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Article

15 Citations

5,375 Views

18 Pages

2-Unsubstituted Imidazole N-Oxides as Novel Precursors of Chiral 3-Alkoxyimidazol-2-ylidenes Derived from trans-1,2-Diaminocyclohexane and Other Chiral Amino Compounds

Grzegorz Mlostoń,
Małgorzata Celeda,
Marcin Jasiński,
Katarzyna Urbaniak and ,
Przemysław J. Boratyński,
Peter R. Schreiner and
Heinz Heimgartner
+ 2 authors+ 0 author

Molecules2019, 24(23), 4398;https://doi.org/10.3390/molecules24234398

2 December 2019

‘Desymmetrization’ of trans-1,2-diaminocyclohexane by treatment with α,ω-dihalogenated alkylation reagents leads to mono-NH₂ derivatives (‘primary-tertiary diamines’). Upon reaction with formaldehyde, these product...

(This article belongs to the Special Issue Stereochemistry in Action)

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Article

7 Citations

4,053 Views

16 Pages

Synthesis, Selected Transformations, and Biological Activity of Alkoxy Analogues of Lepidilines A and C

Grzegorz Mlostoń,
Małgorzata Celeda,
Wiktor Poper,
Mateusz Kowalczyk and ,
Katarzyna Gach-Janczak,
Anna Janecka and
Marcin Jasiński
+ 2 authors+ 0 author

Materials2020, 13(18), 4190;https://doi.org/10.3390/ma13184190

21 September 2020

Condensation of diacetyl monooxime with formaldimines derived from alkoxyamines in glacial acetic acid at room temperature leads to corresponding 2-unsubstituted imidazole N-oxides bearing an alkoxy substituent at the N(1) atom of the imidazole ring....

(This article belongs to the Special Issue Research of Organic Molecules and Materials for Biological Application)

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