily from refractory harzburgitic and dunitic protoliths. Whole-rock geochemistry and highly depleted chromite compositions (Cr# = 0.50–0.68; Mg# = 0.43–0.77; TiO2 ≤ 0.18 wt.%) demonstrate that these peridotites represent refractory residues formed after high degrees of partial melting (~15–25%). The data delineate a clear evolutionary trend from abyssal to fore-arc and back-arc environments, where infiltrating boninitic melts drove localized podiform chromitite formation through intense melt–rock interaction. Crucially, thermodynamic and mineral–chemical constraints challenge previous models of simple greenschist-facies obduction. Equilibration temperatures exceeding 600 °C and chromite stability within the lower amphibolite to near-granulite facies indicate that the oceanic lithosphere underwent deep subduction prior to its exhumation. This high-temperature, high-pressure metamorphism was followed by multistage retrogressive serpentinization and intense CO2-rich metasomatism (talc-magnesite alteration) during Pan-African transpressional tectonics. Ultimately, the Bou Azzer ophiolite represents a mature SSZ mantle wedge, recording a complete geodynamic cycle from deep subduction-zone metamorphism to final tectonic emplacement along the northern margin of the West African Craton. Full article
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18 pages, 60393 KB  
Article
Mineralogical Characteristics of White Nephrite from Dikou, Fujian Province, Southeastern China
by Shuo Ran and Yingxin Liu
Crystals 2026, 16(5), 284; https://doi.org/10.3390/cryst16050284 - 24 Apr 2026
Viewed by 299
Abstract
Nephrite is a significant jade resource, and systematic investigation of its deposits contributes to regional metallogenic synthesis and exploration targeting. The recently discovered white nephrite deposit in the Dikou area, Fujian Province, remains inadequately characterized. This study presents a comprehensive mineralogical investigation employing [...] Read more.
Nephrite is a significant jade resource, and systematic investigation of its deposits contributes to regional metallogenic synthesis and exploration targeting. The recently discovered white nephrite deposit in the Dikou area, Fujian Province, remains inadequately characterized. This study presents a comprehensive mineralogical investigation employing polarizing microscopy, scanning electron microscopy, electron probe microanalysis, X-ray powder diffraction and laser Raman spectroscopy to elucidate the mineralogical and petrochemical characteristics of Dikou nephrite and constrain its genesis. The results demonstrate that tremolite constitutes the predominant mineral phase, accompanied by abundant diopside and quartz, with minor dolomite, prehnite, and apatite. Based on subtle compositional variations, tremolite can be categorized into two generations: early metasomatic Tr-I and late-stage Tr-II. All tremolite samples exhibit Fe-depleted, Mg-enriched composition with Mg# > 0.99. The mineral assemblage and textural relationships record multiple episodes of hydrothermal metasomatism. Integrated with the regional geological constraints, the deposit formation is genetically linked to the Neoproterozoic–Early Paleozoic ocean–continent transition of the South China Plate and is classified as D-type nephrite. The Dikou nephrite exhibits the mineral assemblage typical of dolomite-related deposits, displaying a distinctive felt-like fibrous texture that yields a homogeneous structure and superior aesthetic quality. Its Fe-depleted composition imparts a notably lighter coloration relative to D-type nephrite from other deposits. This study advances understanding of Dikou nephrite genesis, highlights the diversity of metallogenic environments in Fujian Province, and provides a theoretical framework for exploration of analogous deposits. Full article
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25 pages, 8644 KB  
Article
Apatite as an Indicator of Sedimentary Environment and Diagenesis for the Hengyang Neoproterozoic Iron Formation, South China
by Chuangye Zhang, Lei Liu, Kuanxin Huang and Tianyang Hu
Minerals 2026, 16(4), 392; https://doi.org/10.3390/min16040392 - 10 Apr 2026
Viewed by 269
Abstract
Neoproterozoic iron formations (NIFs), deposited during Cryogenian glaciation events, are critical for understanding early Earth oxidation events and the evolution of glacial–interglacial environments. Apatite, a common accessory mineral in iron formations, holds significant implications for sedimentary environments and diagenetic processes, but these aspects [...] Read more.
Neoproterozoic iron formations (NIFs), deposited during Cryogenian glaciation events, are critical for understanding early Earth oxidation events and the evolution of glacial–interglacial environments. Apatite, a common accessory mineral in iron formations, holds significant implications for sedimentary environments and diagenetic processes, but these aspects remain underexplored. This study focuses on the Hengyang NIF in the Nanhua Basin, South China. Using whole-rock geochemistry and major and trace element analysis of apatite, we investigate the environmental significance of apatite and associated diagenetic processes. Our results show that the Hengyang NIF are formed through the mixing of low-temperature hydrothermal fluids, seawater, and terrigenous detrital materials, with hydrothermal contributions increasing progressively from the bottom to the top of the iron formation layers. Whole-rock geochemical proxies indicate that the depositional water column evolved from relatively oxidizing to weakly oxidizing conditions. The study further demonstrates that the rare earth element patterns in apatite, characterized by middle rare earth element enrichment, are primarily controlled by porewater chemistry during diagenesis. In contrast, Ce anomalies and the V/Cr and V/(V + Ni) ratios in apatite, which are strongly influenced by fluid–rock interactions and magnetite recrystallization, no longer reliably reflect the primary depositional environment. The Th/U ratio in apatite, due to its geochemical stability, aligns with whole-rock trends and serves as a more reliable redox proxy. Based on these findings, we propose a three-stage depositional-diagenetic model: the early and late stages are characterized by high-energy, rapid sedimentation with minimal diagenetic modification, while the middle stage is dominated by low-energy, stagnant conditions with slow sedimentation rates, leading to prolonged diagenesis and significant decoupling of mineral geochemical signatures. This study emphasizes the need to distinguish between sedimentary and diagenetic signals when using mineral geochemical proxies to reconstruct paleoenvironments and provides new insights into the genesis of Neoproterozoic iron formations. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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28 pages, 14728 KB  
Article
Decoding the Middle Tonian Tectonic Evolution of the Jiangnan Orogen, South China: Integrated Constraints from Volcano-Sedimentary and Magmatic Records of the Fanjingshan Region
by Yaran Dai, Jiawei Zhang, Taiping Ye, Tingting Zhang, Jianshu Chen and Lei Shi
Minerals 2026, 16(3), 334; https://doi.org/10.3390/min16030334 - 21 Mar 2026
Viewed by 305
Abstract
The Middle Tonian tectonic setting of the Jiangnan Orogen, South China, remains intensely debated, and is centered on two competing models: subduction–collision versus mantle plume. This study addresses this critical knowledge gap through an integrated, multi-proxy investigation of the Middle Tonian Fanjingshan Group. [...] Read more.
The Middle Tonian tectonic setting of the Jiangnan Orogen, South China, remains intensely debated, and is centered on two competing models: subduction–collision versus mantle plume. This study addresses this critical knowledge gap through an integrated, multi-proxy investigation of the Middle Tonian Fanjingshan Group. This region preserves a continuous volcano-sedimentary and magmatic record, offering key insights into the orogen’s full lifecycle. To test these hypotheses, we employed a synthesis of geological survey, sediment provenance analysis, detrital zircon U-Pb geochronology of clastic rocks to determine sediment provenance and basin evolution, and petrogenetic study of coeval magmatic suites (pillow lava, mafic–ultramafic sills, and granitoids) to evaluate their magmatic processes and tectonic setting. Analysis of 1736 detrital zircon U-Pb ages from Middle Tonian strata reveals a four-stage provenance evolution: (1) SW Yangtze sources in a passive margin basin before 870 Ma; (2) bidirectional sources in an 870–835 Ma arc-derived basin; (3) syn-collisional detritus during 835–820 Ma amalgamation; and (4) post-collisional and northern Yangtze inputs in an 800 Ma rifting basin. Geochemical data from ~845–840 Ma basalts and coeval sills reveal calc-alkaline affinities and marked subduction-fluid signatures. Their calculated mantle potential temperature (1404 °C) is significantly lower than that expected for plume-derived melts (1570 °C), which is consistent with melting in a subduction-modified mantle wedge, supporting a continental rear-arc basin setting. The ~845–832 Ma mafic–ultramafic sills exhibit symmetrical geochemical zoning and two-stage emplacement, recording sustained magma recharge in the rear-arc basin. Furthermore, the ~830 Ma Fanjingshan granite is identified as a crust-derived, syn-collisional S-type granite. Synthesizing these findings, we demonstrate that the sedimentary and magmatic records collectively point to plate margin setting. A four-stage tectonic model is suggested: (1) pre-870 Ma passive margin without significant magmatic activity; (2) 870–835 Ma continental arc development at an active continental margin; (3) 835–820 Ma Yangtze–Cathaysia collision; and (4) post-820 Ma post-orogenic rifting. This work provides a robust regional case study, demonstrating that integrating records of deep magmatic processes with coeval shifts in sedimentary provenance and basin architecture is essential to reconstruct the complete evolution of ancient orogens. Full article
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21 pages, 7513 KB  
Article
The Geochronology and Geochemistry of Zircon and Apatite from the Shenshan Epimetamorphic Rocks in Ningdu, China: Implications for Ion-Adsorption-Type REE Metallogenesis
by Shuilong Wang, Huihu Fan, Luping Zeng, Dehai Wu, Wei Wan and Junpeng Wang
Minerals 2026, 16(3), 324; https://doi.org/10.3390/min16030324 - 19 Mar 2026
Viewed by 429
Abstract
In recent decades, ion-adsorption-type rare earth element (iREE) deposits have been widely documented in the weathering crusts of granitic and volcanic rocks and their geological characteristics and genetic mechanisms extensively studied. Ion-adsorption-type REE mineralization was documented for the first time in the weathered [...] Read more.
In recent decades, ion-adsorption-type rare earth element (iREE) deposits have been widely documented in the weathering crusts of granitic and volcanic rocks and their geological characteristics and genetic mechanisms extensively studied. Ion-adsorption-type REE mineralization was documented for the first time in the weathered crust overlying the epimetamorphic rocks in Ningdu County, China. In contrast to well-documented granite-derived weathering profiles, investigations of epimetamorphic rocks as protoliths for such REE deposits remain limited, particularly regarding the mineralogy of REE-bearing phases and the geochronology and geochemistry of their parent rocks. To address this gap, the present study combines comprehensive petrographic and mineralogical analyses of REE-mineralized Shenshan Formation phyllites with the U–Pb dating of zircon and apatite and trace element geochemical investigations. U–Pb zircon and apatite geochronology yields a protolith age of ca. 785 Ma for Shenshan Formation metamorphic rocks, consistent with mid-Neoproterozoic magmatism. REE-bearing minerals in the Shenshan Formation phyllites comprise allanite-(Ce), apatite, cerianite-(Ce), monazite-(Ce), rhabdophane-(La), rutile, Y-bearing thorianite and xenotime-(Y). Among these, apatite is the most abundant and likely the principal source of ionic REEs in the deposit. Ti-in-zircon thermometry indicates crystallization temperatures of 641–749 °C (mean ~704 °C), reflecting a prolonged magmatic–hydrothermal evolution. This extended history chiefly controlled the differentiation and redistribution of rare earth elements (REEs), thus governing their availability for subsequent supergene enrichment. Zircon-based oxygen fugacity (fO2) estimates a range from −31.4 to −9.9 (mean −17.9), consistent with reduced magmatic conditions. Trace element correlation diagrams for zircon and apatite indicate that the intrusion underwent an extensive fractional crystallization of accessory phases (zircon, monazite, apatite, titanite, rutile) and plagioclase. The distribution patterns of trace elements further suggest that the Shenshan Formation protolith formed in a continental margin arc or arc-related orogenic belt setting, with geochemical signatures characteristic of an S-type granite. The Shenshan Formation phyllites in southern Jiangxi exhibit high REE abundances and host a labile assemblage of weatherable REE-bearing minerals, providing an optimal material framework for ion-adsorption-type REE deposits and indicating substantial mineralization potential. Full article
(This article belongs to the Special Issue Advances in Granite Geochronology and Geochemistry)
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29 pages, 47085 KB  
Article
Discovery of Waimirite-(Y) in Egypt: Insights into REE Mineralization in Neoproterozoic Granite and Metasediments, Wadi Abu Rusheid, Eastern Desert
by Mustafa A. Elsagheer, Hilmy E. Moussa, Ayman E. Maurice, Paul D. Asimow, Oliver D. Wilner, Maysa M. N. Taha, Adel A. Surour and Mokhles K. Azer
Geosciences 2026, 16(3), 122; https://doi.org/10.3390/geosciences16030122 - 16 Mar 2026
Viewed by 440
Abstract
We report, for the first time, waimirite-(Y) in Egypt. This is only the third reported occurrence of this mineral in the world. This observation arose during our study of the rare earth element (REE) mineralization associated with the Neoproterozoic rare-metal granite intrusion in [...] Read more.
We report, for the first time, waimirite-(Y) in Egypt. This is only the third reported occurrence of this mineral in the world. This observation arose during our study of the rare earth element (REE) mineralization associated with the Neoproterozoic rare-metal granite intrusion in Wadi Abu Rusheid in the Eastern Desert of Egypt. The principal lanthanide and yttrium (Y) hosts in the area are waimirite-(Y) and bastnäsite-(Ce) in leucogranite and bastnäsite-(Y) in adjacent metasedimentary country rock. The leucogranite is a strongly fractionated, metaluminous to weakly peraluminous (A/CNK = 0.98–1.03), medium- to high-K calk-alkaline I-type granite. The metasediments are composed of upper greenschist to lower amphibolite-grade biotite schists with variable amounts of amphibole, graphite, and garnet. Leucogranite contains accessory Li-bearing mica, garnet, zircon, fluorite, and columbite in addition to the REE minerals. It is enriched by three orders of magnitude relative to primitive mantle in Li, Rb, Th, Ta, Nb, Pb, U, and Sn; relative to these highly enriched elements the concentrations of Sr, Ba, Ga, Zr, Hf, and Y are notably low. The REE patterns of most samples show strong enrichment in heavy relative to light REE but occasional samples have light REE-enriched patterns controlled by accessory REE minerals, and all display strong negative Eu anomalies (Eu/Eu* ≤ 0.05). The whole-rock chemistry of the metasedimentary units are different; relative to average upper continental crust they show enrichments of one to two orders of magnitude in Li, Rb, Pb, Sn, Cs, and sometimes Cr and Zn. The REE patterns of the metasedimentary units are nearly flat, with some samples showing negative Eu anomalies. Waimirite-(Y), nominally YF3, also contains several weight percent each of Yb, Dy, and Er. The empirical formula (based on one cation) is (Y0.55Ce0.02Pr0.01Nd0.02Sm0.02Gd0.02Dy0.05Er0.04Yb0.05Th0.05Ca0.16Pb0.01)∑1.00(F2.48O0.52)∑3.00. Bastnäsite-(Ce) in leucogranite samples, nominally Ce(CO3)F, also has several weight percent each of Nd2O3 and La2O3. The REE host in metasedimentary rocks is bastnäsite-(Y), nominally Y(CO3)F, but also rich in Nd2O3 (11–19 wt.%) and La2O3 (4–14 wt.%). It is intimately associated with fluorophlogopite. The geochemical, mineralogical, and textural evidence indicates that waimirite-(Y) and bastnäsite-(Ce) in leucogranite crystallized from granite-derived F- and CO2-bearing hydrothermal fluids, whereas the source of Y for growth of the bastnäsite-(Y) in the metasedimentary rocks is unclear; the large negative Ce anomaly in bastnäsite-(Y) suggests an oxidizing supergene setting. Despite their proximity, if there is a genetic connection between the mineralization in the granite and in its country rocks, the relationship is not evident from elemental patterns or host mineralogy. Full article
(This article belongs to the Section Geochemistry)
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19 pages, 6662 KB  
Article
Natural H2 Emanations in the Rio de la Plata Craton, First Data
by Isabelle Moretti, Alain Prinzhofer and Vincent Roche
Geosciences 2026, 16(3), 120; https://doi.org/10.3390/geosciences16030120 - 14 Mar 2026
Viewed by 588
Abstract
This study presents the first comprehensive soil gas survey across southern Uruguay’s H2 prospective terranes. A pre-field trip selection was done on the basement rock nature, as well as vegetation anomalies in subcircular depressions and fault presence. The Neoproterozoic terrane, north of [...] Read more.
This study presents the first comprehensive soil gas survey across southern Uruguay’s H2 prospective terranes. A pre-field trip selection was done on the basement rock nature, as well as vegetation anomalies in subcircular depressions and fault presence. The Neoproterozoic terrane, north of Punta del Este, and the Archean Rio de la Plata Craton, north of Montevideo, as well as along the suture zones between the two, were targeted. Our findings reveal substantial H2 concentrations, significantly outperforming many established basins worldwide. The suture zones act as critical migration conduits for H2 coming from a deeper structural level. Slightly abnormal helium signatures confirm an active, deep-sourced fluid system, particularly within the Sierra Ballena and Cordillera shear zones. The Archean Rio de la Plata Craton appears promising but has only been partially sampled and warrants further investigation. These results underscore the high potential of Uruguay as a new frontier for natural hydrogen exploration. Full article
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24 pages, 8000 KB  
Article
Petrogenesis of Epimetamorphic Rock from an Ion-Adsorption-Type REE Deposit in Ningdu County, Southern Jiangxi, China: Contraints from U–Pb Geochronology and the Geochemistry of Zircon and Apatite
by Wei Wan, Huihu Fan, Dehai Wu, Fuyong Qi, Zhenghui Chen, Shuilong Wang, Guangming Xu and Bimin Zhang
Minerals 2026, 16(3), 283; https://doi.org/10.3390/min16030283 - 9 Mar 2026
Viewed by 382
Abstract
In recent years, an ion-adsorption type REE deposit has been discovered for the first time in the weathering crust of epimetamorphic rocks in Ningdu County, Jiangxi Province, which provides a new idea for the exploration of ion-adsorption-type REE deposits. However, most previous studies [...] Read more.
In recent years, an ion-adsorption type REE deposit has been discovered for the first time in the weathering crust of epimetamorphic rocks in Ningdu County, Jiangxi Province, which provides a new idea for the exploration of ion-adsorption-type REE deposits. However, most previous studies on the ore-forming parent rocks of ion-adsorption-type REE deposits have focused on granites and volcanic rocks, while studies on epimetamorphic rocks remain extremely scarce. In this paper, petrographic analysis of epimetamorphic rocks, LA-ICP-MS U–Pb dating and trace element analysis of zircon and apatite were conducted on the metamorphic tuff from the Kuli Formation in Ningdu County, Jiangxi Province, so as to constrain the formation age and tectonic dynamic setting of the rock mass, investigate the petrogenesis and material source of the rock mass, and reveal the metallogenic potential of the rock mass. The results of zircon and apatite U–Pb dating show that the protolith of the metamorphic tuff from the Kuli Formation formed at ca. 770 Ma, representing a product of mid-Neoproterozoic magmatic activity. The protolith restoration of metamorphic rocks suggests that the protolith of the metamorphic tuff from the Kuli Formation is magmatic rock. The estimated results of zircon Ti thermometry indicate that the magmatic crystallization temperature ranges from 623 to 723 °C, with an average value of approximately 696 °C, and the calculated zircon oxygen fugacity values vary from −18.7 to −9.4, with an average of −13.8, implying that the rock formed under conditions of relatively low temperature and high oxygen fugacity. The correlation diagrams of trace elements and element ratios in zircon and apatite reveal that the magmatic evolution involved extensive fractional crystallization of minerals such as zircon, monazite, apatite, titanite, rutile, and plagioclase during the formation of the rock mass. The discrimination diagrams of trace elements in zircon and apatite demonstrate that the metamorphic tuff from the Kuli Formation was formed in a continental margin arc or arc-related orogenic belt, and the magmatic source is characterized by crust–mantle mixing. Combined with previous research findings on regional tectonic-magmatic activities, it can be concluded that the metamorphic tuff from the Kuli Formation was formed in a tectonic setting of back-arc extension and intra-arc rifting caused by the rollback of the subducting oceanic slab. The upwelling of the asthenospheric mantle induced the partial melting of arc-derived sediments in the continental crust, which was subsequently mixed with mantle-derived magma, ultimately generating the parent magma of the metamorphic tuff. The metamorphic tuff from the Kuli Formation in Ningdu County, Jiangxi Province, has high REE abundance and relatively easily weathered REE mineral assemblages, which can provide sufficient material sources for ion-adsorption REE mineralization and have a great metallogenic potential for ion-adsorption REE deposits. Full article
(This article belongs to the Special Issue Advances in Granite Geochronology and Geochemistry)
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29 pages, 21139 KB  
Article
Composition of Chlorite as a Proxy for Fluid Evolution and Gold Precipitation Mechanisms in the Jinshan Gold Deposit, Dexing District, South China
by Danli Wang, Tao Zhang, Minjuan Zhou, Shaohao Zou, Xilian Chen, Deru Xu, Yongwen Zhang and Cui Yang
Minerals 2026, 16(3), 269; https://doi.org/10.3390/min16030269 - 28 Feb 2026
Viewed by 376
Abstract
The physicochemical controls on gold precipitation in orogenic gold deposits remain poorly constrained, with traditional fluid inclusion and isotopic studies often yielding ambiguous results due to overprinting or incomplete records. This study addresses this challenge using chlorite—a sensitive mineral proxy for fluid conditions—as [...] Read more.
The physicochemical controls on gold precipitation in orogenic gold deposits remain poorly constrained, with traditional fluid inclusion and isotopic studies often yielding ambiguous results due to overprinting or incomplete records. This study addresses this challenge using chlorite—a sensitive mineral proxy for fluid conditions—as a quantitative sensor in the Jinshan orogenic gold deposit (>200 t Au) of the Jiangnan orogenic belt, South China. Hosted in Neoproterozoic phyllite within NE–NNE-trending ductile–brittle shear zones, Jinshan features auriferous quartz–polymetallic sulfide veins with prominent chlorite alteration. Integrating high-resolution SEM-EPMA analyses of multi-generational chlorite with thermodynamic modeling, we reconstruct the temporal evolution of temperature, oxygen fugacity (fO2), pH and sulfur fugacity (fS2) during ore formation. Four paragenetic stages are identified: Stage 1 (ankerite–quartz), Stage 2 (pyrite–arsenopyrite–quartz), Stage 3 (quartz–gold–polymetallic sulfide), and Stage 4 (chlorite–carbonate–quartz). Electron microprobe analysis reveals that the chlorite composition changes from Fe-rich chamosite (Stage 2) to Mg-rich clinochlore (Stage 3) and then to Fe-rich chamosite (Stage 4). Chlorite from Stage 2 (Chl-1) formed metasomatically at low fluid/rock ratios, while Stage 3 and 4 chlorites (Chl-2 and Chl-3) precipitated directly from higher fluid/rock ratio fluids. Chlorite compositions record a critical Stage 2–3 transition involving cooling from ~320 °C to ~260 °C, reduction (log fO2 from −33.6 to −39.7), and alkalinization, and sulfur fugacity remained stable within a narrow range (log fS2 = −13.6 to −8.0), followed in Stage 4 by minor reheating to ~280 °C, re-acidification, and a slight rebound in oxygen fugacity. Thermodynamic simulations reveal that the destabilization of Au(HS)2 complexes, primarily driven by the synergistic effects of cooling, pH increase, and decreasing oxygen fugacity, triggered gold precipitation during the main ore stage. Results demonstrate that abrupt cooling coupled with fluid alkalinization and reduction exerted the dominant control on gold precipitation in Jinshan, resolving long-standing debates on ore-forming mechanisms and highlighting chlorite as a robust quantitative sensor for fluid evolution. Full article
(This article belongs to the Special Issue Gold Deposits: From Primary to Placers and Tailings After Mining)
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39 pages, 31758 KB  
Review
Tectonics and Metallogeny of the Neoproterozoic Paraguay Belt Gold Province, Western Brazil
by Pedro Maciel de Paula Garcia, Weslley Guimarães Silva, Willian Valentin Coqueiro Sanches, Mauro César Geraldes, Cláudia do Couto Tokashiki and Victor Gabriel Moreira de Arruda
Minerals 2026, 16(3), 246; https://doi.org/10.3390/min16030246 - 27 Feb 2026
Viewed by 1222
Abstract
The Neoproterozoic Paraguay Belt (western Brazil), formed by the Brasiliano/Pan-African Orogenic Cycle during Western Gondwana amalgamation, hosts tens of gold occurrences and deposits. This review provides new insights into the metallogeny and tectonics of the Paraguay Belt Gold Province, based on previous and [...] Read more.
The Neoproterozoic Paraguay Belt (western Brazil), formed by the Brasiliano/Pan-African Orogenic Cycle during Western Gondwana amalgamation, hosts tens of gold occurrences and deposits. This review provides new insights into the metallogeny and tectonics of the Paraguay Belt Gold Province, based on previous and new data on stratigraphy, structural geology, metamorphism, hydrothermal alteration, and gold grades. The mineralizations correspond to turbidite-hosted orogenic gold systems, with quartz veins cutting metasedimentary rocks with minor metavolcanics. A six-phase tectonic–metallogenic evolution model is proposed. The early stages correspond to glaciolacustrine deposition in a rift that evolved into a passive margin and then into a foreland basin, with glaciomarine sediments. Late sedimentation corresponds to glacial-to-post-glacial shallow marine units in the foreland. The orogeny progressed with cratonic collisions, resulting in three deformation (two compressional and one extensional) and three metamorphic (regional, dynamic, and contact) phases. The Au mineralization results from metamorphic fluids that transported metals from the metasedimentary pile and deposited them in reactive rocks (rich in magnetite or organic carbon). Gold occurs in sulfide-rich (pyrite and galena) veins and hydrothermal alteration zones. The metallotects and structural controls highlighted here are useful tools for prospecting gold in the Paraguay Belt and similar geological terranes. Full article
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15 pages, 4686 KB  
Article
Petrogenesis of Quartz Diorite in the Datian Complex, Western Yangtze Block: Evidence from U-Pb Geochronology, Geochemistry, and Sr-Nd-Hf Isotopes
by Jian Yao, Youliang Chen, Yu Wu, Jing Zhao, Luyu Huang and Minghui Yin
Appl. Sci. 2026, 16(3), 1647; https://doi.org/10.3390/app16031647 - 6 Feb 2026
Viewed by 400
Abstract
This study presents integrated zircon U-Pb geochronology, whole-rock geochemistry, and Sr-Nd-Hf isotopic investigations of quartz diorite and gneissic quartz diorite from the Datian Complex along the western Yangtze Block, elucidating their petrogenesis and tectonic implications. Key findings reveal: (1) The crystallization ages of [...] Read more.
This study presents integrated zircon U-Pb geochronology, whole-rock geochemistry, and Sr-Nd-Hf isotopic investigations of quartz diorite and gneissic quartz diorite from the Datian Complex along the western Yangtze Block, elucidating their petrogenesis and tectonic implications. Key findings reveal: (1) The crystallization ages of the Datian Complex (~770–755 Ma) record episodic magmatic activity over a ~16 Ma period, indicating a multi-stage tectonic evolution; (2) Both rock types exhibit intermediate SiO2 (57–64.58 wt.%), high Al2O3 (15.44–17.80 wt.%), and MgO (2.18–3.67 wt.%; Mg# = 47.41–52.65) with calc-alkaline signatures (Na2O/K2O = 1.14–2.65), coupled with adakitic traits including pronounced LREE/HREE fractionation (LaN/YbN = 3.83–26.4), negative Eu anomalies (δEu = 0.61–1.05), elevated Sr (372–701 ppm), and Sr/Y ratios (24.6–56.2), collectively classifying the complex as high-Si adakite; (3) The isotopic homogeneity (whole-rock Sr-Nd: 87Sr/86Sr(i) = 0.7038–0.7048, εNd(t) = −1.5 to–3.8; zircon Hf: εHf(t) = 1.24–6.88) supports a two-stage petrogenetic model involving partial melting of subducted oceanic slab, followed by mantle wedge metasomatism during magma ascent. These results position the Datian Complex as a Neoproterozoic arc-related adakitic magmatic system within the active continental margin of the Yangtze Block. Full article
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30 pages, 7342 KB  
Article
Petrogenesis of the Monzonite in the Jiashan Area, Northern Jiangsu, China: Constraints from Whole-Rock Geochemistry and Zircon U–Pb Ages and Lu–Hf Isotopes
by Tao Kang, Duolikun Hainaer, Peng Zhu, Wei-Guo Zhang, Bostan Damla, Zhe-Ming Cao and Xiao-Qiang Liu
Minerals 2026, 16(2), 137; https://doi.org/10.3390/min16020137 - 27 Jan 2026
Viewed by 528
Abstract
Recent discoveries of fluorite–barite deposits in the Donghai–Linshu area in northern Jiangsu Province, China, underscore the region’s mineral potential, yet detailed geological investigations remain limited. In this study, we examined monzonite and quartz monzonite from drill cores in the Jiashan mining area using [...] Read more.
Recent discoveries of fluorite–barite deposits in the Donghai–Linshu area in northern Jiangsu Province, China, underscore the region’s mineral potential, yet detailed geological investigations remain limited. In this study, we examined monzonite and quartz monzonite from drill cores in the Jiashan mining area using petrography, U–Pb zircon dating, zircon trace element geochemistry, whole-rock geochemistry, and zircon Lu–Hf isotopes. Laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) zircon U–Pb analyses were conducted to constrain the crystallization ages of the monzonite (127.06 ± 0.54 Ma and 126.83 ± 0.75 Ma) and quartz monzonite (127.2 ± 0.5 Ma and 128.59 ± 0.62 Ma) to the Early Cretaceous, marking a significant magmatic event. Many of the zircons contain inherited Neoproterozoic cores (718–760 Ma and 800–860 Ma), indicating the assimilation of deep crustal materials of this age. The monzonite is metaluminous, with moderate SiO2 (61.61–62.41 wt.%), high alkalis (Na2O + K2O = 7.48–7.92 wt.%), and A/CNK = 0.72–0.91. The quartz monzonite has higher SiO2 (66.26–68.18 wt.%) and alkalis (8.32–9.33 wt.%). Both rock types exhibit similar trace and rare earth element patterns: enrichment in large-ion lithophile and light rare earth elements, depletions in Nb, Ta, and Ti, no significant Zr-Hf depletion, and weak negative Eu anomalies (δEu ≈ 0.84–1.00). Their low Zr + Nb + Ce + Y contents, Ga/Al ratios, and TFeO/MgO ratios indicate that they have an I-type granite affinity. The Early Cretaceous zircons have highly negative εHf(t) values (−33.7 to −23.5) and ancient two-stage model ages (2622–3247 Ma), which are consistent with derivation from Archean crust. The inherited Neoproterozoic zircons have younger Paleo–Mesoproterozoic TDM2 ages. The evidence suggests that both intrusions were mainly generated by partial melting of ancient Archean basement, with minor mantle input. The magma generation was likely triggered by crustal anatexis induced by the underplating of mantle-derived magmas in an extensional tectonic regime, coeval with Early Cretaceous magmatism in the Sulu orogen. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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35 pages, 10330 KB  
Article
Mineral Chemistry, Whole-Rock Characterization, and EnMap Hyperspectral Data Analysis of Granitic Rocks of the Nubian Shield: A Case Study from Suwayqat El-Arsha District, Central Eastern Desert, Egypt
by Ahmed M. Abdel-Rahman, Bassam A. Abuamarah, Ali Shebl, Jason B. Price, Andrey Bekker and Mokhles K. Azer
Geosciences 2026, 16(1), 37; https://doi.org/10.3390/geosciences16010037 - 9 Jan 2026
Cited by 1 | Viewed by 821
Abstract
Gabal (G.) Suwayqat El-Arsha contains two distinct phases of granitoids: I-type granodiorite and A-type monzogranite. Both of them experienced intense fractional crystallization that affected plagioclase, alkali feldspar, quartz, and, to a lesser degree, ferromagnesian minerals. EnMAP hyperspectral data were used to discriminate between [...] Read more.
Gabal (G.) Suwayqat El-Arsha contains two distinct phases of granitoids: I-type granodiorite and A-type monzogranite. Both of them experienced intense fractional crystallization that affected plagioclase, alkali feldspar, quartz, and, to a lesser degree, ferromagnesian minerals. EnMAP hyperspectral data were used to discriminate between the different granitoid types through spectral analysis, using various techniques, including the Sequential Maximum Angle Convex Cone (SMACC) method. Granodiorite has high SiO2 (68.21–71.44 wt%), Al2O3 (14.29–14.92 wt%), Fe2O3 (1.99–3.32 wt%), and CaO (2.34–3.87 wt%), whereas monzogranite has even higher SiO2 (73.58–75.87 wt%) and K2O (4.28–4.88 wt%). Both granodiorite and monzogranite exhibit calc-alkaline, peraluminous to metaluminous, and medium- to high-K characteristics, with attendant enrichment of light REE and LILE and depletion of heavy REE and HFSE. A negative Eu anomaly may indicate early plagioclase fractionation, especially in the monzogranite. The I-type granodiorite is likely derived from a high-K, mafic protolith that partially melted during lithospheric delamination, leading to severe fractional crystallization in the upper crust in a post-collisional environment. In contrast, the monzogranite exhibits A-type characteristics and was likely emplaced in an anorogenic setting. Both granites were affected by several episodes of hydrothermal alteration, resulting in silicification, kaolinitization, sericitization, and chloritization. The intrusions studied here exhibit key similarities with those in the Wadi El-Hima area, including tectonic setting, petrogenetic type, Neoproterozoic age (Stage I collisional: ca. 650–620 Ma; Stage II post-collisional: ca. 630–590 Ma), and mineralogical assemblages (notably two-mica granites). These correlations suggest that both suites form part of a regionally extensive batholith composed of I- and A-type granites, stretching from north of the Marsa Alam Road (Umm Salatit–Homrit Waggat) southward to at least Wadi El-Hima. Full article
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19 pages, 2272 KB  
Article
Detrital Zircon U–Pb Geochronology of the Muti Formation: Implications for Provenance and Evolution of the Oman Foreland Basin
by Iftikhar Ahmed Abbasi, Muhammad Qasim, Jenan Ahmed Attar, Mohamed A. K. El-Ghali, Mohamed S. H. Moustafa and Lin Ding
Geosciences 2026, 16(1), 15; https://doi.org/10.3390/geosciences16010015 - 24 Dec 2025
Cited by 1 | Viewed by 1026
Abstract
Detrital zircon U–Pb dating from the Muti Formation sheds light on sediment sources and foreland basin development along the northeastern Arabian margin during the Late Cretaceous. The siliciclastic-rich Muti Formation was deposited in a syn-obduction foreland basin that formed as the Semail Ophiolite [...] Read more.
Detrital zircon U–Pb dating from the Muti Formation sheds light on sediment sources and foreland basin development along the northeastern Arabian margin during the Late Cretaceous. The siliciclastic-rich Muti Formation was deposited in a syn-obduction foreland basin that formed as the Semail Ophiolite advanced. Zircon age spectra from eastern (Nakhal and Sayga) and western (Murri) sections are dominated by Neoproterozoic–Cambrian ages (450–900 Ma), linked to the Pan-African orogeny and the Arabian–Nubian Shield, indicating these as the main sediment sources. The Murri section also contains older Mesoproterozoic to Archean zircons, likely recycled from the Nafun Group (part of the Huqf Supergroup), suggesting reworking of ancient Gondwanan cover sequences rather than direct input from the Indian craton. Additional Permian zircons reflect input from Arabian Plate magmatic rocks, while Jurassic–Cretaceous grains indicate material derived from the Semail Ophiolite and related arc terranes. Overall, the Muti Formation records a mixed sediment supply from the Arabian Shield, reworked Gondwanan sandstones, and ophiolitic detritus, marking the transition from a passive margin to a flexural foreland basin. The dominance of Pan-African zircon ages highlights continued recycling of Gondwanan sequences and refines models of Late Cretaceous basin evolution in northern Oman, underscoring the complex, multi-cycle nature of sedimentation in this tectonically active setting. Full article
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26 pages, 6608 KB  
Article
From Mantle to Cratonic Reactivation: Petrological Insights from Kimberlites and Lamproites of the São Francisco Craton, Brazil
by Matheus Andrade Nascimento, Debora Correia Rios, Nivea Maria Assis Magalhães and Francisco Valdir Silveira
Minerals 2026, 16(1), 19; https://doi.org/10.3390/min16010019 - 24 Dec 2025
Viewed by 545
Abstract
This study redefines the Nordestina Kimberlite Province (PKN), in the northeastern sector of the São Francisco Craton (SFC), as a composite kimberlitic–lamproitic system that hosts two genetically distinct magma types: (1) the primitive Braúna kimberlite and (2) hybridized phlogopite-rich lamproites belonging to the [...] Read more.
This study redefines the Nordestina Kimberlite Province (PKN), in the northeastern sector of the São Francisco Craton (SFC), as a composite kimberlitic–lamproitic system that hosts two genetically distinct magma types: (1) the primitive Braúna kimberlite and (2) hybridized phlogopite-rich lamproites belonging to the SFC lamproite variety. Braúna kimberlites represent an olivine-rich kimberlite sourced from a metasomatized lithospheric mantle, as reflected by its high MgO (15%–30.6%), Ni (up to 1172 ppm), and Cr (up to 2500 ppm). These geochemical signatures are consistent with a primitive melt capable of preserving diamond stability conditions. In contrast, the SFC lamproite variety exhibits strong crustal overprinting, marked by hydrothermal barite–carbonate–silica veining, cristobalite, elevated SiO2 (up to 80 wt.%), and high LOI (up to 27.5%). These features indicate significant post-magmatic alteration, felsic crust assimilation, and melt hybridization. Textural and mineralogical features found in both magma types, including olivine-phlogopite aggregates, irregular zoning, and disequilibrium assemblages, suggest magma mingling between compositionally distinct melts and/or crystallization under polybaric conditions. These findings clarify long-standing classification controversies by demonstrating that PKN magmatism is not represented by a single rock type but instead spans a continuum spectrum from primitive kimberlite to strongly hybridized lamproite. Regionally, the data reveal that PKN magmatism reflects Paleoproterozoic mantle metasomatism reactivated during Neoproterozoic tectonism. This dual-stage evolution explains the contrasting degrees of primitiveness and hybridization melt signatures observed across the province. Full article
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