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Corrosion and Corrosion Protection of Metals/Alloys

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Corrosion".

Deadline for manuscript submissions: 20 March 2026 | Viewed by 281

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Department of Engineering Materials and Biomaterials, Mechanical Engineering Faculty, Silesian University of Technology, ul. Konarskiego, 18a, 44-100 Gliwice, Poland
Interests: stainless steels; duplex stainless steel; heat-resistant steels; creep-resistant steels; corrosion; powder metallurgy; additive manufacturing; surface engineering; laser processing of metals; electrochemical impedance spectroscopy
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Special Issue Information

Dear Colleagues,

The corrosion of metals and alloys remains one of the most critical challenges in materials engineering. It affects the durability, safety, and performance of products and systems in a range of industries, including energy, construction, transport, and biomedical applications. Despite significant advances in alloy design, protective coatings, and surface engineering, the complex mechanisms of corrosion in different environments and operating conditions require ongoing research. This Special Issue, entitled “Corrosion and Corrosion Protection of Metals/Alloys”, aims to provide a platform for researchers and engineers to share recent advances in our understanding of corrosion phenomena and in the development of innovative protection strategies. Topics include fundamental studies of electrochemical processes, environmental degradation, localised corrosion, and stress corrosion cracking, as well as advanced approaches such as nanostructured coatings, corrosion inhibitors, surface modifications, and sustainable corrosion protection technologies. Contributions addressing modelling, testing methods, and case studies from industrial applications are also encouraged. By bringing together theoretical, experimental, and applied perspectives, this Special Issue seeks to promote knowledge exchange and highlight practical solutions for extending the service life of metallic materials. Potential authors are invited to submit original research articles, reviews, or case reports that contribute to advancing corrosion science and protective technologies.

Dr. Zbigniew Brytan
Guest Editor

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Keywords

  • corrosion mechanisms
  • corrosion protection
  • metallic alloys
  • surface engineering
  • protective coatings
  • corrosion inhibitors
  • stress corrosion cracking
  • localized corrosion
  • electrochemical methods
  • service life extension

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Published Papers (1 paper)

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Research

26 pages, 18739 KB  
Article
ZnO Thin Films as Promising Corrosion Protection on Mg-Based Alloys
by Aneta Kania, Magdalena M. Szindler, Marek Szindler, Zbigniew Brytan, Monika Kciuk, Wojciech Pakieła, Łukasz Reimann and Paweł M. Nuckowski
Materials 2025, 18(24), 5568; https://doi.org/10.3390/ma18245568 - 11 Dec 2025
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Abstract
The present study examined the microstructure and corrosion characteristics of MgCa4Zn1Gd1 and MgCa2Zn1Gd3 alloys that were coated with ZnO thin films, which were deposited by atomic layer deposition (ALD). Coatings of different thicknesses (42.5, 95.4 and 133.7 nm for 500, 1000, and 1500 [...] Read more.
The present study examined the microstructure and corrosion characteristics of MgCa4Zn1Gd1 and MgCa2Zn1Gd3 alloys that were coated with ZnO thin films, which were deposited by atomic layer deposition (ALD). Coatings of different thicknesses (42.5, 95.4 and 133.7 nm for 500, 1000, and 1500 cycles, respectively) were characterized using X-ray diffraction (XRD), Raman spectroscopy, SEM/EDS, AFM (atomic force microscope), and FTIR (Fourier transform infrared spectroscopy). XRD and Raman analyses were conducted to verify the formation of crystalline zinc oxide (ZnO) with a homogeneous granular morphology. Surface roughness decreased with increasing coating thickness, reaching the lowest values for the 1500-cycle ZnO layer on MgCa2Zn1Gd3 (Ra = 7.65 nm, Rs = 9.8 nm). Potentiodynamic and immersion tests in Ringer solution at 37 °C revealed improved corrosion resistance for thicker coatings, with the lowest hydrogen evolution (20.89 mL·cm−2) observed for MgCa2Zn1Gd3 coated after 1500 cycles. Analysis of corrosion products by FTIR identified Mg(OH)2 and MgCO3 as dominant and then MgO and ZnO. Phase analysis also indicated the presence of ZnO coating after 100 h of immersion. The ZnO film deposited after 1500 ALD cycles on MgCa2Zn1Gd3 provides the most effective corrosion protection and is a promising solution for biodegradable magnesium implants. Full article
(This article belongs to the Special Issue Corrosion and Corrosion Protection of Metals/Alloys)
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