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Advances in Organic Framework Materials: Syntheses and Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: closed (10 April 2024) | Viewed by 8781

Special Issue Editors

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
Interests: covalent organic frameworks; polymer-based photoelectric materials
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Guest Editor
Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
Interests: metal–organic frameworks; porous materials; shape-selective catalysis

Special Issue Information

Dear Colleagues,

It is my pleasure to invite you to submit full papers, communications, and reviews to the forthcoming Special Issue “Advance in Organic Framework Materials: Synthetic Strategies and Applications”.

Accurately controlling the assembly of functional motifs presents a significant challenge for the construction of organic framework materials, which requires the development of structurally diverse building blocks and highly reliable synthetic strategies. Porous organic materials have aroused much attention due to their modular nature and tunable structures. In particular, organic framework materials such as metal–organic frameworks (MOFs), covalent organic frameworks (COFs), hydrogen-bonded organic frameworks (HOFs), supramolecular organic frameworks (SOFs), and halogen-bonded organic frameworks (XOFs) have been widely used in the fields of gas sorption and storage, catalysis, luminescence, sensing, biomedicine, environmental remediation, energy storage, and conversion. Although there has been remarkable progress in the field of reticular chemistry over the past decade, the exploration of new synthetic strategies and applications is still in its infancy. It is also necessary to establish a fundamental understanding of the relationships between chemical structures and physicochemical properties in organic framework materials used for diverse applications. Manuscripts dedicated to the research and development of organic framework materials, especially for MOFs, COFs, HOFs, SOFs, and XOFs, will be gladly considered.

Dr. Cheng Qian
Dr. Weiqiang Zhou
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • metal–organic frameworks
  • covalent organic frameworks
  • hydrogen-bonded organic frameworks
  • supramolecular organic frameworks
  • halogen-bonded organic framework
  • water splitting
  • CO2 reduction
  • degradation

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Published Papers (4 papers)

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Research

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9 pages, 3356 KiB  
Article
Tailoring the Microstructure of Porous Carbon Spheres as High Rate Performance Anodes for Lithium-Ion Batteries
by Zikun Liang, Ang Li, Kaiming Deng, Bo Ouyang and Erjun Kan
Materials 2023, 16(13), 4828; https://doi.org/10.3390/ma16134828 - 5 Jul 2023
Cited by 1 | Viewed by 1478
Abstract
Benefiting from their high surface areas, excellent conductivity, and environmental-friendliness, porous carbon nanospheres (PCSs) are of particular attraction for the anodes of lithium-ion batteries (LIBs). However, the regulation of carbon nanospheres with controlled pore distribution and graphitization for delivering high Li+ storage [...] Read more.
Benefiting from their high surface areas, excellent conductivity, and environmental-friendliness, porous carbon nanospheres (PCSs) are of particular attraction for the anodes of lithium-ion batteries (LIBs). However, the regulation of carbon nanospheres with controlled pore distribution and graphitization for delivering high Li+ storage behavior is still under investigation. Here, we provide a facile approach to obtain PCSs with different microstructures via modulating the carbonization temperatures. With the processing temperature of 850 °C, the optimized PCSs exhibit an increased surface area, electrical conductivity, and enhanced specific capacity (202 mA h g−1 at 2 A g−1) compared to the PCSs carbonized at lower temperatures. Additionally, PCSs 850 provide excellent cyclability with a capacity retention of 83% for 500 cycles. Such work can pave a new pathway to achieve carbon nanospheres with excellent performances in LIBs. Full article
(This article belongs to the Special Issue Advances in Organic Framework Materials: Syntheses and Applications)
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11 pages, 2475 KiB  
Article
Optimized Pinecone-Squama-Structure MoS2-Coated CNT and Graphene Framework as Binder-Free Anode for Li-Ion Battery with High Capacity and Cycling Stability
by Hanwen Jian, Tongyu Wang, Kaiming Deng, Ang Li, Zikun Liang, Erjun Kan and Bo Ouyang
Materials 2023, 16(8), 3218; https://doi.org/10.3390/ma16083218 - 19 Apr 2023
Cited by 3 | Viewed by 1464
Abstract
Extensive research has been conducted on the development of high-rate and cyclic stability anodes for lithium batteries (LIBs) due to their high energy density. Molybdenum disulfide (MoS2) with layered structure has garnered significant interest due to its exceptional theoretic Li+ [...] Read more.
Extensive research has been conducted on the development of high-rate and cyclic stability anodes for lithium batteries (LIBs) due to their high energy density. Molybdenum disulfide (MoS2) with layered structure has garnered significant interest due to its exceptional theoretic Li+ storage behavior as anodes (670 mA h g−1). However, achieving a high rate and long cyclic life of anode materials remains a challenge. Herein, we designed and synthesized a free-standing carbon nanotubes-graphene (CGF) foam, then presented a facile strategy to fabricate the MoS2-coated CGF self-assembly anodes with different MoS2 distributions. Such binder-free electrode possesses the advantages of both MoS2 and graphene-based materials. Through rational regulation of the ratio of MoS2, the MoS2-coated CGF with uniformly distributed MoS2 exhibits a nano pinecone-squama-like structure that can accommodate the large volume change during the cycle process, thereby significantly enhancing the cycling stability (417 mA h g−1 after 1000 cycles), ideal rate performance, and high pseudocapacitive behavior (with a 76.6% contribution at 1 mV s−1). Such a neat nano-pinecone structure can effectively coordinate MoS2 and carbon framework, providing valuable insights for the construction of advanced anode materials. Full article
(This article belongs to the Special Issue Advances in Organic Framework Materials: Syntheses and Applications)
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12 pages, 4728 KiB  
Article
Vertical Graphene-Supported NiMo Nanoparticles as Efficient Electrocatalysts for Hydrogen Evolution Reaction under Alkaline Conditions
by Hongbin Wang, Beirong Ye, Chen Li, Tao Tang, Sipu Li, Shaojun Shi, Chunyang Wu and Yongqi Zhang
Materials 2023, 16(8), 3171; https://doi.org/10.3390/ma16083171 - 18 Apr 2023
Cited by 5 | Viewed by 2335
Abstract
Water electrolysis as an important and facile strategy to generate hydrogen has attracted great attention, and efficient electrocatalysts play a key role in hydrogen evolution reaction (HER). Herein, vertical graphene (VG)-supported ultrafine NiMo alloy nanoparticles (NiMo@VG@CC) were fabricated successfully via electro-depositing as efficient [...] Read more.
Water electrolysis as an important and facile strategy to generate hydrogen has attracted great attention, and efficient electrocatalysts play a key role in hydrogen evolution reaction (HER). Herein, vertical graphene (VG)-supported ultrafine NiMo alloy nanoparticles (NiMo@VG@CC) were fabricated successfully via electro-depositing as efficient self-supported electrocatalysts for HER. The introduction of metal Mo optimized the catalytic activity of transition metal Ni. In addition, VG arrays as the three-dimensional (3D) conductive scaffold not only ensured high electron conductivity and robust structural stability, but also endowed the self-supported electrode large specific surface area and exposed more active sites. With the synergistic effect between NiMo alloys and VG, the optimized NiMo@VG@CC electrode exhibited a low overpotential of 70.95 mV at 10 mA cm−2 and a remarkable stable performance over 24 h. This research is anticipated to offer a powerful strategy for the fabrication of high-performance hydrogen evolution catalysts. Full article
(This article belongs to the Special Issue Advances in Organic Framework Materials: Syntheses and Applications)
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Review

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31 pages, 16945 KiB  
Review
Nanostructured TiO2 Arrays for Energy Storage
by Pingyun Si, Zhilong Zheng, Yijie Gu, Chao Geng, Zhizhong Guo, Jiayi Qin and Wei Wen
Materials 2023, 16(10), 3864; https://doi.org/10.3390/ma16103864 - 20 May 2023
Cited by 11 | Viewed by 2903
Abstract
Because of their extensive specific surface area, excellent charge transfer rate, superior chemical stability, low cost, and Earth abundance, nanostructured titanium dioxide (TiO2) arrays have been thoroughly explored during the past few decades. The synthesis methods for TiO2 nanoarrays, which [...] Read more.
Because of their extensive specific surface area, excellent charge transfer rate, superior chemical stability, low cost, and Earth abundance, nanostructured titanium dioxide (TiO2) arrays have been thoroughly explored during the past few decades. The synthesis methods for TiO2 nanoarrays, which mainly include hydrothermal/solvothermal processes, vapor-based approaches, templated growth, and top-down fabrication techniques, are summarized, and the mechanisms are also discussed. In order to improve their electrochemical performance, several attempts have been conducted to produce TiO2 nanoarrays with morphologies and sizes that show tremendous promise for energy storage. This paper provides an overview of current developments in the research of TiO2 nanostructured arrays. Initially, the morphological engineering of TiO2 materials is discussed, with an emphasis on the various synthetic techniques and associated chemical and physical characteristics. We then give a brief overview of the most recent uses of TiO2 nanoarrays in the manufacture of batteries and supercapacitors. This paper also highlights the emerging tendencies and difficulties of TiO2 nanoarrays in different applications. Full article
(This article belongs to the Special Issue Advances in Organic Framework Materials: Syntheses and Applications)
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