Biochar Pyrolysis Process and Carbon Emission

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Sustainable Processes".

Deadline for manuscript submissions: closed (20 February 2024) | Viewed by 1432

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Guest Editor
Institute of Nuclear Sciences—National Institute of the Republic of Serbia, University of Belgrade, “Vinča”, Mike Petrovića Alasa 12-14, P.O. Box 522, 11001 Belgrade, Serbia
Interests: active carbon; adsorption; environment; carbonization; hydrothermal synthesis; thermodynamic parameters; process parameter optimization
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Guest Editor
Center for Sustainable Biomaterials & Bioenergy, West Virginia University, Morgantown, WV 26506, USA
Interests: biomass; thermal conversion; biochar application; waste management; water purification; carbon emission

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Guest Editor
Department of Physical Chemistry, University of Belgrade, Mike Petrovića Alasa 12-14, P.O. Box 522, 11001 Belgrade, Serbia
Interests: ionization; energy parameters; analysis clusters; mass spectrometry; small chemical reactors

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Co-Guest Editor
Department of Materials Science, University of Belgrade, Belgrade, Mike Petrovića Alasa 12-14, P.O. Box 522, 11001 Belgrade, Serbia
Interests: obtaining carbon materials; adsorption of heavy metals; characterization of the material; biowaste examination

Special Issue Information

Dear Colleagues,

The process of biochar pyrolysis entails the transformation of biomass into biochar by subjecting it to heat in an environment with limited or no oxygen. Biochar can be applied in various domains of human existence, such as carbon sequestration, which is widely regarded as a promising strategy for mitigating carbon emissions and climate change. The biochar pyrolysis procedure commences by gathering biomass feedstock, encompassing agricultural residues, forestry waste, or dedicated energy crops. The biomass is subsequently exposed to elevated temperatures, typically ranging from 350 to 700 degrees Celsius, within an environment that is either low in oxygen or completely devoid of oxygen. The thermal decomposition process, commonly referred to as pyrolysis, facilitates the breakdown of biomass into three primary constituents, namely biochar, syngas, and bio-oil. Biochar refers to the solid byproduct that is generated as a result of the process of pyrolysis. The substance in question is characterized by a high carbon content and the presence of stable carbon compounds, which imparts it with a notable resistance to decomposition. The characteristics of biochar, including its surface area, porosity, and chemical composition, exhibit variability contingent upon the specific feedstock utilized and the conditions employed during the pyrolysis process.

The process of biochar pyrolysis also presents a carbon-negative approach, as it has the potential to counterbalance carbon emissions. When biomass is exposed to pyrolysis, it undergoes an incomplete combustion process, leading to the formation of biochar as opposed to the direct emission of carbon dioxide (CO2) into the Earth's atmosphere. Furthermore, the syngas and bio-oil produced through the process of pyrolysis can be effectively harnessed as alternative energy sources, thereby contributing to a reduction in fossil fuel usage and the subsequent release of carbon emissions. However, the carbon emissions and environmental impact associated with biochar pyrolysis are contingent upon several factors, such as the origin and handling of biomass feedstock, the effectiveness of the pyrolysis procedure, and the transportation and utilization of biochar. A thorough examination of these factors is imperative to guarantee the environmental sustainability of the complete life cycle of biochar production and utilization.

Dr. Vladimir M. Dodevski
Dr. Wanhe Hu
Dr. Filip Veljkovic
Dr. Sanja Krstic
Guest Editors

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Keywords

  • biochar production
  • pyrolysis process
  • temperature
  • heating rate
  • pyrolysis device
  • life cycle assessment (LCA)
  • carbon emiassion
  • carbon sequestration

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Published Papers (1 paper)

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Research

15 pages, 4192 KiB  
Article
Performance and Mechanism of Porous Carbons Derived from Biomass as Adsorbent for Removal of Cr(VI)
by Bingbing Mi and Yuanjie Wang
Processes 2024, 12(10), 2229; https://doi.org/10.3390/pr12102229 - 13 Oct 2024
Cited by 1 | Viewed by 1155
Abstract
To solve the problem of heavy metal hexavalent chromium (Cr(VI)) pollution in water bodies, this study was carried out to prepare nitrogen-doped porous carbon by using bamboo shoots as the raw material and KHCO3 as the activator, which has a good ability [...] Read more.
To solve the problem of heavy metal hexavalent chromium (Cr(VI)) pollution in water bodies, this study was carried out to prepare nitrogen-doped porous carbon by using bamboo shoots as the raw material and KHCO3 as the activator, which has a good ability to remove Cr(VI) from water bodies. The prepared N-doped carbon materials were characterized by thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), elemental analysis, and scanning electron microscopy (SEM). The results showed that the prepared carbon material had hierarchical pore structures and abundant functional groups, which is conducive to the adsorption of Cr(VI). The effects of various factors on the adsorption performance of Cr(VI), such as the carbon materials prepared under different conditions, the pH of the initial solution, the concentration of the initial solution, and the contact time between the carbon and Cr(VI), were explored. The results showed that the bamboo shoot-based nitrogen-doped carbon materials, especially BSNC-800 (prepared at 800 °C with a mass ratio of KHCO3 to bamboo shoot of 4:1), performed well in removing Cr(VI) from a water solution. The maximum adsorption of Cr(VI) by BSNC-800 under equilibrium conditions was 385.8 mg g−1 (conditions: at the pH of 2 with the initial concentration of 400 mg L−1). The adsorption kinetics and isotherms were analyzed, and the adsorption mechanism was discussed. It can be found that the adsorption of Cr(VI) by BSNC-800 fits better with the Langmuir isotherm model and the pseudo-second-order kinetic model. The adsorption mechanism between the Cr(VI)-containing solution and BSNC-800 was controlled by membrane diffusion and chemisorption. The results broaden the ways of utilizing biomass resources as precursors of carbon materials, which is significant and helpful for applying biomass carbon materials as adsorbents for wastewater treatment. Full article
(This article belongs to the Special Issue Biochar Pyrolysis Process and Carbon Emission)
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