Quantum Beam Science

This article explores the utilization of cathodic-arc deposition Cr-Al overlay coatings as oxidation protection for Ti-Al-Nb intermetallic alloys. The primary objective is to investigate PVD Al-Cr coatings deposited via cathodic-arc deposition without subsequent vacuum annealing. The microstructure, phase, and chemical composition of the coatings were characterized using scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction analysis. Isothermal exposure of samples in a laboratory air furnace was conducted, revealing the efficacy of Cr-Al coatings in protecting the Ti49-11Al-40Nb-1.5Zr-0.75V-0.75Mo-0.2Si (mass%) intermetallic alloy VTI-4 against oxidation. The findings highlight that the as-deposited coatings possess a layered structure and contain Al-Cr intermetallics. Post-exposure to the furnace without prior vacuum annealing results in coatings exhibiting a porous microstructure, raising concerns regarding oxidation protection. This investigation of Cr-Al coatings on a VTI-4 alloy substrate yields valuable insights into their nanolaminate structure and challenges associated with aluminum droplet fractions. The proposed additional vacuum heat treatment at 650 °C for 500 h effectively homogenizes the coating, leading to predominant Cr₂Al and Ti-Al phases. Additionally, the formation of diffusion layers at the “coating–substrate” interface and the presence of oxide barriers contribute to the coatings’ heat resistance. Our research introduces possibilities for tailoring coating properties for specific high-temperature applications in aerospace, energy, or industrial contexts. Further refinement of the heat treatment process offers the potential for developing advanced coatings with enhanced performance characteristics. Full article

Polarisation analysis for neutron scattering experiments is a powerful tool suitable for a wide variety of studies, including soft-matter samples which have no bulk magnetic behaviour and/or a significant hydrogen content. Here, we describe a method to leverage the versatility and spin-polarisation capabilities of a cold triple-axis spectrometer to perform a measurement to separate coherent and incoherent neutron scattering for a non-magnetic sample in the quasielastic neutron scattering (QENS) regime. Such measurements are complementary to unpolarised QENS measurements, which may typically be performed on a backscattering or time-of-flight spectrometer instrument where polarisation analysis can be significantly more difficult to achieve, and utilise the strengths of each type of instrument. Full article

MgB₂ represents a hexagonal superconductive material renowned for its straightforward composition, which has facilitated the development of cost-effective practical wires. Its capacity to function at temperatures as low as liquid hydrogen (LH₂) has made it a prominent candidate as wire material for the coils of next-generation fusion reactors. Much like other superconducting wires, a prevalent issue arises when these wires are employed in coils, wherein electromagnetic forces induce tensile stress and strain within the wire. This, in turn, diminishes the critical current, which is the maximum current capable of flowing within the generated magnetic field and strain. The techniques and methods for accurately measuring the actual strain on the filaments are of paramount importance. While strain measurements have been conducted with synchrotron radiation and neutrons for other practical wires in the past, no such measurements have been undertaken for MgB₂. Presumably, this lack of measurement is attributed to its relatively greater thickness, making it less suitable for synchrotron radiation measurements. Additionally, the high absorption cross-section of the included boron-10 poses challenges in obtaining elastic scattering data for neutron measurements. In response, we fabricated a wire enriched with boron-11, an isotope with a smaller neutron absorption cross-section. We then embarked on the endeavor to measure its strain under tensile loading using pulsed neutrons. Consequently, we succeeded in obtaining changes in the lattice constant under tensile loading through Rietveld analysis. This marks the inaugural instance of strain measurement on an MgB₂ filament, signifying a significant milestone in superconductivity research. Full article

The collective acceleration of helium ions from its residual atmosphere in the Luce diode was studied at helium pressures from 0.13 to 0.23 Pa. The energy of accelerated ions was determined from the drift velocity of the virtual cathode accelerating the ions. The number of ⁴He was determined by radioactivities of ¹³N and ³⁰P induced in h-BN and Al targets via the nuclear reactions ¹⁰B(α,n)¹³N and ²⁷Al(α,n)³⁰P. The efficiency of capturing ⁴He ions in collective acceleration from the residual helium atmosphere was estimated as 0.25%. With increasing helium pressure above 0.15 Pa, the energy of the main ion group noticeably decreased to 0.46 MeV/amu compared to the acceleration from a usual residual atmosphere (~0.6 MeV/amu); however, the probability of ion acceleration to a specific energy of up to 1.57 MeV/amu increased significantly. Such increases in the ion energy were accompanied by the appearance of the signal of the second virtual cathode 7–9 ns after the appearance of the first virtual cathode. Full article

Tensile deformation in situ neutron diffraction of an extruded AZ31 alloy was performed to validate conventional procedures and to develop new procedures for stress evaluation from lattice strains by diffraction measurements of HCP-structured magnesium alloys. Increases in the lattice strains with respect to the applied true stress after yielding largely vary among [hk.l] grains. Some [hk.l] grains have little or no increase in lattice strain, making it difficult to use the conventional procedures to determine the average phase strain by using lattice constants or by averaging several lattice strains. The newly proposed procedure of stress evaluation from the lattice strains shows very high accuracy and reliability by weighting the volume fraction of [hk.l] grains and evaluating them in many [hk.l] orientations in addition to multiplication by the diffraction elastic constant. When multiple hk.l peaks cannot be obtained simultaneously, we recommend to use the 12.1 peak for stress evaluation. The lattice strain value evaluated from the 12.1 peak shows a good linear relationship with the applied true stress for the whole deformation region. Full article

Silicon carbide junction field-effect transistors (SiC JFETs) are promising candidates as devices applicable to radiation conditions, such as the decommissioning of nuclear facilities or the space environment. We investigate the origin of the threshold volage (V_th) shift and hysteresis of differently structured SiC JFETs. A large positive V_th shift and hysteresis are observed for a depletion-type JFET with a larger depletion layer width. With changing the sweep range of the gate voltage and depletion width, the V_th shift was positively proportional to the difference between the channel depth and depletion width (channel depth–gate depletion width). By illuminating the sub-band gap light, the V_th of the irradiated depletion JFETs recovers close to nonirradiated ones, while a smaller shift and hysteresis are observed for the enhancement type with a narrower width. It can be interpreted that positive charges generated in a gate depletion layer cause a positive V_th shift. When they are swept out from the depletion layer and trapped in the channel, this gives rise to a further V_th shift and hysteresis in gamma-irradiated SiC JFETs. Full article

A diagnostic analysis of the painting depicting San Patroba che predica ai fedeli di Pozzuoli by Massimo Stanzione was carried out. The painting was completed in 1635–1637 to decorate the choir of the Cathedral of Saint Procolo in Pozzuoli (Naples, Italy). The technique of X-ray fluorescence (XRF) and multispectral imaging were applied on site to learn about the executive technique, the palette of the painting, and the restoration works, as well as understand the influence of the other painters active in Naples in that period. The results of the research are presented and discussed to draw general aspects and peculiarities of the pigments and the pictorial technique used by this important painter, as well as the restorations. Full article

Bismuth sodium titanate (BNT) thin films were deposited on Pt/SiN substrates by Sol-Gel spin coating technique and annealed under O₂ atmosphere. The microstructural, structural, and electrical properties of the obtained film were investigated. Electron microscopy scans and atomic force microscopy micrographs were used to analyze the microstructure of the films. Furthermore, energy-dispersive X-ray spectroscopy (EDX) analysis revealed a Na-deficient composition for the obtained film. X-ray diffraction and Raman spectroscopy allowed the identification of a pure perovskite BNT phase. Dielectric, ferroelectric, and leakage current measurements revealed good frequency stability of the dielectric constant and dielectric losses for BNT thin film. The results are discussed in terms of Na deficiency effects on the defect structure of BNT. Further, the film showed attractive electrostatic energy storage properties with energy density that exceeds 1.04 J/cm³ under E = 630 kV/cm. Full article

The existing experimental data for the $\gamma$ decay of the stable $N=Z$ doubly-odd nuclei and the $\beta$ decay of the corresponding isospin multiplets is reviewed. The structure of the lightest nuclei with masses $A\le 14$ is used to test and constrain ab initio nuclear theories. Most of the data were obtained in the second half of the last century and, in some cases, lack the needed precision for comparison with theoretical calculations. Recent spectroscopic studies in the lightest doubly-odd N = Z nuclei are discussed, as well as open problems related to the understanding of their structures and ideas for future experiments. Full article

Photons with energy totaling more than 10 MeV provide efficient treatment for deeply seated tumors but interact with the nuclei of high-Z materials constituting a head of the linac. These interactions result in photoneutrons that deliver an additional out-of-field dose to the patient, which increases the risk of radiation-induced cancer. Monte Carlo simulation is an accurate strategy for estimating the effective photoneutron dose for a patient. In the current study, the possibility of using GEANT4 to calculate the photoneutron spectrum from the medical linac was investigated. The free-in-air photoneutron spectrum from a head of the linac was simulated using the NeutronHP experimental package. Validation of the simulated model was carried out based on a comparison of simulated and measured percentage depth–dose curves from photons in the water phantom. The obtained photoneutron spectrum was compared with the previously measured spectrum at the Varian Thilogy linac. GEANT4 may improve the accuracy of calculations of the effective dose based on photoneutrons. However, the simulated model should be improved and optimized. In the future, this model may constitute a physical basis for the prediction of the risk of radiation-induced cancer at our clinical center. Full article

The conventional theory of neutron beams interacting with many-body systems treats the beam as a classical system, i.e., with its dynamical variables appearing in the quantum dynamics of the scattering process not as operators but only as c-numbers. Moreover, neutrons are described with plane waves, i.e., the concept of a neutron’s (finite) coherence length is here irrelevant. The same holds for electron, atom or X-ray scattering. This simplification results in the full decoupling of the probe particle’s dynamics from the quantum dynamics of the scatterer—a well-known fact also reflected in the standard formalism of time-correlation functions (see textbooks). Making contact with modern quantum-theoretical approaches (e.g., quantum entanglement, “which-path information” versus interference, von Neumann measurement, Weak Values (WV), etc.), new observable effects of non-relativistic quantum beam scattering may be exposed and/or predicted, for instance, a momentum-transfer deficit and an intensity deficit in neutron scattering from protons of hydrogen-containing samples. A new WV-theoretical treatment is provided, which explains both these “deficit effects” from first principles and on equal footing. Full article

The chemical composition and stoichiometry of vertically aligned arrays of nitrogen-doped multi-walled carbon nanotubes (N-CNTs) were studied by photoelectron spectroscopy using laboratory and synchrotron X-ray sources. We performed careful deconvolution of high-resolution core-level spectra to quantify pyridine/pyrrole-like defects in N-CNTs, which are a key factor in the efficiency of the piezoelectric response for this material. It is shown that the XPS method makes it possible to estimate the concentration and type of nitrogen incorporation (qualitatively and quantitatively) in the “N-CNT/Mo electrode” system using both synchrotron and laboratory sources. The obtained results allow us to study the effect of the nickel catalytic layer thickness on the concentration of pyridine/pyrrole-like nitrogen and piezoelectric response in the nanotubes. Full article

The study of the chemical composition of historical glasses is widely used in archaeometry. The results of such analyses provide information on the probable date, place, and technological features of their production. Over time, a weathered layer may form on the surface of the glass, which differs in composition from the original one. To determine the initial composition using conventional methods (for example, X-ray fluorescence spectroscopy), the weathered layer should be removed. For historical objects, such manipulation is unacceptable and should be minimized. One of the methods for analyzing the chemical composition with minimal damage to a sample is laser-induced breakdown spectroscopy. The aim of this work was to develop a LIBS method, which makes it possible to perform a quantitative analysis of lead silicate glasses, including glasses containing a weathered layer. Reference glasses with a variable content of potassium, silicon, and lead oxides were synthesized, and based on the LIBS spectra, a calibration dependence was obtained that made it possible to measure the concentration of lead and potassium oxides in glasses within 70–85 and 5–20 wt%, respectively. The method was applied to analyze the composition of the glaze on a historic glazed tile from the burial church in the Euphrosinian monastery in Polotsk (the second half of the 12th century AD). The crater formed with the laser beam on the glazed surface was about 200 microns. Such damage is negligible compared to the total surface area of the tile (~10 cm²). The thickness of the weathered glaze layer was 70 microns, which was determined using variation in lead oxide content. Full article

Plastically deformed low-carbon steel has been analyzed by nondestructive three-dimensional orientation and strain mapping using scanning three-dimensional X-ray diffraction microscopy (S3DXRD). However, the application of S3DXRD is limited to single-phase alloys. In this study, we propose a modified S3DXRD analysis for dual-phase alloys, such as ferrite–pearlite carbon steel, which is composed of grains detectable as diffraction spots and a phase undetectable as diffraction spots. We performed validation experiments for ferrite–pearlite carbon steel with different pearlite fractions, in which the ferrite grains and the pearlite corresponded to the detectable grains and an undetectable phase, respectively. The regions of pearlite appeared more remarkably in orientation maps of the ferrite grains obtained from the carbon steel samples than that of the single-phase low-carbon steel and increased with the increase in the carbon concentration. The fractions of the detectable grains and the undetectable phase were determined with an uncertainty of 15%–20%. These results indicate that the proposed modified analysis is qualitatively valid for dual-phase alloys comprising detectable grains and an undetectable phase. Full article

In the presented work, a total of 60 bronze artefacts from the prehistoric settlement of Baley, Bulgaria were analyzed by means of laser-induced breakdown spectroscopy (LIBS) and X-ray fluorescence spectroscopy (XRF). The archaeological finds were excavated from three levels, with a time span from the 15th century BC to the first half of the 11th century BC. The obtained analytical information was used for quantitative estimation of the amount of tin, lead and arsenic, which determine the mechanical properties of the alloy and the manufacturing technology. Based on the estimated quantities of these elements, a chemometric statistical analysis (principal component analysis—PCA) was performed to classify and divide the samples into separate groups according to the production dating. The data obtained in this study can be used for comparison with the elemental content in deposits from other settlements of this period. Full article

In this paper, the magnetic heating effect of the superconducting quarter-wave resonator (QWR) cavities is investigated, and the Q slopes of the superconducting cavities are measured with an increasing accelerating field. Bardeen–Cooper–Schrieffer (BCS) resistance is calculated for the zero-temperature limit. The vertical test is shown for the performance test of the QWR cavities. The parameters for the QWR cavity are presented. The Q slopes are measured as a function of an accelerating electric field at 4.2 K. The surface resistance of the superconducting cavity increases with an increasing peak magnetic field. The magnetic defects degrade the quality factor. From the magnetic degradation, we determine the magnetic moments of the superconducting cavities. All quarter-wave resonator (QWR) cryomodules are installed in the tunnel, and beam commissioning is performed successfully. Full article

The popularity of the pair distribution function (PDF) analysis of X-ray total scattering data has steadily grown as access to ex situ synchrotron data has expanded. Due to the broadening of the PDF user community, there is a growing demand for software that can be used to extract PDFs and is accessible to non-expert users. While user-friendly options have been developed over the past decade for fast, streamlined data analysis, care must be taken in both processing the data and understanding any limitations, especially in the case of liquids. In this review, the same scattering data are analyzed using different total X-ray scattering software, in order to compare the accuracy of the extracted structure factors and associated pair distribution functions. The goal is to assess the best practices for extracting the most accurate liquid data for each software package. The importance of absolute normalization and the application of the most appropriate corrections are emphasized via quantitative comparisons between liquid sulfur and water. Additionally, an awareness of the competing conventions used to define the PDF in crystallography and liquids/glasses is crucial for both the downstream analyses of the data and a comparison with the previous results in the literature. Full article

We have investigated the ultrasonically induced birefringence traces of aqueous solutions of dexamethasone disodium phosphate, a derivative of hydrocortisone (cortisol). The stationary birefringence and the transient built-up and decay relaxation processes were studied as a function of solution concentration, ultrasound frequency and intensity, as well as a function of temperature. The results were analyzed in view of structural peculiarities of the system in an effort to gain further insights into the molecular relaxation dynamics and the proposed self-association process occurring in the system. The detected ultrasonically induced birefringence relaxation is motivated by the rotational diffusion of dexamethasone disodium phosphate aggregates due to self-association depending on the solution concentration. The observed relaxation mechanism is directly linked to the hydrodynamic size of the acoustic field-induced self-assembly. The systematic analysis of the transient birefringence signals caused by the applied ultrasonic field allowed us to evaluate the interplay between permanent and induced dipoles with changing concentration, temperature, and ultrasound properties. The birefringence traces are adequately fitted with a stretched exponential law indicating the polydispersive nature of the self-aggregated molecular structures. The obtained results are described in the light of recent studies performed on this system. Full article

The Hellenic Naval Academy (HNA) reports the latest results from a medium-range, near-maritime, free-space laser-communications-testing facility, between the lighthouse of Psitalia Island and the academy’s laboratory building. The FSO link is established within the premises of Piraeus port, with a path length of 2958 m and an average altitude of 35 m, mainly above water. Recently, the facility was upgraded through the addition of a BLS450 scintillometer, which is co-located with the MRV TS5000/155 FSO system and a WS-2000 weather station. This paper presents the preliminary optical turbulence measurements, collected from 24 to 31 of May 2022, alongside the macroscopic meteorological parameters. Four machine-learning algorithms (random forest (RF), gradient boosting regressor (GBR), single layer (ANN), and deep neural network (DNN)) were utilized for refractive-index-structural-parameter regression modeling. Additionally, another DNN was used to classify the strength level of the optical turbulence, as either strong or weak. The results showed very good prediction accuracy for all the models. Specifically, the ANN algorithm resulted in an R-squared of 0.896 and a mean square error (MSE) of 0.0834; the RF algorithm also gave a highly acceptable R-squared of 0.865 and a root mean square error (RMSE) of 0.241. The Gradient Boosting Regressor (GBR) resulted in an R-squared of 0.851 and a RMSE of 0.252 and, finally, the DNN algorithm resulted in an R-squared of 0.79 and a RMSE of 0.088. The DNN-turbulence-strength-classification model exhibited a very acceptable classification performance, given the highly variability of our target value ($C_n^2$), since we observed a predictive accuracy of 87% with the model. Full article