Inorganic Compounds for Catalysis

A special issue of Inorganics (ISSN 2304-6740).

Deadline for manuscript submissions: closed (5 September 2022) | Viewed by 3960

Special Issue Editors


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Inorganic, Isotope and Actinide Chemistry Group (C-IIAC), Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA
Interests: inorganic and organometallic chemistry; catalysis; chemistry for sustainable and renewable energy applications
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Guest Editor
Department of Organic and Inorganic Chemistry, Universidad de Alcala, 28801 Alcala de Henares, Spain
Interests: organometallic compounds; catalysis; polymerization; metal transition; main groups metals; oxidation processes; nanocatalyst

Special Issue Information

Dear Colleagues,

As you know, catalysts make possible certain processes, and their importance at the industrial level is in many cases crucial, so chemists from many different fields continue to work on their design. From a sustainable point of view, catalysts are particularly interesting considering the "twelve principles" of green chemistry used to obtain the benefits of the "atom economy". Achieving more efficient processes, either from a stereoselectivity or conversion point of view, remains one of the goals in this field. Using abundant and cheap metals fulfils the goal of ”reducing and replacing” that which would otherwise be needed.

These “smart molecules” are in many cases discrete inorganic compounds of principal groups metals or transition metals where the ligands play an important role that is sometimes “not innocent”. So, the tailoring of ligands can alter the electronic structure properties and reactivity of metal centres.

With all of these pieces together, inorganic compounds as catalysis can be harnessed as an engine to satisfy multiple objectives.

Dr. John C. Gordon
Dr. Vanessa Tabernero
Guest Editors

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Keywords

  • catalysis
  • main group catalysis
  • transition metal catalysis
  • stereoselectivity
  • sustainable catalysis

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Published Papers (1 paper)

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Research

14 pages, 5308 KiB  
Article
Enhanced Photocatalytic Degradation of Rhodamine-B under Led Light Using CuZnAl Hydrotalcite Synthesized by Co-Precipitation Technique
by Van Nhuong Vu, Thi Ha Thanh Pham, Maiboun Chanthavong, Tra Huong Do, Thi Hien Lan Nguyen, Quoc Dung Nguyen and Thi Kim Ngan Tran
Inorganics 2022, 10(7), 89; https://doi.org/10.3390/inorganics10070089 - 23 Jun 2022
Cited by 7 | Viewed by 2480
Abstract
The co-precipitation method was employed to synthesize a set of ZnAl hydrotalcite materials modified by Cu2+. The synthesized materials have a similar lamellar structure to that of hydrotalcite. The distance between layers is in the range of 7.73–8.56 Å. The network [...] Read more.
The co-precipitation method was employed to synthesize a set of ZnAl hydrotalcite materials modified by Cu2+. The synthesized materials have a similar lamellar structure to that of hydrotalcite. The distance between layers is in the range of 7.73–8.56 Å. The network parameters a and c ranged from 3.058 to 3.074 Å and from 23.01 to 24.44, respectively. According to the IUPAC classification, the composites possess a mesoporous structure which belongs to class IV, type H 3. Particularly, the absorption edge shifts strongly to the visible light region when increasing the molar ratio of Cu2+ in the samples from 0 to 3.5. The photocatalytic activity of the synthetic materials was evaluated through the degradation efficiency of rhodamine-B (Rh-B) in the water and colorants in textile wastewater. The present study was the first to synthesize a material sample that contains a molar ratio of Cu2+ in the range of 2.5–3.5 and has high catalytic activities. They were able to degrade Rh-B at a high concentration (100 ppm) with a conversion rate of approximately 90% after 240 min of irradiation using a 30 W LED light. The catalytic activity of the composites depends on the molar ratio of modified Cu2+, the value of environmental pH, the H2O2 concentration and the irradiation time. Full article
(This article belongs to the Special Issue Inorganic Compounds for Catalysis)
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