Advances in Electrochemical Catalysis for CO2 Reduction

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Chemical Processes and Systems".

Deadline for manuscript submissions: closed (25 February 2025) | Viewed by 2666

Special Issue Editor


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Guest Editor
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, AB T6G 1H9, Canada
Interests: electrocatalysis; CO2 reduction; nanomaterials; operando/in situ characterizations

Special Issue Information

Dear Colleagues,

The utilization of CO2 is an effective strategy for mitigating the greenhouse effect through the production of valuable chemicals and fuels. The electrochemical CO2 reduction reaction (CO2RR) is considered a promising technology for reducing CO2 emissions and achieving sustainable carbon neutrality. However, the practical application and commercialization of CO2RR face significant challenges, including high overpotential, sluggish kinetics, a broad distribution of target products, competitive hydrogen evolution reaction (HER) in aqueous media, and the requirement of multi-electron transfer steps for most catalysts during CO2RR. Therefore, it is essential to develop highly selective and active electrocatalysts to improve CO2RR performance.

In recent years, a variety of approaches have been developed to address the challenges of CO2RR. These include employing engineering strategies in electrocatalyst design to enhance electrocatalytic activity and selectivity, using flow electrolyzer or membrane electrode assembly electrolyzer to boost electrochemical performance, and advancing operando/in situ characterization techniques for a deeper understanding of the reaction mechanisms.

This Special Issue, entitled “Advances in Electrochemical Catalysis for CO2 Reduction,” aims to provide a platform for highlighting the recent advances in this field. Potential topics include, but are not limited to, the following:

  • Advances in electrocatalyst design;
  • The development of CO2RR devices;
  • Operando/in situ characterization techniques;
  • The investigation of dynamic reaction processes for understanding reaction mechanisms.

Dr. Pengfei Sui
Guest Editor

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Keywords

  • CO2 electroreduction
  • electrocatalysis
  • device design
  • In situ characterizations
  • nanomaterials
  • reaction mechanism

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Published Papers (1 paper)

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Review

19 pages, 9121 KiB  
Review
Structural Control of Copper-Based MOF Catalysts for Electroreduction of CO2: A Review
by Hongxin Fu, Hailing Ma and Shuaifei Zhao
Processes 2024, 12(10), 2205; https://doi.org/10.3390/pr12102205 - 10 Oct 2024
Cited by 2 | Viewed by 2047
Abstract
With the excessive use of fossil fuels, atmospheric carbon dioxide (CO2) concentrations have risen dramatically in recent decades, leading to serious environmental and social issues linked to global climate change. The emergence of renewable energy sources, such as solar, tidal, and [...] Read more.
With the excessive use of fossil fuels, atmospheric carbon dioxide (CO2) concentrations have risen dramatically in recent decades, leading to serious environmental and social issues linked to global climate change. The emergence of renewable energy sources, such as solar, tidal, and wind energy, has created favorable conditions for large-scale electricity production. Recently, significant attention has been drawn to utilizing renewable energy to catalyze the conversion of CO2 into fuels, producing substantial industrial feedstocks. In these CO2 conversion processes, the structure and performance of catalysts are critical. Metal-organic frameworks (MOFs) and their derivatives have emerged as promising electrocatalysts for CO2 reduction, offering advantages such as high surface area, porosity, exceptional functionality, and high conversion efficiency. This article provides a comprehensive review of structural regulation strategies for copper-based MOFs, highlighting innovative mechanisms like synergistic bimetallic catalysis, targeted doping strategies, and the construction of heterostructures. These novel approaches distinguish this review from previous studies, offering new insights into the electrocatalytic performance of copper-based MOFs and proposing future research directions for improved catalyst design. Full article
(This article belongs to the Special Issue Advances in Electrochemical Catalysis for CO2 Reduction)
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