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Functional Materials for Separation and Recovery of Rare Earth Elements and Heavy Metals

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Green Materials".

Deadline for manuscript submissions: 20 December 2025 | Viewed by 628

Special Issue Editors


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Guest Editor
1. Department of Energy Power & Mechanical Engineering, North China Electric Power University, Baoding 071003, China
2. Hebei Key Laboratory of Low Carbon and High Efficiency Power Generation Technology, North China Electric Power University, Baoding 071003, China
Interests: catalytic technology for the capture of gaseous heavy metals; efficient transformation and resource utilization of solid waste

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Guest Editor
State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China
Interests: simultaneous removal and resource utilization in heavy metals from industrial production (Tl/As/Se/Hg0); catalytic technology for the capture of gaseous heavy metals; application of earth elements in catalytic technology for gaseous multipollutant emission control
1. Zhongyuan Critical Metals Laboratory, Zhengzhou University, Zhengzhou 450001, China
2. Key Laboratory of Critical Metals Minerals Supernormal Enrichment and Extraction of Ministry of Education, Zhengzhou University, Zhengzhou 450001, China
3. State Key Laboratory of Critical Metals Beneficiation, Metallurgy and Purification, Zhengzhou University, Zhengzhou 450001, China
Interests: critical metal recovery from low-grade ores; heavy metal pollution control
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Special Issue Information

Dear Colleagues,

Rare-earth elements (REEs) and some heavy metals are critical mineral resources for modern technologies, yet their extraction, use, and improper disposal pose significant environmental and health risks due to their toxicity, persistence, and bioaccumulative nature. With the growing global demand for clean energy technologies (e.g., batteries, magnets, and solar energy) and the urgent need to mitigate environmental pollution, the development of advanced functional materials capable of selectively separating, recovering, storing, utilizing, and recovering these elements from complex matrices—such as industrial wastewater, flue gas, electronic waste, and mining effluents—has become a pressing priority. Addressing the dual challenges of resource scarcity and environmental contamination requires innovative solutions at the intersection of material science, environmental engineering, and circular economy principles.

In recent years, significant progress has been made in designing functional materials—including porous adsorbents, ion-imprinted polymers, catalytic membranes, and defect-engineered nanomaterials—that enhance the efficiency, selectivity, and reusability of separation processes.

Advanced characterization techniques and simulation methods (e.g., in situ spectroscopy, DFT simulations, machine learning) have deepened our understanding of mechanisms such as ion exchange, surface complexation, and redox-driven recovery. However, challenges remain in scaling these materials for industrial applications, optimizing their performance under real-world conditions (e.g., low concentrations, multi-component competition), and ensuring economic and environmental sustainability across their lifecycle.

The purpose of this Special Issue is to compile cutting-edge research that advances the science and engineering of functional materials for REE and heavy metal separation, recovery, storage, and utilization. We welcome contributions addressing functional material properties, mechanistic studies, process optimization, and case studies on resource recycling from secondary sources (e.g., end-of-life products and industrial sludges). Submissions may comprise original research articles, reviews, or perspectives that bridge fundamental discoveries and practical applications, ultimately fostering sustainable resource management and pollution control.

We look forward to receiving your innovative contributions to this critical field.

Dr. Yue Zhang
Dr. Jiaying Xing
Dr. Biao Fu
Guest Editors

Manuscript Submission Information

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Keywords

  • rare-earth element recovery
  • heavy metal extraction and separation
  • interface catalysis
  • resource recycling
  • selective redox
  • functional material properties
  • active site regulation
  • flue gas treatment
  • defect engineering
  • circular economy

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Published Papers (1 paper)

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Research

13 pages, 3049 KiB  
Article
Preparation of Foamed Ceramic from Cr Slag and MSWI Fly Ash and Its Cr Leaching Inhibition
by Hesong Li, Cheng Liu, Yikun Tang and Shilin Zhao
Materials 2025, 18(14), 3372; https://doi.org/10.3390/ma18143372 - 18 Jul 2025
Viewed by 219
Abstract
The sustainable utilization of solid waste is crucial for environmental protection. This work investigates the fabrication of foamed ceramics from Cr slag and municipal solid waste incineration (MSWI) fly ash, focusing on the effects of three inhibitors—NH2SO3H, ZnO·TiO2 [...] Read more.
The sustainable utilization of solid waste is crucial for environmental protection. This work investigates the fabrication of foamed ceramics from Cr slag and municipal solid waste incineration (MSWI) fly ash, focusing on the effects of three inhibitors—NH2SO3H, ZnO·TiO2, and (NH4)2HPO4—on material properties and Cr leaching behavior. Experimental analysis, chemical thermodynamic calculations, and material characterization were all employed. Results show that the prepared foamed ceramics meet the JG/T 511-2017 standard for building materials, exhibiting excellent physical properties but significant Cr leaching. Among the inhibitors, (NH4)2HPO4 with a molar ratio of n(P)/n(Cr) = 1 shows the best performance, achieving a bulk density of 205 kg/m3, compressive strength of 0.850 MPa, Cr leaching concentration of 188 μg/L, and a 70.0% of Cr leaching inhibition rate. The improvement is attributed to the AlPO4 formation that enhancing the strength, and Ca2P2O7 that stabilizing Cr during sintering. This work provides a feasible method for the safe resource utilization of Cr-containing waste. Full article
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