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14 Results Found

  • Article
  • Open Access
58 Citations
11,150 Views
8 Pages

Catalytic Transfer Hydrogenation of Biobased HMF to 2,5-Bis-(Hydroxymethyl)Furan over Ru/Co3O4

  • Ting Wang,
  • Junhua Zhang,
  • Wenxing Xie,
  • Yanjun Tang,
  • Daliang Guo and
  • Yonghao Ni

21 March 2017

2,5-Bis-(hydroxymethyl)furan (BHMF) is an important biomass-based platform chemical that can be derived from the hydrogenation of biomass-based 5-hydroxymethylfurfural (HMF). In this paper, the formation of BHMF from HMF via the catalytic transfer hy...

  • Feature Paper
  • Article
  • Open Access
7 Citations
3,361 Views
20 Pages

19 November 2022

Synthesis of 2,5-bis(hydroxymethyl)furan (BHMF) by selective 5-hydroxymethylfurfural (HMF) hydrogenation is ecofriendly and industrially important since HMF is obtained from renewable sources, and BHMF is a raw material used for production of biodegr...

  • Feature Paper
  • Article
  • Open Access
11 Citations
2,860 Views
15 Pages

17 February 2023

Aerobic oxidation of bio-sourced 2,5-bis(hydroxymethyl)furan (BHMF) to 2, 5-furandicarboxylic acid (FDCA), a renewable and green alternative to petroleum-derived terephthalic acid (TPA), is of great significance in green chemicals production. Herein,...

  • Article
  • Open Access
1,512 Views
22 Pages

2,5-bis(hydroxymethy)lfuran (BHMF), a renewable compound with extensive industrial applications, can be obtained by selective hydrogenation of the C=O group of 5-hydroxymethylfurfural (HMF), a platform molecule derived from lignocellulosic biomass. I...

  • Article
  • Open Access
23 Citations
5,568 Views
12 Pages

7 December 2018

Catalytic reduction of 5-hydroxymethylfurfural (HMF), deemed as one of the key bio-based platform compounds, is a very promising pathway for the upgrading of biomass to biofuels and value-added chemicals. Conventional hydrogenation of HMF is mainly c...

  • Article
  • Open Access
29 Citations
4,238 Views
15 Pages

7 December 2021

The establishment of lignocellulosic biorefineries is dependent on microorganisms being able to cope with the stressful conditions resulting from the release of inhibitory compounds during biomass processing. The yeast Kluyveromyces marxianus has bee...

  • Article
  • Open Access
29 Citations
4,331 Views
13 Pages

29 January 2020

A series of biobased phosphorus flame retardants has been prepared by converting starch-derived bis-2,5-(hydroxymethyl)furan to the corresponding diacrylate followed by Michael addition of phosphite to generate derivatives with phosphorus moieties at...

  • Communication
  • Open Access
24 Citations
4,573 Views
13 Pages

13 August 2023

In this paper we produced a bio-based polyether-polyurethane foam PU1 through the prepolymer method. The prepolymer was obtained by the reaction of PEG 400 with L-Lysine ethyl ester diisocyanate (L-LDI). The freshly prepared prepolymer was extended w...

  • Communication
  • Open Access
10 Citations
3,727 Views
10 Pages

Two Possible Side Reaction Pathways during Furanic Etherification

  • Wenting Fang,
  • Hualei Hu,
  • Zhongsen Ma,
  • Lei Wang and
  • Yajie Zhang

8 September 2018

The revealing mechanism of side reactions is crucial for obtaining theoretical yield in industrialization when 2,5-bis(methoxymethyl)furan (BMMF) yield is above 95%. By-products catalyzed by the conventional ZSM-5 (C-ZSM-5) and hierarchical porous ZS...

  • Review
  • Open Access
26 Citations
4,663 Views
15 Pages

8 February 2022

The implementation of cost-effective and sustainable biorefineries to substitute the petroleum-based economy is dependent on coupling the production of bioenergy with high-value chemicals. For this purpose, the US Department of Energy identified a gr...

  • Article
  • Open Access
5 Citations
4,172 Views
14 Pages

14 December 2021

Due to growing environmental issues, research on carbon dioxide (CO2) use is widely conducted and efforts are being made to produce useful materials from biomass-derived resources. However, polymer materials developed by a combined strategy (i.e., bo...

  • Article
  • Open Access
4 Citations
3,569 Views
14 Pages

High Tg, Bio-Based Isosorbide Methacrylate Resin Systems for Vat Photopolymerization

  • Xi Chu,
  • Jianwei Tu,
  • Heather R. Berensmann,
  • John J. La Scala and
  • Giuseppe R. Palmese

24 April 2023

The use of isosorbide-derived polymers has garnered significant attention in recent decades as a high-performance, renewable material sourced from biomass. Of particular interest is isosorbide methacrylate, which possesses low viscosity (<500 cps)...

  • Article
  • Open Access
3 Citations
1,022 Views
17 Pages

Oil Spill Recovery of Petroleum-Derived Fuels Using a Bio-Based Flexible Polyurethane Foam

  • Fabrizio Olivito,
  • Zul Ilham,
  • Wan Abd Al Qadr Imad Wan-Mohtar,
  • Goldie Oza,
  • Antonio Procopio and
  • Monica Nardi

17 July 2025

In this study, we tested a flexible polyurethane (PU) foam, synthesized from bio-based components, for the removal of petroleum-derived fuels from water samples. The PU was synthesized via the prepolymer method through the reaction of PEG 400 with L-...

  • Article
  • Open Access
8 Citations
4,327 Views
23 Pages

Catalytic Transfer Hydrogenation and Acid Reactions of Furfural and 5-(Hydroxymethyl)furfural over Hf-TUD-1 Type Catalysts

  • Margarida M. Antunes,
  • Andreia F. Silva,
  • Carolina D. Bernardino,
  • Auguste Fernandes,
  • Filipa Ribeiro and
  • Anabela A. Valente

27 November 2021

Heterogeneous catalysis, which has served well the petrochemical industry, may valuably contribute towards a bio-based economy by sustainably enabling selective reactions to renewable chemicals. Carbohydrate-containing matter may be obtained from var...