Degradation of Organic Coatings

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Functional Polymer Coatings and Films".

Deadline for manuscript submissions: 20 June 2024 | Viewed by 2428

Special Issue Editor


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Guest Editor
Department of Industrial Engineering, University of Trento, Via Sommarive n. 9, 38123 Trento, TN, Italy
Interests: organic coatings (paints); corrosion inhibitors; surface conversion treatments; electrochemical techniques applied to corrosion studies; rare-earth-oxide-based coatings; conductive polymers; layered double hydroxides (LDH)-based coatings; anodic oxidation
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Special Issue Information

Dear Colleagues,

The performance of organic coatings designed for appearance or functional purposes is generally assessed using accelerated test cabinets, where natural weathering is strongly exacerbated (this is carried out by closely controlling levels of ions, humidity, UV radiation, wet/dry time, etc.). These characterization procedures (which include UV weathering, thermal cycling, wet/dry cycling, and in many cases, a combination) aspire to simulate, as much as possible, the actual environment (though in an accelerated manner). The assessment of the extent of degradation after a number of hours of exposure (or a number of aging cycles) can be performed simply via a visual check or by using analytical tools, including electrochemical techniques (such as electrochemical impedance spectroscopy—EIS, electrochemical noise—ENM), spectroscopic techniques (such as energy dispersive X-ray spectroscopy—EDX, X-ray photoelectron spectroscopy—XPS, Fourier-transform infrared Raman—FT-IR, UV-visible absorption and fluorescence, and X-ray diffraction—XRD) and thermoanalytical methods (such as differential scanning calorimetry—DSC, thermogravimetric analysis—TGA, and thermomechanical analysis—TMA). The relevant amount of collected experimental data can be exploited to enable effective service life prediction models by comparing the effect of different natural environments to which identical coated coupons are exposed. Field tests and outdoor exposure are ideal for assessing the real durability of an organic coating. However, it takes a long time to gain useful information, particularly for industrial and marine coatings. For this reason, effective predictive models should be developed with durability of organic coatings based on short-term, reliable, accelerated tests. For this reason, a large amount of experimental data is required to implement, test, and validate these models. A comprehensive and systematic collection of experimental data regarding the degradation of organic coatings is essential, not only to unravel the corrosion and degradation mechanisms, but also to provide the basis for training AI-based models using a large set of labeled data.

This Special Issue will provide a snapshot of state-of-the-art advances and the very latest developments in the study of the degradation of organic coatings exposed to accelerated laboratory tests and/or natural environments.

You are invited to contribute to this Special Issue to share your experimental data and update this research field with state-of-the-art durability assessment methods.

The scope of this Special Issue will include, but is not limited to, the following fundamental and applied research topics:

  • Corrosion and degradation of painted metals;
  • Service life predictions models for organic coatings;
  • New methods for the service life assessment and/or rating of organic coatings;
  • Accelerated test methods for the assessment of the performance of organic coatings and painted metals;
  • Outdoor aging of organic coatings;
  • Electrochemical methods for outdoor corrosion monitoring;
  • Effect of the weathering parameters on the aging of organic coatings.

Dr. Michele Fedel
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Coatings is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • organic coatings
  • durability
  • corrosion and polymers degradation
  • degradation assessment

Published Papers (1 paper)

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Research

21 pages, 8072 KiB  
Article
On the Limits of the EIS Low-Frequency Impedance Modulus as a Tool to Describe the Protection Properties of Organic Coatings Exposed to Accelerated Aging Tests
by Andrea Cristoforetti, Stefano Rossi, Flavio Deflorian and Michele Fedel
Coatings 2023, 13(3), 598; https://doi.org/10.3390/coatings13030598 - 11 Mar 2023
Cited by 8 | Viewed by 2072
Abstract
This study analyzes the limitations of the low-frequency EIS impedance modulus as a tool to describe the protective properties of organic coatings subjected to accelerated aging tests. Acrylic clear-coated steel and hot-dip galvanized steel were exposed to accelerated test methods such as the [...] Read more.
This study analyzes the limitations of the low-frequency EIS impedance modulus as a tool to describe the protective properties of organic coatings subjected to accelerated aging tests. Acrylic clear-coated steel and hot-dip galvanized steel were exposed to accelerated test methods such as the neutral salt spray chamber and the Prohesion test for up to 2000 and 3000 h, respectively. During exposure, the protective properties of the coatings were monitored by EIS and visual inspection. We observed a significant discrepancy between the measured impedance modulus in the low frequency range (|Z0.01Hz|), and the actual deterioration of the metal–paint interface. The degradation of the two painted substrates is independent of the accelerated test considered. The |Z0.01Hz| values do not represent the actual degradation state of the metal–polymer interface. The manuscript discusses the reasons for the lack of agreement between EIS and visual inspection. The limitations of using the low-frequency EIS impedance modulus to describe the protective properties of organic coatings are highlighted, and several cautions for interpreting the raw EIS data are suggested. The reliability of possible thresholds of |Z0.01Hz| (e.g., failure below 106 ohm∙cm2) to define the protective performance of the coating turned out to be misleading. Full article
(This article belongs to the Special Issue Degradation of Organic Coatings)
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