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Sustainable Thermochemical Conversion of Organic Solid Waste

A special issue of Sustainability (ISSN 2071-1050). This special issue belongs to the section "Waste and Recycling".

Deadline for manuscript submissions: 30 June 2025 | Viewed by 2759

Special Issue Editor


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Guest Editor
School of Ecology and Environment, Zhengzhou University, Zhengzhou 450001, China
Interests: thermochemical conversion of biomass and plastic waste into liquid fuels and chemicals, including pyrolysis, gasification, hydro-pyrolysis
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Special Issue Information

Dear Colleagues,

Organic solid waste (OSW) refers to solid waste containing organic matter, e.g., domestic waste, agricultural waste, industrial waste, etc. Traditional disposal methods include landfill and incineration, but these methods have problems with environmental pollution and resource waste. There will also be a lot of excess carbon dioxide emissions, which will have a huge impact on global warming and climate change. Therefore, the development of a sustainable use of OSW technology becomes particularly important. As a result, the annual global generation of OSW has been threateningly increasing, which contributes to severe issues in appropriate waste conversion and utilization.

The organic solid waste thermochemical conversion process is a technology that converts OSW into renewable energy or high-value chemicals through a thermochemical reaction. Through the application of high temperatures and catalysts, the OSW is decomposed into gas, liquid, and solid products to achieve efficient utilization of resources and harmless treatment of waste.

The core of the OSW thermochemical conversion process is the pyrolysis reaction and catalytic conversion. The pyrolysis reaction refers to the process of decomposing organic solid waste into gas, liquid, and solid products at high temperatures. In this process, the organic matter in the OSW is cracked, dehydrogenated, and deoxygenated to produce flammable gas and liquid fuel. At the same time, it will also produce a part of the solid residue.

The utilization of OSW not only contributes to reducing pollution but also provides an alternative way of generating bio-energy and environmentally friendly products. This Special Issue aims to attract works of scientific interest to promote the conversion and utilization of OSW.

Dr. Changsen Zhang
Guest Editor

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Keywords

  • organic solid waste
  • biomass
  • waste plastic
  • scrap tire
  • biofuels
  • high-valued chemical
  • thermochemical conversion
  • biorefining
  • catalyst

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Published Papers (2 papers)

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Research

16 pages, 2149 KiB  
Article
Rapid Adsorption of Ammonium on Coffee Husk and Chicken Manure-Derived Biochars: Mechanisms Unveiled by Chemical Speciation, Physical, and Spectroscopic Approaches
by Everton Geraldo de Morais, Carlos Alberto Silva, Suduan Gao, Leônidas Carrijo Azevedo Melo, Pedro Antônio Namorato Benevenute, Bruno Cocco Lago, Jéssica Cristina Teodoro and Luiz Roberto Guimarães Guilherme
Sustainability 2025, 17(4), 1616; https://doi.org/10.3390/su17041616 - 15 Feb 2025
Cited by 1 | Viewed by 764
Abstract
Biochars have emerged as a sustainable technology for converting waste into high-value, stable carbon products. Depending on its properties, biochar can retain various elements, including nitrogen (N) as ammonium (N-NH4+). This study aimed to evaluate the rapid retention of N-NH [...] Read more.
Biochars have emerged as a sustainable technology for converting waste into high-value, stable carbon products. Depending on its properties, biochar can retain various elements, including nitrogen (N) as ammonium (N-NH4+). This study aimed to evaluate the rapid retention of N-NH4+ in biochars produced from coffee husk (CH) and chicken manure (CM) at different pyrolysis temperatures (PTs) (300 °C, 400 °C, and 900 °C) and investigate the mechanisms involved. A rapid N-NH4+ adsorption experiment was conducted, in which an NH4Cl solution was passed through the biochars. The following analyses were performed: cation exchange capacity (CEC), surface area, pore volume and size, total N content, N retention, infrared analysis (ATR-FTIR), and leachate solution analysis, followed by chemical speciation using Visual MINTEQ software. The results indicated that different mechanisms were involved in rapid N-NH4+ retention. In CH-derived biochars produced at 300 °C, N-NH4+ retention occurred primarily through electrostatic interactions with negative charges (CEC), as confirmed by ATR-FTIR analysis. In CM-derived biochars produced at 400 °C, N-NH4+ retention was mainly through the formation of struvite (NH4MgPO4·6H2O), as confirmed by chemical speciation of leachate solution in Visual MINTEQ. In CH-derived biochars produced at 900 °C, N-NH4+ ions were trapped in the pores of the charred matrix due to the increased biochar surface area, pore volume, and decreased pore size. The biochars studied proved effective in retaining N-NH4+ through different mechanisms, suggesting that biochars can enhance rapid N retention and reduce N leaching, potentially serving as a source of N for crops. Full article
(This article belongs to the Special Issue Sustainable Thermochemical Conversion of Organic Solid Waste)
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19 pages, 3108 KiB  
Article
Selective Phenolics Recovery from Aqueous Residues of Pyrolysis Oil through Computationally Designed Green Solvent
by Amna Qaisar, Lorenzo Bartolucci, Rocco Cancelliere, Nishanth G. Chemmangattuvalappil, Pietro Mele, Laura Micheli and Elisa Paialunga
Sustainability 2024, 16(17), 7497; https://doi.org/10.3390/su16177497 - 29 Aug 2024
Cited by 1 | Viewed by 1663
Abstract
Leveraging advanced computational techniques, this study introduces an innovative hybrid computational-experimental approach for the recovery of hydroquinone and p-benzoquinone from the aqueous residue of pyrolysis oil derived from spent coffee grounds, offering a sustainable pathway for value-added chemicals recovery. A screw-type reactor operating [...] Read more.
Leveraging advanced computational techniques, this study introduces an innovative hybrid computational-experimental approach for the recovery of hydroquinone and p-benzoquinone from the aqueous residue of pyrolysis oil derived from spent coffee grounds, offering a sustainable pathway for value-added chemicals recovery. A screw-type reactor operating within the temperature range of 450–550 °C was utilized for the conversion of spent coffee grounds into pyrolysis oil. A comprehensive characterization of the bio-oil was conducted using gas chromatography–mass spectroscopy (GC–MS) and high-performance liquid chromatography (HPLC), revealing hydroquinone and benzoquinone as the predominant phenolic compounds. Employing computer-aided molecular design (CAMD), we identified 1-propanol as an optimal green solvent for the selective extraction of quinones, offering superior process efficiency and economic viability. Notably, the extraction efficiency achieved for hydroquinone and p-benzoquinone reached up to 23.38 g/L and 14.39 g/L, respectively, from the aqueous fraction of pyrolysis oil at 550 °C, with an extraction time of 1 h. Techno-economic analysis indicated a robust rate of return of 20% and a payback period of 1.1 years for the separation process. This study underscores the critical role of a hybrid experimental-modelling approach in developing sustainable processes for the valorization of biowaste into valuable materials. Full article
(This article belongs to the Special Issue Sustainable Thermochemical Conversion of Organic Solid Waste)
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