Search Results (2)

Determination of airflow rates is an inevitable part of the energy-efficient control of ventilation systems. To achieve efficient control, the flowmeters used must be suitably accurate and create minimum disturbance to the airflow. In this study, we evaluate the quantitative performance characteristics of an innovative micro-electromechanical systems (MEMS) flowmeter, a so-called Elastic Filament Velocimetry (EFV), in ventilation ducts. Two versions of the EFV-sensor, i.e., an 11-nanoribbon and a 22-nanoribbon variety, were evaluated in laboratory studies. The results indicate that the 11-nanoribbon sensor is more suitable for air velocity measurements in ducts than the 22-nanoribbon sensor. The 11-nanoribbon sensor can measure air velocities from 0.3 m/s. The maximum variation of the sensor-output is 3% for velocities over 0.5 m/s. Calibration models have been developed for the 11-nanoribbon sensor. The error due to model calibration is lower than ±5% for velocities over 0.6 m/s. Moreover, laboratory studies were performed to investigate the airflow disturbance in a duct system due to the EFV sensor. The results were compared with the corresponding disturbance caused by two different types of self-averaging probes. At a bulk velocity of 3 m/s, the self-averaging probes introduced a greater pressure drop by at least 50% compared to the EFV-sensor. Full article

In this study, a new hybrid sensor was developed using titanium oxide nanoparticles (TiO₂-NPs) and nafion as an anchor agent on a glassy carbon electrode (GCE/TiO₂-NPs-nafion) to detect efavirenz (EFV), an anti-HIV medication. TiO₂-NPs was synthesized using Eucalyptus globulus leaf extract and characterized using ultraviolet–visible spectroscopy (UV–VIS), scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy-dispersive spectroscopy (EDS). The electrochemical and sensing properties of the developed sensor for EFV were assessed using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The current response of GCE/TiO₂-NPs-nafion electrode towards the oxidation of EFV was greater compared to the bare GCE and GCE/TiO₂-NPs electrodes. A linear dynamic range of 4.5 to 18.7 µM with 0.01 µM limit of detection was recorded on the electrode using differential pulse voltammetry (DPV). The electrochemical sensor demonstrated good selectivity and practicality for detecting EFV in pharmaceuticals (EFV drugs) with excellent recovery rates, ranging from 92.0–103.9%. The reactive sites of EFV have been analyzed using quantum chemical calculations based on density functional theory (DFT). Monte Carlo (MC) simulations revealed a strong electrostatic interaction on the substrate-adsorbate (GCE/TiO₂-NPs-nafion-EFV) system. Results show good agreement between the MC computed adsorption energies and the experimental CV results for EFV. The stronger adsorption energy of nafion onto the GCE/TiO₂-NPs substrate contributed to the catalytic role in the signal amplification for sensing of EFV. Our results provide an effective way to explore the design of new 2D materials for sensing of EFV, which is highly significant in medicinal and materials chemistry. Full article